全文获取类型
收费全文 | 1404篇 |
免费 | 56篇 |
国内免费 | 169篇 |
专业分类
化学 | 838篇 |
力学 | 88篇 |
综合类 | 15篇 |
数学 | 79篇 |
物理学 | 609篇 |
出版年
2020年 | 3篇 |
2016年 | 7篇 |
2015年 | 19篇 |
2014年 | 10篇 |
2013年 | 19篇 |
2012年 | 16篇 |
2011年 | 283篇 |
2010年 | 160篇 |
2009年 | 137篇 |
2008年 | 16篇 |
2007年 | 16篇 |
2006年 | 19篇 |
2005年 | 61篇 |
2004年 | 181篇 |
2003年 | 140篇 |
2002年 | 109篇 |
2001年 | 124篇 |
2000年 | 32篇 |
1999年 | 25篇 |
1998年 | 20篇 |
1997年 | 17篇 |
1996年 | 9篇 |
1995年 | 8篇 |
1994年 | 10篇 |
1993年 | 52篇 |
1992年 | 49篇 |
1991年 | 29篇 |
1990年 | 17篇 |
1989年 | 22篇 |
1988年 | 10篇 |
1987年 | 2篇 |
1982年 | 1篇 |
1979年 | 1篇 |
1973年 | 1篇 |
1964年 | 2篇 |
1933年 | 2篇 |
排序方式: 共有1629条查询结果,搜索用时 390 毫秒
141.
ZHAO Hai-feng WU Lei LU Ming HU Yu-lin HAN Xiao LI Zheng-qiang . Key Laboratory for Molecular Enzymology & Engineering Ministry of Education Jilin University Changchun P. R. China . Medical 《高等学校化学研究》2011,(3):450-454
Lipid-bound [VHb(406)] and lipid-free [VHb(402)] wide type Vitreoscilla hemoglobin were separated from E. coli BL21(DE3). The RZ is 3.30 for [VHb(406)] and 3.15 for [VHb(402)], respectively. VHb(406) shows a characteristic absorption band at 626 nm, while VHb(402) shows one at 644 nm, and it has more α-helix than VHb(402). Data of Raman spectra experiment shows under the excitation wavelength 488 nm, υ4 vibration of both VHb(402) and VHb(406) had a pure and strong signal at 1375 cm-1, which proves that iron... 相似文献
142.
FU JunDan TANG ZhiWei FENG Xia & WEN YiHang Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces 《中国科学:化学》2010,(5)
Three d10 tetranuclear complexes,Cd 4(1,8-nap) 4(2,2′-bipy) 4(H2O) 8·6H2O(1,8-nap=naphthalene-1,8-dicarboxylate and 2,2′bipy=2,2′-bipyridine)(1),Cd4(1,8-nap) 4(2,2′-bipy) 4(H2O) 8·6H2O(2) andZn4(1,8-nap) 4(2,2′-bipy) 4(H2O) 4·2H2O(3),have been synthesized under hydrothermal conditions and characterized by elemental analyses,IR and X-ray diffraction techniques. Complexes 1 and 2 are isomers showing one-dimensional ribbon-like structures connected by O-H···O hydrogen bonds,and the one-dimensional ribbons are ... 相似文献
143.
ZHANG Hong YU Yaoting PAN Jilun XU Yuanping ZHU Hesun Bioactive Materials Research Laboratory Nankai University Tianjin The Center of Materials Research Beijing Institute of Technology Beijing 《Chinese Journal of Reactive Polymers》2001,(1)
1. INTRODUCTION Bioreactors using membranes as substrates of cell cultures have become widely used for hybrid liver support systems [1]. For enhancing and prolonging the metabolism of the bioreactors, cytocompatible membranes are necessary because the cell culture is closely affected by the substrate surface. Surface factors considered to be important in cell culture are the concentration of ionic groups, the nature of polar and non-polar groups and the hydrophilic-hydrophobic balance [2].… 相似文献
144.
Min WANG You Gang MAO* Yan Ying LU Ren Fei YANG Fei LI Jia Cong SHEN Key Laboratory for Supramolecular Structure Spectroscopy of Ministry of Education Jilin University Changchun 《中国化学快报》2001,(11)
It has been known that the propagation rate coefficient (kp) will change with monomer conversion, Friss, Hamielec et al.1-5 have proposed many formulas about kp to fit this change. In order to obtain the relation between Arrhenius parameters and monomer conversion, a group of kp values at the same monomer conversion must be measured. We adopted a new method through analysis of kp values measured by usual experimental techniques for this purpose. Firstly, we chose a value of monomer convers… 相似文献
145.
