可换环上上三角矩阵代数的局部若当导子和局部若当自同构

Let R be a commutative ring with identity, Tn （R） the R-algebra of all upper triangular n by n matrices over R. In this paper, it is proved that every local Jordan derivation of Tn （R） is an inner derivation and that every local Jordan automorphism of Tn（R） is a Jordan automorphism. As applications, we show that local derivations and local automorphisms of Tn （R） are inner.     

Biological evaluation and SPECT imaging of tumor hypoxia using a novel technetium-99m labeled tracer with 2-nitroimidazole moiety

Journal of Radioanalytical and Nuclear Chemistry - To develop novel 99mTc labeled nitroimidazole imaging agents for imaging tumor hypoxia, 99mTc labeled ethylene diamine tetraacetic acid derivative...     

Electronic Perturbation of Copper Single-Atom CO2 Reduction Catalysts in a Molecular Way

Fine-tuning electronic structures of single-atom catalysts (SACs) plays a crucial role in harnessing their catalytic activities, yet challenges remain at a molecular scale in a controlled fashion. By tailoring the structure of graphdiyne (GDY) with electron-withdrawing/-donating groups, we show herein the electronic perturbation of Cu single-atom CO₂ reduction catalysts in a molecular way. The elaborately introduced functional groups (−F, −H and −OMe) can regulate the valance state of Cu^δ+, which is found to be directly scaled with the selectivity of the electrochemical CO₂-to-CH₄ conversion. An optimum CH₄ Faradaic efficiency of 72.3 % was achieved over the Cu SAC on the F-substituted GDY. In situ spectroscopic studies and theoretical calculations revealed that the positive Cu^δ+ centers adjusted by the electron-withdrawing group decrease the pK_a of adsorbed H₂O, promoting the hydrogenation of intermediates toward the CH₄ production. Our strategy paves the way for precise electronic perturbation of SACs toward efficient electrocatalysis.     

基于Si-rich SiNx/N-rich SiNy多层膜结构的量子点构筑及发光特性

利用等离子体增强化学气相沉积法制备Si-rich SiN_x/N-rich SiN_y多层膜,分别使用热退火和激光辐照技术对多层膜进行退火,以构筑三维限制、尺寸可控、有序的硅纳米晶.实验结果表明,经退火后,纳米硅晶粒在Si-rich SiN_x子层内形成,其尺寸可由Si-rich SiN_x子层厚度调控.实验还发现,激光辐照技术相比于热退火能更有效地改善多层膜的微结构,提高多层膜的晶化率,以激光技术诱导晶化的Si-rich SiN_x/N-rich SiN_y多层膜作为有源层构建电致发光器件,在室温下观察到了增强的电致可见发光,并且发光效率较退火前提高了40%以上. 关键词： 氮化硅 多层膜 限制结晶 纳米晶硅     

Stochastic modeling of unresolved scales in complex systems

Model uncertainties or simulation uncertainties occur in mathematical modeling of multiscale complex systems, since some mechanisms or scales are not represented (i.e., ‘unresolved’) due to a lack in our understanding of these mechanisms or limitations in computational power. The impact of these unresolved scales on the resolved scales needs to be parameterized or taken into account. A stochastic scheme is devised to take the effects of unresolved scales into account, in the context of solving nonlinear partial differential equations. An example is presented to demonstrate this strategy. Dedicated to Professor Peter E. Kloeden on the occasion of his 60th birthday     

离子速度成像技术研究2-溴戊烷的光解离动力学

运用离子速度成像技术研究了2-溴戊烷分子在～234 nm处的光解离动力学. 通过分析光解产物Br(²P_3/2)(简称Br)和Br(²P_1/2) (简称Br*)的速度影像,分别得到其速度分布和角度分布. Br和Br*的速度分布可以用两个高斯分布拟合,分别对应于2-溴戊烷在～234 nm处两个独立的光解离反应通道. 高能的高斯分量对应于C-Br伸缩振动模式的直接解离,低能的高斯分量对应于弯曲振动和C-Br伸缩振动耦合所导致的解离. 确定出光解离产物Br的相对量子产率为0.892,结合Br和Br*碎片的各项异性参数和溴原子的相对量子产率,讨论了³Q₀、³Q₁和¹Q₁激发态分别对产物Br和Br*的贡献. 通过对比溴代戊烷4种同分异构体光解离过程的差异,讨论了分子烷基分支化对光解机理的影响.     

判定Q上多项式不可约的一种方法

本文运用复变函数论中的Rouche定理,对Person不可约方法作了大的改进,一系列多项式的不可约性被证实.     

太赫兹辐射场下的石墨烯光生载流子和光子发射

通过半经典的玻尔兹曼平衡方程理论研究了太赫兹辐射场下的石墨烯光生载流子和光子发射.研究得到了太赫兹辐射场下石墨烯的光生载流子浓度和光子发生率的解析公式.研究发现,掺杂电子浓度越小,或者温度越低,光生载流子浓度越大;掺杂电子浓度越大,或者温度越低,石墨烯的光子发射率越大.通过改变门电压或温度,可以有效地调控石墨烯光生载流子浓度和光子发射概率.理论研究结果和解析表达式对发展以石墨烯为基础的新型太赫兹光电器件具有重要的参考价值.     

高速高饱和单行载流子光探测器的设计与分析

设计了一种In P基的背入射台面结构的单行载流子光探测器.通过在吸收层中采取高斯型掺杂界面及引入合适厚度和掺杂浓度的崖层,使得光探测器同时具备了高速和高饱和电流特性.理论分析表明,在光敏面为14μm2、反向偏压为2 V条件下,该器件的3 d B带宽可达58 GHz,直流饱和电流高达158 m A.在大功率光注入条件下,详细分析了光探测器带宽降低和电流饱和现象,得出能带偏移和电场坍塌是其根本原因的结论.