Crystal Structure of [Co(NH3)5NO3](NO3)(PF6)?·?1.5H2O and the Vibrational Bands of its Normal and 15NO3-Enriched Cation

The crystal structure of [Co(NH₃)₅NO₃](NO₃)(PF₆) ·1.5 H₂O was studied by X-ray diffraction methods in order to obtain the unknown molecular structure of the [Co(NH₃)₅NO₃]²⁺ cation . The substance crystallizes in the monoclinic system, space group C2/m, with a = 18.6231(6) ?, b = 7.8757(3) ?, c = 9.6434(3) ? and β = 95.484(2)°. An infrared and Raman study of the bromide salt was also performed and the spectra interpreted with the aid of ¹⁴NO₃/¹⁵NO₃ isotopic replacement and quantum chemistry calculations. E.L. Varetti — Member of the Carrera del Investigador Científico, CONICET, R. Argentina     

Zur Bestimmung der Reinheit von Terpentinöl

Analytical and Bioanalytical Chemistry -     

Failure of the discrete maximum principle for an elliptic finite element problem

There has been a long-standing question of whether certain mesh restrictions are required for a maximum condition to hold for the discrete equations arising from a finite element approximation of an elliptic problem. This is related to knowing whether the discrete Green's function is positive for triangular meshes allowing sufficiently good approximation of functions. We study this question for the Poisson problem in two dimensions discretized via the Galerkin method with continuous piecewise linears. We give examples which show that in general the answer is negative, and furthermore we extend the number of cases where it is known to be positive. Our techniques utilize some new results about discrete Green's functions that are of independent interest.

     

Individual transferable vessel quotas and efficient restructuring of the primary harvesting sector

Over the last three decades most of the world's fisheries have been subject to management programs that have tried to limit the use of key fishing inputs. Inevitably, these restrictions have proven ineffective at preventing rent dissipation and stock depletion. More noteworthy is that fishers have subverted the intentions of these restrictions by adjusting the primary harvesting technology. This has led to an inefficient industrial structure characterized by capital stuffing on the part of each vessel, excess employment, an inefficient mix of vessels in the fleet, and too many vessels altogether.A promising means of encouraging more efficient primary harvesting is the individual transferable vessel quota that allocates a given catch to each vessel, thereby giving an incentive to catch the quota at least cost. This paper examines efficiency gains and potential industry restructuring from the introduction of an ITVQ into a fishery that was previously subject to input restrictions.Using data from the British Columbia salmon fishery, this paper estimates restricted cost functions for each of four different vessel types and simulates the operations of a market for ITVQs. The demand for quota comes from individual vessels and is found by differentiating the cost function with respect to the shadow price of quota. The market for quota is in equilibrium when the total demand for quota is equal to the fixed supply of quota set by the government. This implicitly defines the equilibrium quota rental price. Results show that the ITVQ could generate unit rental prices for quota between 31 and 93 cents per pound (18–53% of the average landed price).Using this simulated price, each vessel's costminimizing strategy is defined and both low cost vessels (those that will buy quota) and high cost vessels (those that will sell quota and exit the fishery) are identified. Quota trades between the two groups result in efficiency gains. These include reduced capital stuffing, exit of less efficient vessel types, attainment of economies of scale, and an efficient composition of vessel types in the fleet. In aggregate these gains lead to an estimate of annual resource rent that is approximately equal to one third of the value of the catch.     

Dynamical Stark Effect in the nu(2)/nu(4) Vibrational Polyad of SiH(4): Theory and Observation

We report a theoretical and experimental investigation of the dynamical Stark effect in a tetrahedral molecule, silane (SiH(4)). We use a tetrahedral formalism and Floquet theory to calculate the absorption spectra for the molecule dressed by an intense nonresonant pulsed laser. Experimentally, the dynamical Stark effect is observed for transitions of the nu(2)/nu(4) vibrational polyad of SiH(4) by means of nanosecond diode laser absorption spectroscopy and a Nd:YAG laser excitation. Copyright 2000 Academic Press.