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81.
LetD be a Dedekind domain. It is well known thatD is then an atomic integral domain (that is to say, a domain in which each nonzero nonunit has a factorization as a product
of irreducible elements). We study factorization properties of elements in Dedekind domains with finite class group. IfD has the property that any factorization of an elementα into irreducibles has the same length, thenD is called a half factorial domain (HFD, see [41]). IfD has the property that any factorization of an elementα into irreducibles has the same length modulor (for somer>1), thenD is called a congruence half factorial domain of orderr. In Section I we consider some general factorization properties of atomic integral domains as well as the interrelationship
of the HFD and CHFD property in the Dedekind setting. In Section II we extend many of the results of [41], [42] and [36] concerning
HFDs when the class group ofD is cyclic. Finally, in Section III we consider the CHFD property in detail and determine some basic properties of Dedekind
CHFDs. IfG is any Abelian group andS any subset ofG−[0], then {G, S} is called a realizable pair if there exists a Dedekind domainD with class groupG such thatS is the set of nonprincipal classes ofG which contain prime ideals. We prove that for a finite abelian groupG there exists a realizable pair {G, S} such that any Dedekind domain associated to {G, S} is CHFD for somer>1 but not HFD if and only ifG is not isomorphic toZ
2,Z
2,Z
2 ⊕Z
2, orZ
3 ⊕Z
3.
The first author received support under the John M. Bennett Fellowship at Trinity University and also gratefully acknowledges
the support of The University of North Carolina at Chapel Hill. 相似文献
82.
R. Hyndman P. Warin J. Gierak J. N. Chapman J. Ferr J. P. Jamet V. Mathet C. Chappert 《Journal of magnetism and magnetic materials》2002,240(1-3):50-52
We present a study of the structural and magnetic effects induced by focused 30 keV Ga+ ion beam irradiation on a Pt(2.8 nm)/[Pt(0.6 nm)/Co(0.3 nm)]6/Pt(6.5 nm) ferromagnetic multilayer, using transmission electron microscopy, optical and magneto-optical microscopy. The work is of relevance to high-density data-storage applications, where media planarity is crucial for device reliability. 相似文献
83.
Synthesis and pH‐Dependent Spectroscopic Behavior of 2,4,6‐Trisubstituted Pyridine Derivatives 下载免费PDF全文
Gala Chapman Isaac Solomon Gabor Patonay Maged Henary 《Journal of heterocyclic chemistry》2015,52(3):861-872
Seven 2,4,6‐trisubstituted pyridine derivatives with N,N‐diethylaniline substituents at the 4‐position were synthesized, and their spectroscopic properties in the absence and presence of acid were studied. The spectral effects of protonation, molar absorptivities, pKa values, and the structural origins of the observed spectral behavior were ascertained. The pyridine nitrogen was found to be more basic than the diethylamino nitrogen atom. Protonation of the pyridine ring nitrogen is associated with the appearance of a red‐shifted intramolecular charge transfer peak in the UV‐visible spectra. Favorable color indicating properties result from electron‐donating substitution at the 2 and 6 positions of pyridine, which provide a greater absorptivity of the red‐shifted peak associated with protonation of the pyridine nitrogen. These findings will assist in the design and optimization of these compounds for ion‐indicating and pH‐sensing applications. 相似文献
84.
Surface and Structural Investigation of a MnOx Birnessite‐Type Water Oxidation Catalyst Formed under Photocatalytic Conditions 下载免费PDF全文
Benjamin J. Deibert Jingming Zhang Paul F. Smith Dr. Karena W. Chapman Dr. Sylvie Rangan Debasis Banerjee Kui Tan Hao Wang Nicholas Pasquale Prof. Feng Chen Prof. Ki‐Bum Lee Prof. G. Charles Dismukes Prof. Yves J. Chabal Prof. Jing Li 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(40):14218-14228
Catalytically active MnOx species have been reported to form in situ from various Mn‐complexes during electrocatalytic and solution‐based water oxidation when employing cerium(IV) ammonium ammonium nitrate (CAN) oxidant as a sacrificial reagent. The full structural characterization of these oxides may be complicated by the presence of support material and lack of a pure bulk phase. For the first time, we show that highly active MnOx catalysts form without supports in situ under photocatalytic conditions. Our most active 4MnOx catalyst (~0.84 mmol O2 mol Mn?1 s?1) forms from a Mn4O4 bearing a metal–organic framework. 4MnOx is characterized by pair distribution function analysis (PDF), Raman spectroscopy, and HR‐TEM as a disordered, layered Mn‐oxide with high surface area (216 m2g?1) and small regions of crystallinity and layer flexibility. In contrast, the SMnOx formed from Mn2+ salt gives an amorphous species of lower surface area (80 m2g?1) and lower activity (~0.15 mmol O2 mol Mn?1 s?1). We compare these catalysts to crystalline hexagonal birnessite, which activates under the same conditions. Full deconvolution of the XPS Mn2p3/2 core levels detects enriched Mn3+ and Mn2+ content on the surfaces, which indicates possible disproportionation/comproportionation surface equilibria. 相似文献
85.