Xi Rong HUANG * Yue Zhong LI Guo Liang YANG Li Li LIU Yin Bo QU Wen Juan ZHANG State Key Lab of Microbial Technology of China Shandong University Jinan Key Lab for Colloid Inferface Chemistry of the Education Ministry of Chin 《中国化学快报》2001,(5)
Lipase is one of the hydrolases. It catalyzes the hydrolysis of triglycerides, liberating fat acids. Based on its catalysis and the response of a glass electrode to the acids, a glass-electrode-based lipase sensor can be fabricated1, which has great potential in clinical medicine for the detection of blood fat in human serum samples.The immobilization of lipase on the bulb of a glass electrode is the key to the development of the sensor. In addition to its response time, which has a lot to do … 相似文献
146.
CHEN YuJin SHI XiaoLing CAO MaoSheng & ZHU ChunLing School of Materials Science Engineering Beijing Institute of Technology Beijing China Micro-Nano Technologies Research Center Hunan University Changsha College of Science Harbin Engineering University Harbin College of Material Science Chemical Engineering 《中国科学G辑(英文版)》2009,(7)
CdS/α-Fe2O3 hierarchical nanostructures, where the CdS nanorods grow irregularly on the side surface of α-Fe2O3 nanorods, were synthesized via a three-step process. The diameters and lengths of CdS nanorods can be tuned by changing the ethylenediamine (EDA) and Cd ion concentrations. The magnetic investigations by superconducting quantum interference device indicate that the hierarchical nanostructures have an Morin transition at lower temperature (230 K) than that of the single bulk α-Fe2O3 materials (263 ... 相似文献
147.
Jun Wang De-min Xu Zhong-yang Liu Yong-jun Chen Dong Wang Center for Molecular Science Institute of Chemistry Chinese Academy of Sciences Beijing China 《高分子科学》2002,(3)
A novel ligand (3), in which the indenyl group is linked to a β-diketone moiety through a three-carbon bridge, andits titanium complex (4) were synthesized. The titanium complex was employed as a metallocene analog with co-catalystmethylaluminoxane (MAO) in catalytic syndiospecific polymerization of styrene to give highly syndiotactic polystyrene(s-PS, 96%-97%). Polymerization temperature (T_p) strongly influenced the catalytic activity and syndiotacticity of theproduced PS. The activities of catalyst 4 increase from 1.84×10~6 to 3.26×10~6 gPS/molTi·h with the increase of T_p from60℃ to 80℃ and the syndiotacticities of the produced s-PS also increase slightly. Then, both the catalytic activity and thesyndiotacticity of PS decrease at T_p of 90℃. 相似文献
148.
用红外光谱法研究麦秸各层面的化学组成 总被引:20,自引:2,他引:18
本文以麦秸为例 ,用红外OMNI采样器研究了麦秸各层面红外光谱的差异 ,并进一步研究了麦草表面在不同的处理条件下 ,表面化学成分的变化规律。实验结果表明 :麦秸表面聚积着大量的SiO2 (~ 1 0 70cm- 1 ~ 80 0cm- 1 ) ,麦秸表皮层脂类物质含量高 (νCO =1 733cm- 1 )。麦秸表面的羟基 (~ 330 0cm- 1 )物质很少。麦秸的中层和内层主要是木素 ( 1 731 ,1 65 0 ,1 5 95 ,1 5 0 5 1 ,1 45 5 ,1 42 5 ,1 2 34,1 0 39和 835cm- 1 )和纤维素类物质 ( 335 0 ,2 935 ,2 85 0 ,1 65 0 ,1 45 5 ,1 430 ,1 367,1 31 7,1 1 60 ,1 0 34和 891cm- 1 )。木素的含量由外向里逐渐减少。麦秸表面的SiO2 是人造板制造中麦草不易粘接的主要原因。用热水处理后 ,表面仅有部分简单的碳水化合物和少量脂类物质溶出 ,而用NaOH处理麦草 ,可使表面的脂类物质和SiO2 溶出 ,便于人造板加工。 相似文献
149.
本文采用高温X射线衍射方法研究了含有过量TiO_2的BaTiO_3粉末在不同温度下的物相关系,并对实验结果进行了分析和讨论。 相似文献
150.
GuoQiangLI XiangLI ZhiWeiDENG HuaShiGUAN WenHanLIN 《中国化学快报》2005,16(4):494-496
Two new compounds, namely 7α, 10α-dimethyl-3β-isopropene-1, 2-ene-octahydro-naphthalene (1) and ethyl 5Z,8Z, 11Z, 14Z-nonadecatetraenoate (2) were isolated from the soft coralNephthea hainansis. Compound 1 was a pseutosesquiterpene and 2 was a polyunsaturated fattyacid ethylate. Their structures were established on the basis of spectroscopic methods. 相似文献