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81.
O. S. Kukovinets T. I. Zvereva V. G. Kasradze L. R. Khalitova N. N. Kabal’nova E. V. Salimova M. I. Abdullin 《Russian Journal of Organic Chemistry》2012,48(7):914-917
The conditions of ozonolysis of verbenone in methanol strongly affect the mechanism of formation of the major product, (1R,3S)-3-acetyl-2,2-dimethylcyclobutane-1-carboxylic acid. 相似文献
82.
Oganessian YTs Abdullin FSh Dmitriev SN Gostic JM Hamilton JH Henderson RA Itkis MG Moody KJ Polyakov AN Ramayya AV Roberto JB Rykaczewski KP Sagaidak RN Shaughnessy DA Shirokovsky IV Stoyer MA Subbotin VG Sukhov AM Tsyganov YS Utyonkov VK Voinov AA Vostokin GK 《Physical review letters》2012,108(2):022502
Results of a new series of experiments on the study of production cross sections and decay properties of the isotopes of element 115 in the reaction (243)Am+(48)Ca are presented. Twenty-one new decay chains originating from (288)115 were established as the product of the 3n-evaporation channel by measuring the excitation function at three excitation energies of the compound nucleus (291)115. The decay properties of all newly observed nuclei are in full agreement with those we measured in 2003. At the lowest excitation energy E*=33 MeV, for the first time we registered the product of the 2n-evaporation channel, (289)115, which was also observed previously in the reaction (249)Bk+(48)Ca as the daughter nucleus of the decay of (293)117. The maximum cross section for the production of (288)115 is found to be 8.5 pb at E*≈36 MeV. 相似文献
83.
Prof. Lucia Zakharova Dr. Mikhail Voronin Dr. Vyacheslav Semenov Dinar Gabdrakhmanov Dr. Victor Syakaev Dr. Yuri Gogolev Dr. Rashit Giniyatullin Dr. Svetlana Lukashenko Prof. Vladimir Reznik Dr. Shamil Latypov Alexander Konovalov Prof. Yuri Zuev 《Chemphyschem》2012,13(3):788-796
Novel mono‐ and dicationic pyrimidinic surfactants are synthesized and their aggregation behavior is studied by methods of tensiometry and nuclear magnetic resonance (NMR) self‐diffusion. To estimate their potentiality as gene delivery agents, the complexation with oligonucleotides (ONus) is explored by dynamic light scattering (DLS) and zeta‐potential titration methods and ethidium bromide exclusion experiments. Bola‐type pyrimidinic amphiphile (BPM) demonstrates rather a weak affinity to ONus. Although it induces mixed associations with ONus, only slight charge compensation changes occur at a large excess of bola, with no recharging reached. Similarly, the ethydium bromide exclusion study reveals a slow increase in the binding capacity toward an ONu with an increment in BPM concentration. The monocationic pyrimidinic surfactant (MPM) and its gemini analogue (GPM‐1) are ranked as intermediates in both their aggregative activity and complexing properties toward ONus. They both form mixed associates with ONus well below the critical micelle concentrations (cmcs) of 2 and 15 mM respectively. However, GPM‐1 has a much lower isoelectric point at the molar ratio surfactant/ONu r~1 compared to r~3 for MPM. This probably indicates a larger electrostatic contribution to the ONu complexation in the case of GPM‐1. The most hydrophobic pyrimidinic surfactant (GPM‐2), bearing three alkyl tails, demonstrates enhanced aggregative activity and binding capacity toward ONus as compared to former pyrimidinic surfactants. Due to effective aggregative (low cmc of 0.04 mM ) plus binding properties (fraction of bound ONu β=0.76 at r=2.5), GPM‐2 may be ranked as a promising agent for wider biological applications. 相似文献
84.
