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11.
Aziz Gozgen Aydan Dag Hakan Durmaz Okan Sirkecioglu Gurkan Hizal Umit Tunca 《Journal of polymer science. Part A, Polymer chemistry》2009,47(2):497-504
A combination of ring opening metathesis polymerization (ROMP) and click chemistry approach is first time utilized in the preparation of 3‐miktoarm star terpolymer. The bromide end‐functionality of monotelechelic poly(N‐butyl oxanorbornene imide) (PNBONI‐Br) is first transformed to azide and then reacted with polystyrene‐b‐poly(methyl methacrylate) copolymer with alkyne at the junction point (PS‐b‐PMMA‐alkyne) via click chemistry strategy, producing PS‐PMMA‐PNBONI 3‐miktoarm star terpolymer. PNBONI‐Br was prepared by ROMP of N‐butyl oxanorbornene imide (NBONI) 1 in the presence of (Z)‐but‐2‐ene‐1,4‐diyl bis(2‐bromopropanoate) 2 as terminating agent. PS‐b‐PMMA‐alkyne copolymer was prepared successively via nitroxide‐mediated radical polymerization (NMP) of St and atom transfer radical polymerization (ATRP) of MMA. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 497–504, 2009 相似文献
12.
Aydan Dag Hakan Durmaz Umit Tunca Gurkan Hizal 《Journal of polymer science. Part A, Polymer chemistry》2009,47(1):178-187
Two types of multiarm star block copolymers: (polystyrene)m‐poly(divinylbenzene)‐poly(methyl methacrylate)n, (PS)m‐polyDVB‐(PMMA)n and (polystyrene)m‐poly(divinylbenzene)‐poly(tert‐butyl acrylate)k, (PS)m‐polyDVB‐(PtBA)k were successfully prepared via a combination of cross‐linking and Diels–Alder click reactions based on “arm‐first” methodology. For this purpose, multiarm star polymer with anthracene functionality as reactive periphery groups was prepared by a cross‐linking reaction of divinyl benzene using α‐anthracene end functionalized polystyrene (PS‐Anth) as a macroinitiator. Thus, obtained multiarm star polymer was then reacted with furan protected maleimide‐end functionalized polymers: PMMA‐MI or PtBA‐MI at reflux temperature of toluene for 48 h resulting in the corresponding multiarm star block copolymers via Diels–Alder click reaction. The multiarm star and multiarm star block copolymers were characterized by using 1H NMR, SEC, Viscotek triple detection SEC (TD‐SEC) and UV. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 178–187, 2009 相似文献
13.
Aydan Dag Hakan Durmaz Emrah Demir Gurkan Hizal Umit Tunca 《Journal of polymer science. Part A, Polymer chemistry》2008,46(20):6969-6977
The double click reactions (Cu catalyzed Huisgen and Diels–Alder reactions) were used as a new strategy for the preparation of well‐defined heterograft copolymers in one‐pot technique. The synthetic strategy to the various stages of this work is outlined: (i) preparing random copolymers of styrene (St) and p‐chloromethylstyrene (CMS) (which is a functionalizable monomer) via nitroxide mediated radical polymerization (NMP); (ii) attachment of anthracene functionality to the preformed copolymer by the o‐etherification procedure and then conversion of the remaining ? CH2Cl into azide functionality; (iii) by using double click reactions in one‐pot technique, maleimide end‐functionalized poly(methyl methacrylate) (PMMA‐MI) via atom transfer radical polymerization (ATRP) of MMA and alkyne end‐functionalized poly (ethylene glycol) (PEG‐alkyne) were introduced onto the copolymer bearing pendant anthryl and azide moieties. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 6969–6977, 2008 相似文献
14.
Niyazi Bicak Umit Tunca Yusuf Yagci 《Journal of polymer science. Part A, Polymer chemistry》1989,27(11):3759-3767
Three new polyamidoximes (PAO) having appropriate functionalities to bind transition metal ions were prepared. The polymers were obtained by the reaction of dichlorooximino ethane with the corresponding diamine. Characterization and crosslinking of PAOs via coordination with transition metal ions such as Ni(II), Co(II), Cu(II), and UO2(II) are presented. The crosslinked polymer complexes exhibit good thermal stability. It was also found that both square planar and tetrahedral coordination structures are present in the crosslinked polymers. 相似文献
15.
Bunyamin Karagoz Giancarlo Galli Hakan Durmaz Gurkan Hizal Umit Tunca Niyazi Bicak 《Colloid and polymer science》2010,288(5):535-542
A novel strategy was developed for tailoring of SiO2 and TiO2 nanoparticle surfaces with poly(ε-caprolactone) (PCL). Thus, a self-curable polyester, poly(2-hydroxypropylene maleate) was
adsorbed on the nanoparticle surfaces and heated to 180 °C to give a cross-linked polyester layer with residual hydroxyalkyl
groups on their surfaces. Surface-initiated polymerization of ε-caprolactone from hydroxyalkyl groups on the surfaces yielded
core-shell nanoparticles with cross-linked core and PCL shells (22.2–71.4%). The organic shell layers around the nanoparticle
cores were evidenced by transmission electron microscopy, dynamic light scattering, and thermogravimetric analyses techniques.