Development and application of sub‐2‐μm particle CO2‐based chromatography coupled to mass spectrometry for comprehensive analysis of lipids in cottonseed extracts 下载免费PDF全文
86.
David F. Anderson Scott T. Chapman Nathan Kaplan Desmond Torkornoo 《Semigroup Forum》2011,82(1):96-108
Let M be a commutative, cancellative, atomic monoid and x a nonunit in M. We define ω(x)=n if n is the smallest positive integer with the property that whenever x∣a 1???a t , where each a i is an atom, there is a T?{1,2,…,t} with |T|≤n such that x∣∏k∈T a k . The ω-function measures how far x is from being prime in M. In this paper, we give an algorithm for computing ω(x) in any numerical monoid. Simple formulas for ω(x) are given for numerical monoids of the form 〈n,n+1,…,2n?1〉, where n≥3, and 〈n,n+1,…,2n?2〉, where n≥4. The paper then focuses on the special case of 2-generator numerical monoids. We give a formula for computing ω(x) in this case and also necessary and sufficient conditions for determining when x is an atom. Finally, we analyze the asymptotic behavior of ω(x) by computing \(\lim_{x\rightarrow \infty}\frac{\omega(x)}{x}\). 相似文献
87.
Semigroup Forum - John Meakin has had a distinguished career of over half a century in the theory of semigroups. This article gives a synopsis of his most important contributions. The author, a... 相似文献
88.
Samuel Cheeseman Z. L. Shaw Jitraporn Vongsvivut Russell J. Crawford Madeleine F. Dupont Kylie J. Boyce Sheeana Gangadoo Saffron J. Bryant Gary Bryant Daniel Cozzolino James Chapman Aaron Elbourne Vi Khanh Truong 《Molecules (Basel, Switzerland)》2021,26(13)
Biofilms are assemblages of microbial cells, extracellular polymeric substances (EPS), and other components extracted from the environment in which they develop. Within biofilms, the spatial distribution of these components can vary. Here we present a fundamental characterization study to show differences between biofilms formed by Gram-positive methicillin-resistant Staphylococcus aureus (MRSA), Gram-negative Pseudomonas aeruginosa, and the yeast-type Candida albicans using synchrotron macro attenuated total reflectance-Fourier transform infrared (ATR-FTIR) microspectroscopy. We were able to characterise the pathogenic biofilms’ heterogeneous distribution, which is challenging to do using traditional techniques. Multivariate analyses revealed that the polysaccharides area (1200–950 cm−1) accounted for the most significant variance between biofilm samples, and other spectral regions corresponding to amides, lipids, and polysaccharides all contributed to sample variation. In general, this study will advance our understanding of microbial biofilms and serve as a model for future research on how to use synchrotron source ATR-FTIR microspectroscopy to analyse their variations and spatial arrangements. 相似文献
89.
Let D be an integral domain such that Int(D) ≠ K[X] where K is the quotient field of D. There is no known example of such a D so that Int(D) has finite elasticity. If E is a finite nonempty subset of D, then it is known that Int(E, D) = {f(X) ∈ K[X] | f(e) ∈ D for all e ∈ E} is not atomic. In this note, we restrict the notion of elasticity so that it is applicable to nonatomic domains. For each
real number r ≥ 1, we produce a ring of integer-valued polynomials with restricted elasticity r. We further show that if D is a unique factorization domain and E is finite with |E| > 1, then the restricted elasticity of Int(E, D) is infinite. 相似文献
90.