A phase regulated back wave propagation technique for geoacoustic inversion

An inversion method based on the concept of back wave propagation (BWP) is described in this paper for estimation of geoacoustic parameters from acoustic field data. A phase-regulation technique is introduced to increase the sensitivity of the method for geoacoustic model parameters having low sensitivity. The case of data consisting of signal plus additive noise is also addressed. It is shown theoretically that the sensitivity can be increased by a factor alpha using the phase regulation procedure, and that the spatial resolution of signal energy that is concentrated by BWP at the known source position is increased when a increases. This result suggests an effective criterion for use in the inversion, based on the spatial distribution of signal energy around the true source location. The basis for the criterion is the spatial variance of the back-propagated pressure field in a window around the known source location. A multistep search process is proposed to avoid using a complicated multidimensional search process. Inversion results from both simulations and experimental data are given. The real data were taken from the Pacific Shelf experiment carried out in shallow water off the West Coast of Vancouver Island in the Northeast Pacific Ocean.     

Proper fibrations with Hilbert cube manifold fibers

The main result of this paper asserts that any proper fibration over a finite-dimensional ANR with Hilbert cube manifold fibers is a locally trivial bundle.     

The (t,p) reaction on the even isotopes of neodymium

The Aldermaston multi-angle magnetic spectrograph and tandem Van de Graaff accelerator have been used to study the (t, p) reactions leading to the neodymium isotopes ^{144,146,148,150, 152}Nd bombarding energy of 13 MeV. The Q-values were measured for final states with excitation energies up to about 3 MeV.     

Aromaticity and tautomerism—VII: Empirical resonance energy and conjugation energy of pyrazole and isoxazole from heats of dehydration data

The dehydration of various 4,5-dihydro-4- and -5-hydroxy derivatives of pyrazole and isoxazole has been investigated. Heats of dehydration of 4,5-duiydro-4-hydroxy-1,3,5-tripbenylpyrazole and 4,5-dihydro-5-hydroxy-isoxazole are evaluated and used to assess the empirical resonance energy and conjugation energy of pyrazole and isoxazole. The former possesses resonance stabilisation comparable to pyrrole but that of the latter is low.     

Exploration of the ultimate patterning potential achievable with high resolution focused ion beams

Controlled and reproducible fabrication of nano-structured materials will be one of the main industrial challenges in the next few years. We have recently proposed exploitation of the nano-structuring potential of a high resolution Focused Ion Beam Tool, to overcome basic limitations of current nano-fabrication techniques. The aim of this article is to present some new routes for material patterning, which benefit from ion-induced local property modifications or damage. In the experiments we describe hereafter an ultra-sharp pencil of 30 keV gallium ions is used to tailor the characteristics of several materials at a scale of a few nanometres. The experimental results are then compared to simulations. First, we simulate the control of collisional defects generated in a thin magnetic layer under FIB irradiation. The results explain the stable magnetic structures we have obtained experimentally. This was achieved with a low surface ion dose (10¹² to 10¹⁴ ions/cm²). In addition we have explored the promising direction of Bottom-up or self-organization processes using a FIB instrument. We have defined artificial surface defects. These defects created by the impact of an 8-nm FWHM probe were used to pin the diffusion and to organize nanometre-sized gold clusters on a graphite surface. PACS 79.20.Rf; 81.07.-b     

Structural analysis of ion irradiated polycrystalline NiFe/FeMn exchange bias systems

Structural investigations of the ion irradiated polycrystalline NiFe/FeMn exchange bias bilayer system were carried out by means of transmission electron microscopy. Key structural parameters like average grain size, lattice constant, and texture, as well as their dependence upon ion irradiation were determined. This information was extracted from a detailed analysis of a series of bright field images, dark field images, and diffraction patterns. Furthermore a previously established model was tested which ascribes changes in the magnetic properties upon irradiation with 5 keV He+ ions to the creation of point defects within the antiferromagnetic layer and to the intermixing between the ferromagnetic and antiferromagnetic layers. The obtained results indirectly support this model by excluding a change of the aforementioned structural parameters as a possible source of the observed modifications of the magnetic properties.     

Rhodium catalysed tandem conjugate addition-protonation: an enantioselective synthesis of 2-substituted succinic esters

The rhodium catalysed addition of potassium trifluoro(organo)borates to dimethyl itaconate generates an intermediate complex which on protonation provides enantioenriched succinic esters.     

Evidence of red cell alignment in the magnetic field of an NMR spectrometer based on the diffusion tensor of water

The alignment of human erythrocytes in aqueous suspensions in the magnetic field B(0) (called the z-direction) of an NMR spectrometer was shown by calculating the diffusion tensor for water in the sample. The diffusion was measured using a pulsed-field-gradient spin-echo NMR method. The extent of diffusion anisotropy for water was exemplified by the values of the apparent diffusion coefficients with erythrocytes of normal shape and volume: for a typical experiment the values for the x-, y-, and z-directions were (6.88 +/- 0.17) x 10(-10), (7.07 +/- 0.17) x 10(-10), and (10.20 +/- 0.17) x 10(-10) m(2) s(-1), respectively. Cells in hypo- and hyperosmotic media were also studied and they too showed the anisotropy of the apparent diffusion coefficients but the extents were different. A new method of data analysis was developed using the Standard Add-On Packages in a Mathematica program. The experimental findings support evidence of erythrocyte alignment that was previously obtained with a high-field-gradient q-space method.     

The Challenge of Paramagnetism in Two-Dimensional <Superscript>6,7</Superscript>Li Exchange NMR

^6,7Li fast magic-angle spinning solid-state nuclear magnetic resonance (NMR) spectroscopy is used to study LiMn₂O₄ and Li₃V₂(PO₄)₃. The presence of paramagnetic transition metal centers in these materials has a profound effect on the resulting NMR spectra. Lithium ion mobility has been studied by two-dimensional (2-D) exchange spectroscopy (EXSY) in Li₃V₂(PO₄)₃ but an absence of lithium ion exchange was observed for LiMn₂O₄. Several differences between the two materials are explored to explain these results. LiMn₂O₄ experiences a greater donation of electron spin density to the Li nucleus via the Fermi-contact interaction when compared with Li₃V₂(PO₄)₃. This contributes to a greater hyperfine chemical shift and a larger dependence of chemical shift on temperature. The delocalized electrons in LiMn₂O₄ cause temperature-independent T ₁ relaxation rates and shorter relative T ₂ values. The relative rates of ionic conductivity and spin–lattice or spin–spin relaxation in LiMn₂O₄ and Li₃V₂(PO₄)₃ are contrasted to illustrate the constraints on the use of 2-D EXSY to characterize ion dynamics in paramagnetic materials. Authors' address: Gillian R. Goward, Department of Chemistry and Brockhouse Institute for Materials Research, McMaster University, 1280 Main St. West, Hamilton, ON L8S 4M1, Canada