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Dr. Florian Späth Dr. Himadri R. Soni Johann Steinhauer Fabian Düll Dr. Udo Bauer Phillip Bachmann Dr. Wolfgang Hieringer Prof. Dr. Andreas Görling Prof. Dr. Hans-Peter Steinrück Dr. Christian Papp 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(37):8884-8893
The interaction of single-layer hexagonal boron nitride (h-BN) on Ni(111) with molecular oxygen from a supersonic molecular beam led to a covalently bonded molecular oxygen species, which was identified as being between a superoxide and a peroxide. This is a rare example of an activated adsorption process leading to a molecular adsorbate. The amount of oxygen functionalization depended on the kinetic energy of the molecular beam. For a kinetic energy of 0.7 eV, an oxygen coverage of 0.4 ML was found. Near-edge X-ray adsorption fine structure (NEXAFS) spectroscopy revealed a stronger bond of h-BN to the Ni(111) substrate in the presence of the covalently bound oxygen species. Oxygen adsorption also led to a shift of the valence bands to lower binding energies. Subsequent temperature-programmed X-ray photoelectron spectroscopy revealed that the oxygen boron bonds are stable up to approximately 580 K, when desorption, and simultaneously, etching of h-BN set in. The experimental results were substantiated by density functional theory calculations, which provided insight to the adsorption geometry, the adsorption energy and the reaction pathway. 相似文献
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Dr. Niels Zijlstra Fabian Dingfelder Dr. Bengt Wunderlich Dr. Franziska Zosel Dr. Stephan Benke Dr. Daniel Nettels Prof. Dr. Benjamin Schuler 《Angewandte Chemie (International ed. in English)》2017,56(25):7126-7129
To enable the investigation of low-affinity biomolecular complexes with confocal single-molecule spectroscopy, we have developed a microfluidic device that allows a concentrated sample to be diluted by up to five orders of magnitude within milliseconds, at the physical limit dictated by diffusion. We demonstrate the capabilities of the device by studying the dissociation kinetics and structural properties of low-affinity protein complexes using single-molecule two-color and three-color Förster resonance energy transfer (FRET). We show that the versatility of the device makes it suitable for studying complexes with dissociation constants from low nanomolar up to 10 μm , thus covering a wide range of biomolecular interactions. The design and precise fabrication of the devices ensure simple yet reliable operation and high reproducibility of the results. 相似文献
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A key feature of dynamic problems which offer degrees of freedom to the decision maker is the necessity for a goal-oriented decision making routine which is employed every time the logic of the system requires a decision. In this paper, we look at optimization procedures which appear as subroutines in dynamic problems and show how discrete event simulation can be used to assess the quality of algorithms: after establishing a general link between online optimization and discrete event systems, we address performance measurement in dynamic settings and derive a corresponding tool kit. We then analyze several control strategies using the methodologies discussed previously in two real world examples of discrete event simulation models: a manual order picking system and a pickup and delivery service. 相似文献