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31.
32.
Kalpana Sharma Rishi Pal Chahal Suman Mahendia Anil Kumar Tomar Shyam Kumar 《辐射效应与固体损伤》2013,168(5):378-384
Polyvinyl alcohol films were irradiated to 90 MeV O 6+ and 150 MeV Si 14+ ions at fluence ranging from 1010 to 1012 ions/cm2. The observed changes in optical energy gap of this polymer have been investigated and results are tried to be explained in terms of energy transferred by the incident ions. It has been noticed that the value of optical energy gap decreases with increasing energy loss during the ion–polymer interaction process. 相似文献
33.
Azide telechelics of poly(dimethylsiloxane) (PDMS), polypropylene oxide (PPO), and polyethylene oxide (PEO) were synthesized from the corresponding epoxy telechelics and characterized. These oligomeric azides were chain extended by reaction with bispropargyl ether of bisphenol A (BPEBA) through a copper‐catalyzed azide‐alkyne cycloaddition (CuAAC) reaction. PDMS manifested a faster reaction in contrast to PPO or PEO. The chain‐extended polymers underwent cross‐linking above 170°C through thermal cleavage of residual (terminal) azide groups. This was manifested in their rheograms and was further substantiated by FTIR and NMR spectroscopic analyses. Dynamic mechanical analyses of the cross‐linked polymers exhibited characteristic transitions of hard and soft segments, implying microphase separation in the system. Microscopic evaluation of the thermally cross‐linked sample revealed a porous morphology with microsized to nanosized pores. 相似文献
34.
Kenkera Rayappa Naveen Dr. Keshavananda Prabhu CP Dr. Ramanaskanda Braveenth Prof. Jang Hyuk Kwon 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(12):e202103532
Pure organic molecules based thermally activated delayed fluorescence (TADF) emitters have been successfully developed in recent years for their propitious application in highly efficient organic light emitting diodes (OLEDs). In the case of orange red emitters, the non-radiative process is known to be a serious issue due to its lower lying singlet energy level. However, recent studies indicate that there are tremendous efforts put to develop efficient orange red TADF emitters. In addition, the external quantum efficiency (EQE) of heteroaromatic based orange red TADF OLEDs surpassed 30 %. Such heteroaromatic type emitters showed wide emission spectra; therefore, more attention is being paid to develop highly efficient orange red TADF emitters along with good color purity. Herein, the recent progress of orange red TADF emitters based on molecular structures, such as cyanobenzene, heteroaromatic, naphthalimide, and boron-based acceptors, are reviewed. Further, our insight on these acceptors has been provided by their photophysical studies and device performances. Future perspectives of orange red TADF emitters for real practical applications are discussed. 相似文献
35.
Kalpana Tomar Gagandeep Kaur Sandeep Verma Gurunath Ramanathan 《Tetrahedron letters》2018,59(41):3653-3656
The tetrapeptide (Bz-Phe(p-NPh2)-l-DOPA(protected)-l-Phe-l-Phe-OMe was designed to incorporate seven phenyl rings so that it’s conformation, self-assembly and application in Hg2+ ions sensing could be studied. Peptide molecules adopted an overlapping β-turn of type III/III conformation in crystals. The peptide showed a highly selective turn-on response towards mercuric ion over other metal ions with a 10-fold enhancement in fluorescence intensity. This intensity change coupled with the selectivity of the peptide towards mercury allowed us to demonstrate simple colorimetric dip sensing of Hg2+ ions. The technique provides a highly selective and effective way to detect Hg2+ ions. The peptide also self-assembled into nanospheres with diameter ranges from 100 to 500?nm. Mercuric ion coordination enabled these peptide nanospheres to aggregate into well-defined nanoparticles. The enhanced fluorescence upon Hg2+ addition demonstrates that peptide scaffolds can be exploited in the development of different selective sensors. 相似文献
36.
RF sputtered p-type nickel oxide (NiO) thin film exhibiting tunable semiconductor character which in turns enhanced its functional properties. NiO thin film with high hole mobility is developed as a potential matrix for the realization of glucose biosensor. NiO thin film prepared under the optimized deposition conditions offer good electrical conductivity (1.5 × 10−3 Ω−1-cm−1) with high hole mobility (2.8 cm2 V−1 s−1). The bioelectrode (GOx/NiO/ITO/glass) exhibits a low value of Michaelis–Menten constant (Km = 1.05 mM), indicating high affinity of the immobilized GOx toward the analyte (glucose). Due to the high surface coverage (2.32 × 10−7 mol cm−2) of the immobilized enzyme on to the NiO matrix and its high electrocatalytic activity, the prepared biosensor exhibits a high sensitivity of 0.1 mA (mM−1-cm−2) and a good linearity from 25 to 300 mg dL−1 of glucose concentration with fast response time of 5 s. Various functional properties of the material (mobility, crystallinity and stress) are found to influence the charge communication feature of NiO thin film matrix to a great extent, resulting in enhanced sensing response characteristics. 相似文献
37.