O. S. Kukovinets E. T. Yamansarova V. G. Kasradze E. A. Lozhkina R. A. Zainullin M. I. Abdullin 《Russian Journal of Organic Chemistry》2005,41(5):673-677
By reaction of phenoxyethanol with diverse structure acyl chlorides phenoxyethanol esters were synthesized containing in the molecule fragments of undecene acid and also of some ketocarboxylic acids. The latter acids were obtained by ozonation of alkylcyclenes.__________Translated from Zhurnal Organicheskoi Khimii, Vol. 41, No. 5, 2005, pp. 690–694.Original Russian Text Copyright © 2005 by Kukovinets, Yamansarova, Kasradze, Lozhkina, Zainullin, Abdullin. 相似文献
85.
E. T. Yamansarova O. S. Kukovinets R. A. Zainullin F. Z. Galin M. I. Abdullin 《Russian Journal of Organic Chemistry》2005,41(4):546-550
Nitrogen-containing phenoxyacetic acid derivatives were synthesized by reactions of substituted phenoxyacetic acids with amines, urea, and ethyl carbamate.__________Translated from Zhurnal Organicheskoi Khimii, Vol. 41, No. 4, 2005, pp. 557–561.Original Russian Text Copyright © 2005 by Yamansarova, Kukovinets, Zainullin, Galin, Abdullin. 相似文献
86.
M. I. Abdullin A. B. Glazyrin A. V. Sheludchenko A. M. Samoilov V. N. Zaboristov 《Russian Journal of Applied Chemistry》2007,80(11):1936-1939
The physicomechanical, viscoelastic, and rheological characteristics of syndiotactic 1,2-polybutadiene were studied and compared with those of the analogs produced in other countries. 相似文献
87.
E. N. Abdullin N. G. Ivanov B. M. Kovalchuk V. F. Losev G. A. Mesyats V. S. Skakun V. F. Tarasenko I. Yu. Turchanovsky A. G. Yastremsky 《Laser Physics》2006,16(1):89-103
Schemes of high-power electron-beam-pumped pulsed lasers on dense gases and the experimental results on the lasing on XeCl*,
KrF*, and HF molecules are presented. The energy input and the kinetic processes in the active medium of the electron-beam-excited
XeCl laser are calculated. Radiation pulse energies of 1900, 200, and 90 J are obtained at wavelengths of 308 nm, 2.8 μm,
and 249 nm, respectively.
Original Text ? Astro, Ltd., 2006. 相似文献
88.
A. B. Glazyrin M. I. Abdullin V. A. Dokichev R. M. Sultanova R. R. Muslukhov T. A. Yangirov 《Polymer Science Series B》2013,55(11-12):651-656
Polymer products containing methoxycarbonyl-substituted cyclopropane groups in macromolecules with degrees of functionalization up to 40% have been obtained through the interaction of polybutadiene with methyl diazoacetate in an organic solvent in the presence of an organometallic catalyst. The comparative catalyst activity in the reaction of cyclopropanation of polybutadiene has been estimated. The incorporation of methoxycarbonyl-substituted cyclopropane groups into polydiene units results in substantial changes in the polymer properties: solution viscosity, melt flow, glass-transition temperature, and thermal stability. 相似文献
89.
90.
Shakhmaeva II Saifullina DV Sattarova LI Abdullin TI 《Analytical and bioanalytical chemistry》2011,401(8):2591-2597
We designed an electrochemical sensor based on a carbon nanotube modified electrode (ME) to analyze DNA-cleaving activity.
The cleavage of high molecular weight DNA resulted in an increase in the oxidation current from DNA guanine nucleotides due
to a change in DNA adsorptive behavior on the surface of the ME. DNA digestion with DNAse I was accompanied by a linear increase
in the DNA signal in proportion to the enzyme activity. We then proposed an assay based on the sensor for the direct assessment
of the total deoxyribonuclease activity of blood serum as well as the separate detection of DNAse I and DNA abzymes. The assay
was applied to analyze deoxyribonucleases in sera from 21 healthy donors and 17 patients with autoimmune thyroiditis. Our
results show that the response of the sensor to DNA cleavage by blood deoxyribonucleases is a promising diagnostic criterion
for autoimmune thyroiditis. This sensor can be implemented in a disposable screen-printed electrode format for application
in clinical laboratories. 相似文献