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91.
L. V. Ershova V. N. Gogitidze V. M. Belikov S. S. Novikov 《Russian Chemical Bulletin》1959,8(5):910-912
Summary A series of gem-dinitroparaffins, from 1,1-dimtropropane to 1,1-dinitrodecane, were prepared by Chancel's reaction; their constants were measured, and the refraction of the dinitromethyl group was determined. 相似文献
92.
V. A. Maksakov V. P. Kirin V. A. Ershova S. V. Tkachev P. P. Semyannikov 《Russian Chemical Bulletin》1993,42(11):1898-1901
The reactions of cysteine ethyl ester with a series of triosmium clusters have been studied. Enantiomeric (-H)Os3{-SCH2CH(CO2Et)NH2}(CO)10 and diastereomeric (-H)Os3{-2-SCH2CH(CO2Et)NH2}(CO)9 forms of the optically active cluster complexes have been obtained. Diastereomeric clusters have been separated by TLC on Silufol plates. The treatment of the enantiomeric complex (-H)Os3{-SCH2CH(CO2Et)NH2}(CO)10 with the trimethylamine oxide yields the diastereomeric pair (-H)Os3{-2-SCH2CH(CO2Et)NH2}(CO)9. The structures of the complexes obtained have been established on the basis of IR,1H NMR and mass spectrometry as well as X-ray analysis data.Translated fromIzyestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 1981–1984, November, 1993. 相似文献
93.
Optical and Chromaticity Characteristics of Cobalt and Palladium 4-(2-Pyridylazo)resorcinates 总被引:2,自引:0,他引:2
V. M. Ivanov N. I. Ershova V. N. Figurovskaya A. V. Ivanov 《Journal of Analytical Chemistry》2001,56(2):143-148
Optical and chromaticity characteristics (diffuse reflectances, chromaticity coordinates, lightness, color saturation, yellowness, color tint, and whiteness) of cobalt and palladium complexes of 4-(2-pyridylazo)resorcinol were determined at pH 7.2–7.9 and in 1 M H2SO4. The conditions of the separate determination of cobalt and palladium in the presence of each other by changing the order of the addition of reagent and using bifunctional chromaticity measurements and two-wavelength spectrophotometry are specified. The advantages of the chromaticity measurements are demonstrated. The proposed procedures were used for the analysis of model mixtures, binary cobalt–palladium alloys, and cobalt and palladium catalysts. 相似文献
94.
N. G. Chernorukov N. N. Smirnova A. V. Knyazev M. N. Marochkina A. V. Ershova 《Russian Journal of Physical Chemistry A, Focus on Chemistry》2006,80(12):1915-1919
The standard enthalpy of formation of crystalline UO2(BO2)2 at 298.15 K was determined by reaction calorimetry (?2542.5 ± 3.5 kJ/mol). The heat capacity of this compound was measured over the temperature range 6–302 K by adiabatic vacuum calorimetry. The thermodynamic functions were calculated, including the standard entropy (502.8 ± 2.1 J/(mol K)) and Gibbs function of formation (?2392.5 ± 4.0 kJ/mol) at 298.15 K. The standard thermodynamic functions of reactions with the participation of uranyl metaborate were determined and analyzed. 相似文献
95.
N. G. Chernorukov A. V. Knyazev A. V. Ershova 《Russian Journal of Inorganic Chemistry》2007,52(8):1171-1174
Compounds with the composition Ba(M 2/3 III U1/3)O3 (MIII = Sc, Y, In, Nd-Lu) were synthesized by high-temperature solid-state reactions. The structures of the compounds were studied by X-ray diffraction analysis, including the high-temperature method, and IR spectroscopy. 相似文献
96.
Chromaton-N-super and Silasorb C18 (SMT C18) were compared as solid supports for the direct determination of the immobilized beryllium complexes with eriochrome cyanine R by diffuse reflection spectroscopy. The advantage of Silasorb C18 was shown. A detection limit of 0.0002 microg mL(-1) could be reached in a 100-mL sample. The method was used for the analysis of real water samples. 相似文献
97.
Russian Journal of Coordination Chemistry - The currently available published data on the synthesis, structure, and chemical properties of Group III metal complexes based on bi-, tri-, and... 相似文献
98.
E. S. Kelbysheva L. N. Telegina E. A. Ershova T. V. Strelkova M. G. Ezernitskaya E. V. Nosova A. F. Smol´yakov F. M. Dolgushin N. M. Loim 《Russian Chemical Bulletin》2017,66(2):327-335
The synthesis of new quinazoline derivatives with 2,3- and 4-positioned cymantrenyl fragment is described. Alkylation of 2-substituted quinazolin-4-ones with cymantrenylalkyl bromides on using K2CO3, potassium tert-butoxide, and sodium hydride as bases has been studied. It is established for the first time that condensation of 2-methylquinazolin-4-ones with aldehydes can cause elimination of the substituent at the nitrogen atom in position 3. The new cymantrene derivatives possess fluorescence properties. 相似文献
99.
Yu. V. Kokunov M. M. Ershova G. A. Razgonyaeva 《Russian Journal of Coordination Chemistry》2002,28(7):461-463
Reactions of SnF2 and SbF3 with POCl3 and PCl5 in acetonitrile were studied by 19F, 31P, and 119Sn NMR. Tetrahedral compounds POF2Cl and POF3 form in the reaction with POCl3. Interaction of SnF2 and SbF3 with PCl5 yields higher (in terms of fluorine) octahedral complexes [PF5 · MeCN] and [PF6]–. In all cases, fluorine-free phosphorus compounds are found in the acetonitrile solution. 相似文献
100.
N. G. Chernorukov N. N. Smirnova A. V. Knyazev M. N. Marochkina A. V. Ershova 《Russian Journal of Physical Chemistry A, Focus on Chemistry》2008,82(3):337-342
The standard enthalpies of formation of crystalline Ba(BUO5)2 and Ba(BUO5)2 · 2H2O at 298.15 K were determined by reaction calorimetry. The temperature dependences of the heat capacities of these compounds were studied over the temperature range 7–340 K by adiabatic vacuum calorimetry, and their thermodynamic functions were determined. The standard entropies and Gibbs functions of formation of these compounds at 298.15 K were calculated. 相似文献