M. S. Murali A. Bhattacharayya D. R. Raut A. S. Kar B. S. Tomar V. K. Manchanda 《Journal of Radioanalytical and Nuclear Chemistry》2012,294(1):149-153
The high level waste (HLW) generated from the reprocessing of the spent fuel of pressurized heavy water reactor has been characterized for the minor actinides. The radiation dose of the waste solution was reduced by radiochemical separation of cesium from HLW by solvent extraction with chlorinated cobalt dicarbollide dissolved in 20% nitrobenzene in xylene. Minor actinides (Np, Pu, Am, Cm) in the high level waste were assayed by alpha spectrometry following radiochemical separation. The gross alpha activity determined by liquid scintillation agrees well (within 10%) with the cumulative quantities of actinides determined by alpha spectrometry. 相似文献
38.
The theory of Tuncay and Corapcioglu (Transp Porous Media 23:237–258, 1996a) has been employed to investigate the possibility
of plane wave propagation in a fractured porous medium containing two immiscible fluids. Solid phase of the porous medium
is assumed to be linearly elastic, isotropic and the fractures are assumed to be distributed isotropically throughout the
medium. It has been shown that there can exist four compressional waves and one rotational wave. The phase speeds of these
waves are found to be affected by the presence of fractures, in general. Of the four compressional waves, one arises due to
the presence of fractures in the medium and the remaining three are those encountered by Tuncay and Corapcioglu (J Appl Mech
64:313–319, 1997). Reflection and transmission phenomena at a plane interface between a uniform elastic half-space and a fractured
porous half-space containing two immiscible fluids, are analyzed due to incidence of plane longitudinal/transverse wave from
uniform elastic half-space. Variation of modulus of amplitude and energy ratios with the angle of incidence are computed numerically
by taking the elastic half-space as granite and the fractured porous half-space as sandstone material containing non-viscous
wetting and non-wetting fluid phases. The results obtained in case of porous half-space with fractures, are compared graphically
with those in case of porous half-space without fractures. It is found that the presence of fractures in the porous half-space
do affect the reflection/transmission of waves, which is responsible for raising the reflection and lowering the transmission
coefficients. 相似文献
39.
S. Mukherjee A. Sharma S. Sodaye B.S. Tomar A. Goswami S.B. Manohar 《The European Physical Journal A - Hadrons and Nuclei》2001,12(2):199-205
Incomplete fusion reactions were investigated by measuring the excitation functions of nine evaporation residues in 16O + 51V reaction in the beam energy 4-6 MeV/amu, using the well-known recoil catcher technique and gamma-ray spectrometry. The experimental
data were compared with that obtained from Monte Carlo simulation calculations using the PACE2 code. The results indicate
the presence of incomplete fusion process in the production of two alpha emission products. This was further confirmed by
the measurement of recoil range distribution of these isotopes at 96 MeV beam energy. Calculations of the average angular
momentum associated with these products revealed the peripheral nature of these ICF reactions.
Received: 20 June 2001 / Accepted: 11 September 2001 相似文献
40.
The possibility of plane wave propagation in a micropolar fluid of infinite extent has been explored. The reflection and transmission of longitudinal elastic wave at a plane interface between a homogeneous micropolar fluid half-space and a micropolar solid half-space has also been investigated. It is found that there can exist four plane waves propagating with distinct phase speeds in an infinite micropolar fluid. All the four waves are found to be dispersive and attenuated. The reflection and transmission coefficients are found to be the functions of the angle of incidence, the elastic properties of the half-spaces and the frequency of the incident wave. The expressions of energy ratios have also been obtained in explicit form. Frequency equation for the Stoneley wave at micropolar solid/fluid interface has also been derived in the form of sixth-order determinantal expression, which is found in full agreement with the corresponding result of inviscid liquid/elastic solid interface. Numerical computations have been performed for a specific model. The dispersion curves and attenuation of the existed waves in micropolar fluid have been computed and depicted graphically. The variations of various amplitudes and energy ratios are also shown against the angle of incidence. Results of some earlier workers have been deduced from the present formulation. 相似文献