The core-shell nanoparticles were then employed in preparing the stable and the homogenous dispersions with poly(methyl methacrylate-stat-butyl acrylate) solutions. An application of the solutions onto glass substrates yielded uniform and nearly transparent free
standing films (40–60 μm) with good homogeneity as inferred from scanning electron microscopy pictures. 相似文献
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17.
Hakan Durmaz Muge Butun Gurkan Hizal Umit Tunca 《Journal of polymer science. Part A, Polymer chemistry》2012,50(15):3116-3125
We demonstrated the successful postfunctionalization of poly(oxanorbornene imide) (PONB) with two types of double bonds using sequential orthogonal reactions, nucleophilic thiol‐ene coupling via Michael addition and radical thiol‐ene click reactions. First, the synthesis of PONB with side chain acrylate groups is carried out via ring‐opening metathesis polymerization and nitroxide radical coupling reaction, respectively. Subsequently, the resulting polymer having two different orthogonal functionalities, main chain vinyl and side chain acrylate, is selectively modified via two sequential thiol‐ene click reactions, nucleophilic thiol‐ene coupling via Michael addition and photoinduced radical thiol‐ene. The orthogonal reactivity of two diverse double bonds, vinyl and acrylate functionalities, for the abovementioned consecutive thiol‐ene click reactions was first demonstrated on the model compound. © 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2012 相似文献
18.
Hakan Durmaz Aydan Dag Duygu Gursoy A. Levent Demirel Gurkan Hizal Umit Tunca 《Journal of polymer science. Part A, Polymer chemistry》2010,48(7):1557-1564
Multiarm star triblock terpolymers were obtained by using two different click reactions sequentially: Cu(I) catalyzed azide–alkyne and Diels–Alder. The synthetic strategy is described as follows: (poly(methyl methacrylate))n‐(polystyrene)m‐poly(divinyl benzene)) ((PMMA)n‐(PS)m‐polyDVB) multiarm star diblock copolymer was first obtained from an azide–alkyne click reaction of (alkyne‐PS)m‐polyDVB multiarm star polymer with α‐anthracene‐ω‐azide PMMA (anth‐PMMA‐N3), followed by a Diels–Alder click reaction of the anthracene groups at the star periphery with α‐maleimide poly (tert‐butyl acrylate) (PtBA‐MI) or α‐maleimide poly(ethylene glycol) (PEG‐MI) leading to target (PtBA)k‐(PMMA)n‐(PS)m‐polyDVB and (PEG)p‐(PMMA)n‐(PS)m‐polyDVB multiarm star triblock terpolymers. The hydrodynamic diameter of individual multiarm star triblock terpolymers were measured by dynamic light scattering (DLS) to be ~24–27 nm in consistent with the atomic force microscopy (AFM) images on silicon substrates. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 1557–1564, 2010 相似文献
19.
Recep Ucan Umit Tunca Gurkan Hizal 《Journal of polymer science. Part A, Polymer chemistry》2003,41(13):2019-2025
The controlled polymerization of methyl methacrylate (MMA) in bulk was initiated with p‐chlorobenzenediazonium tetrafluoroborate ( 1 ) and Cu(II) or Cu(I)/Cu(II)/N,N,N′,N″,N″‐pentamethyldietylene triamine (PMDETA) complex system at various temperatures (20, 60, and 90 °C). The proposed polymerization mechanism is based on the Meerwein‐type arylation reaction followed by a reverse atom transfer radical polymerization. In this mechanism, aryl radicals formed by the reaction with 1 and Cu(I) and/or PMDETA initiated the polymerization of MMA. The polymerization is controlled up to a molecular weight of 46,000 at 90 °C. Chain extension was carried out to confirm the controlled manner of the polymerization system. In all polymerization systems, the polydispersity index and initiator efficiency ranged from 1.10–1.57 to 0.10–0.21, respectively. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 2019–2025, 2003 相似文献
20.
Gurkan Hizal Umit Tunca Amitav Sanyal 《Journal of polymer science. Part A, Polymer chemistry》2011,49(19):4103-4120
Functional polymeric materials with desired properties can be designed by precise control of macromolecular architectures. Over the recent years, click reactions have enabled efficient synthesis of a variety of polymers with different topologies via efficient polymer–polymer conjugations. While the copper catalyzed Huisgen type (3+2) dipolar cycloaddition between azide and alkyne has been widely used toward this goal, the Diels–Alder (DA) reaction offers an alternative click reaction that allow efficient macromolecular conjugations, oftentimes without the need of any additional reagent or catalyst. This article highlights, with illustrative examples, the power of the DA “click” reaction to efficiently synthesize a variety of different well‐defined macromolecular constructs in a modular fashion. © 2011 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2011 相似文献