全文获取类型
收费全文 | 7307篇 |
免费 | 103篇 |
国内免费 | 18篇 |
专业分类
化学 | 3853篇 |
晶体学 | 81篇 |
力学 | 275篇 |
数学 | 924篇 |
物理学 | 2295篇 |
出版年
2022年 | 66篇 |
2021年 | 173篇 |
2020年 | 145篇 |
2019年 | 151篇 |
2018年 | 167篇 |
2017年 | 156篇 |
2016年 | 237篇 |
2015年 | 121篇 |
2014年 | 195篇 |
2013年 | 347篇 |
2012年 | 359篇 |
2011年 | 382篇 |
2010年 | 311篇 |
2009年 | 278篇 |
2008年 | 374篇 |
2007年 | 310篇 |
2006年 | 314篇 |
2005年 | 299篇 |
2004年 | 215篇 |
2003年 | 188篇 |
2002年 | 197篇 |
2001年 | 160篇 |
2000年 | 140篇 |
1999年 | 99篇 |
1998年 | 121篇 |
1997年 | 83篇 |
1996年 | 89篇 |
1995年 | 64篇 |
1994年 | 60篇 |
1993年 | 62篇 |
1992年 | 75篇 |
1991年 | 53篇 |
1990年 | 86篇 |
1989年 | 57篇 |
1988年 | 55篇 |
1987年 | 63篇 |
1986年 | 60篇 |
1985年 | 59篇 |
1984年 | 71篇 |
1983年 | 57篇 |
1982年 | 71篇 |
1981年 | 48篇 |
1980年 | 55篇 |
1979年 | 48篇 |
1978年 | 50篇 |
1977年 | 62篇 |
1976年 | 60篇 |
1975年 | 58篇 |
1974年 | 62篇 |
1973年 | 73篇 |
排序方式: 共有7428条查询结果,搜索用时 15 毫秒
11.
12.
We consider tilde-geometries (orT-geometries), which are geometries belonging to diagrams of the following shape: Here the rightmost edge stands for the famous triple cover of the classical generalized quadrangle related to the group Sp4(2). The automorphism group of the cover is the nonsplit extension 3·Sp4(2) – 3 ·S
6. Five examples of flag-transitiveT-geometries were known. These are rank 3 geometries related to the groupsM
24 (the Mathieu group),He (the Held group) and and 37·Sp6(2) (a nonsplit extension); a rank 4 geometry related to the Conway groupCo
1 and a rank 5 geometry related to the Fischer-Griess Monster groupF
1. In the present paper we construct an infinite family of flag-transitiveT-geometries and prove that all the new geometries are simply connected. The automorphism group of the rankn geometry in the family is a nonsplit extension of a 3-group by the symplectic group Sp2n
(2). The rank of the 3-group is equal to the number of 2-dimensional subspaces in ann-dimensional vector space over GF(2). 相似文献
13.
The effect of hydrophilic ionic liquids (ILs) on the activity of chloroperoxidase (CPO) was checked through kinetic and stereochemical studies. The possibility to employ this enzyme in synthesis has been demonstrated investigating the chemo- and stereoselectivity of oxidation of phenyl methylsulfide in several citrate buffer-IL mixtures. 相似文献
14.
In a two-dimensional array of magnetic moments with planar magnetization and relatively weak anisotropy in the basal plane, a stepwise phase transition is induced by an external magnetic field parallel to the easy axis of the system. This transition is similar to the spin flop phase transition in weakly anisotropic Heisenberg antiferromagnets with the significant difference that it is accompanied by the rearrangement of the sublattice structure of the magnet; i.e., it can be interpreted as a topological transition. The transition should manifest itself for arrays of submicron magnetic particles (magnetic dots) on nonmagnetic substrates, which have recently become the object of intensive research. 相似文献
15.
J. Gasser M.A. Ivanov E. Lipartia M. Mojzis A. Rusetsky 《The European Physical Journal C - Particles and Fields》2002,26(1):13-34
We investigate the ground-state energy of the atom (pionic hydrogen) in the framework of QCD + QED. In particular, we evaluate the strong energy-level shift. We perform
the calculation at next-to-leading order in the low-energy expansion in the framework of the relevant effective field theory.
The result provides a relation between the strong energy shift and the pion-nucleon S-wave scattering lengths - evaluated in pure QCD - at next-to-leading order in isospin-breaking and in the low-energy expansion.
We compare our result with available model calculations.
Received: 11 June 2002 / Published online: 9 October 2002 相似文献
16.
