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41.
Ersen G
KTÜRK 《Turkish Journal of Chemistry》2020,44(5):1285
In this study, the catalytic activity and stability of flowerlike hybrid horseradish peroxidase (HRP) nanobiocatalyst (HRP-Cu 2+ ) obtained from Cu 2+ ions and HRP enzyme in the polymerization reaction of guaiacol were analyzed. We demonstrated that HRP-Cu 2+ and hydrogen peroxide (H 2 O 2 ) initiator showed significantly increased catalytic activity and stability on the polymerization of guaiacol compared to that of free HRP enzyme. Poly(guaiacol) was observed with quite high yields (88%) and molecular weights (38,000 g/mol) under pH 7.4 phosphate-buffered saline (PBS) conditions at 60 °C with 5 weight% of HRP-Cu 2+ loading. HRP-Cu 2+ also shows very high thermal stability and works even at 70 °C reaction temperature; free HRP enzyme denatures at that temperature. Furthermore, HRP-Cu 2+ provided considerable repeated use and showed some degree of catalytic activity, even after the fourth recycle, in the polymerization of guaiacol. 相似文献
42.
shak ERK Gzde KILI Elif
ZTÜRK engül Alpay KARAOLU Nurettin YAYLI 《Turkish Journal of Chemistry》2020,44(6):1655
The volatile components of essential oil (EO), SPME, and SPME of solvent extracts ( n -hexane, methanol, and water) obtained from fresh Serapias orientalis subsp. orientalis ( Soo ) were analyzed by GC-FID/MS. EO of Soo gave 11 compounds in the percentage of 99.97%; capronaldehyde (37.01%), 2-( E )-hexenal (23.19%), and n -nonanal (19.05%) were found to be major constituents. SPME GC-FID/MS analyses of fresh plant and solvent extracts of Soo revealed 7, 12, 7, and 4 compounds within the range of 99.7% to 99.9%. Limonene (76.5%, 41.7%, and 61.3%) was the major compound in SPMEs of the n -hexane and methanol extracts. α -Methoxy- p -cresol (52.9%) was the main component in its water extract. The antimicrobial activity of EO and the solvent extracts of Soo were screened against 9microorganisms. EO showed the best activity against Mycobacterium smegmatis , with 79.5 µg/mL MIC value. The n -hexane, methanol, and water extracts were the most active against the Staphylococcus aureus within the range of 81.25–125.0 µg/mL (MIC). IC 50 values for the lipase enzyme inhibitory activity of EO and solvent extracts ( n -hexane, methanol, and water) were determined to be 59.87 µg/mL, 64.03 µg/mL, 101.91 µg/mL, and 121.24 µg/mL, respectively. 相似文献
43.
44.
An improved Hardy-Sobolev inequality and its application 总被引:4,自引:0,他引:4
Adimurthi Nirmalendu Chaudhuri Mythily Ramaswamy 《Proceedings of the American Mathematical Society》2002,130(2):489-505
For , a bounded domain, and for , we improve the Hardy-Sobolev inequality by adding a term with a singular weight of the type . We show that this weight function is optimal in the sense that the inequality fails for any other weight function more singular than this one. Moreover, we show that a series of finite terms can be added to improve the Hardy-Sobolev inequality, which answers a question of Brezis-Vazquez. Finally, we use this result to analyze the behaviour of the first eigenvalue of the operator as increases to for .
45.
We study the free energy of the worm-like-chain model, in the constant-extension ensemble, as a function of the stiffness lambda for finite chains of length L. We find that the polymer properties obtained in this ensemble are qualitatively different from those obtained using constant-force ensembles. In particular, we find that as we change the stiffness parameter, t=L/lambda, the polymer makes a transition from the flexible to the rigid phase and there is an intermediate regime of parameter values where the free energy has three minima and both phases are stable. This leads to interesting features in the force-extension curves. 相似文献
46.
Banerjee and Andrade generated axially symmetric electrovac solutions from the spherically symmetric Reissner-Nordström solution by giving a complex translation along theZ axis. We use the same method for generating new more complicated axially symmetric solutions from known solutions. Several such examples are given. 相似文献
47.
Ohne Zusammenfassung
Use of complex forming substitution reactions for the selective enthalpiometric determination of cations and anions相似文献
48.
A simple method for the amperometric estimation of N-cyclohexyl-2-benzothiazole sulphenamide, N-dicyclohexyl-2-benzothiazole sulphenamide, 2-(morpholinothio)benzothiazole and N-tert.-butyl-2-benzothiazole sulphenamide is reported. The results are obtained within 5 min and are correct within +/- 2.0%. 相似文献
49.
C.?SurEmail author B. K.?Sahoo R. K.?Chaudhuri B. P.?Das D.?Mukherjee 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2005,32(1):25-31
We have employed the relativistic coupled cluster theory to calculate
the magnetic dipole and electric quadrupole hyperfine constants for
the ground and low lying excited states of singly ionized magnesium.
Comparison with experimental and the other theoretical results are
done and predictions are also made for a few low lying excited states
which could be of interest. We have made comparative studies of the
important many body effects contributing to the hyperfine constants
for the different states of the ion. 相似文献
50.
Sonjoy?MajumderEmail author G.?Gopakumar R.?K.?Chaudhuri B.?P.?Das H.?Merlitz U.?S.?Mahapatra D.?Mukherjee 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2004,28(1):3-9
The relativistic coupled cluster theory is employed to calculate electric quadrupole (E2) transition probabilities among the doublet states of Mg II which are of interest in astrophysical problems. This is the first time a highly correlated fully ab initio method has been used to compute these quantities for this particular ion. The line strengths and transition probabilities of a number of different transitions are reported and compared with those available in the literature.Received: 4 June 2003, Published online: 30 September 2003PACS:
31.10. + z Theory of electronic structure, electronic transitions, and chemical bindingSonjoy Majumder: Present address: Institut für Theoretische Chemie, Technische Universität München, 85747 Garching, Germany. 相似文献