Ornella Azzolina Simona Collina Daniela Rossi Enrica Lanza 《Tetrahedron letters》2004,45(7):1355-1357
The diastereoselective synthesis of naphthyl amino alcohols via nucleophilic addition to racemic 1-dimethylamino-2-methylpentan-3-one was studied. The use of the appropriate experimental conditions allowed the synthesis of both diastereoisomers. The relative configurations were established via NOESY experiments. 相似文献
17.
L. S. Azhgirey V. V. Arkhipov S. V. Afanasiev V. K. Bondarev V. N. Zhmyro L. S. Zolin V. I. Ivanov A. Yu. Isupov A. A. Kartamyshev V. A. Kashirin V. I. Kolesnikov V. A. Kuznetsov V. P. Ladygin N. B. Ladygina A. G. Litvinenko S. G. Reznikov P. A. Rukoyatkin A. Yu. Semenov I. A. Semenova G. D. Stoletov G. Filipov A. N. Khrenov N. P. Yudin 《Physics of Atomic Nuclei》2003,66(4):690-699
The invariant differential cross section, the tensor analyzing power A yy , and the vector analyzing power A y for the reaction 9Be(d, p)X are measured at an initial deuteron momentum of 4.5 GeV/c and a proton detection angle of about 80 mrad. The data obtained for the differential cross section are consistent with the results of measurements at 3.5 and 5.78 GeV/c and a proton emission angle of 2.5°. The values found for the tensor analyzing power A yy are compared with similar data obtained previously for the deuteron-fragmentation process occurring on a carbon target at various values of the initial deuteron momentum and leading to proton emission at zero angle. The data on the differential cross section for the reaction 9Be(d, p)X can be satisfactorily described within the relativistic impulse approximation by using standard deuteron wave functions; however, the approach based on this conceptual framework proves to be inadequate in dealing with data on the tensor analyzing power. These results indicate that it is necessary either to change the method for describing the relativistic deuteron or to take into account additional mechanisms. 相似文献
18.
Hana Macková Daniela Králová Daniel Horák 《Journal of polymer science. Part A, Polymer chemistry》2007,45(24):5884-5898
The aim of this study was to develop novel thermally responsive polymer microspheres with magnetic properties. Dispersion and inverse emulsion copolymerization of N‐isopropylacrylamide (NIPAAm) and N,N′‐methylenebisacrylamide (MBAAm) was investigated in the presence of γ‐Fe2O3 nanoparticles. The resulting microspheres were characterized in terms of morphology, size, polydispersity, iron content, and temperature‐dependent swelling using optical microscopy, transmission electron microscopy, scanning electron microscopy, QELS, and AAS. The effects of several variables, such as the concentration of γ‐Fe2O3, MBAAm crosslinking agent, Span 80 surfactant, 2,2′‐azobis(2‐methyloctanenitrile) (AMON) initiator, and polymerization temperature on the properties of the microspheres were studied. Swelling and thermoresponsive behavior of the microspheres containing γ‐Fe2O3 nanoparticles were also investigated. The microspheres contained about 8 wt % of iron. The presence of magnetic nanoparticles and their concentration changes did not have any significant effect on the temperature sensitivity of the composites. The particles gradually shrink into an increasingly collapsed state when the temperature is raised to 40 °C since the increase in temperature weakens the hydration and PNIPAAm chains gradually become more hydrophobic, which leads to the collapse of the particles. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 5884–5898, 2007 相似文献
19.
A. V. Ivanov M. Yu. Tsentalovich E. G. Kogan L. G. Tomilova N. S. Zefirov 《Russian Chemical Bulletin》2008,57(8):1676-1679
The chlorination of benzene, toluene, and o-xylene with molecular chlorine in the presence of the phthalocyanine complexes of different structures was studied. The transformations
of the catalysts during the reaction were investigated.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1644–1647, August, 2008. 相似文献
20.
Results of measuring the monochromatic sound field with a dipping probe in the deep ocean are presented. The sound speed profile in the region of measurements had a minimum at a depth of 1600 m. The experiment was carried out in the Atlantic Ocean with the use of two vessels separated by a distance of approximately four ray cycles (~240 km). The experimental data are compared with the calculations based on a new concept of the Brillouin waves for describing the vertical structure of the sound field produced by rays. It is shown that a satisfactory agreement between experiment and calculation can be achieved by fitting the parameters of the experiment. Such a procedure allows one to refine or even to determine the experimental conditions, which not are always known. The proposed method of calculation offers an opportunity for solving inverse problems of ocean acoustics. 相似文献