3,4-二甲基吡咯-2-甲酰肼缩PMBP的镧系(Ce、Pr、Nd)配合物的合成、结构及荧光性质

合成并通过单晶衍射表征了3个稀土配合物[LnL（NO₃）₃（H₂O）][LnL（NO₃）₃（CH₃CN）]·2CH₃CN（Ln=Ce （1）,Pr （2）,Nd （3）,L=3,4-二甲基吡咯-2-甲酰肼缩PMBP）。3个配合物同构,属于单斜晶系,P2₁/n空间群,晶胞参数分别为：1：a=1.758 83（9） nm,b= 1.460 61（8） nm,c=2.626 28（14） nm,β=97.800 0（10）°;2：a=1.756 39（15） nm,b=1.459 97（11） nm,c=2.623 1（2） nm,β=97.771（2）°;3：a=1.758 7（2） nm,b=1.463 87（17） nm,c=2.626 3（3） nm,β=97.760（2）°。每个配合物包含2个不同的中性配合物分子。配合物中每个十配位的Ln（Ⅲ）离子与来自酰腙配体L的2个氧原子和1个氮原子,3个双齿配位硝酸根及1个溶剂分子配位,采取双帽四方反棱柱配位构型。乙腈溶液中,配合物1~3具有与配体完全不同的荧光发射,可能由配位荧光增强效应导致。     

丙烯酸酯/环氧的自由基/阳离子同步光聚合混合体系的研究

科学技术的进步,对新材料的要求逐步向着多功能和高性能的方向发展,单组分材料已难于满足这种要求,在高分子材料方面,人们采用了共混、接枝、嵌段等方法以达到改善和提高性能的目的。感光性高分子是一类很重要的功能材料,至今,大部分采用自由基聚合方式制备。近年来,阳离子引发体系发展很快,特别鎓盐光引发体系受到很大的重视,发展迅速。     

对苯二甲酸二甲酯(DMT)与乙二醇(EG)的酯交换反应模拟动力学

Based on the method of ε-NTU, a mathematical modeling of ester-interchange reaction for dimethyl terephthalate (DMT) with ethylene glycol (EG) by acetate system was simulated, and, in addition, the corresponding kinetic equation is obtained by using the theoretical method of simulation. That is,-(dc)/(dt)=kc(c+k')where:-(dc)/(dt)= the reaction rate of the monomer, C -concentration of the monomer, θ-Suitable parameterk,k'-constant (k'=θ/k)The experimental results have showed that the ester-interchange reaction is a reaction neither first order or second order nor third order,but it is a reaction of secondary linear type. Yamanis^[2] doubted the correctness of the method that has been proved.Moreover,we have suggested the physical meaning of parameters.     

氰根桥连的异金属配位聚合物{[Ni(pn)2][Fe(CN)4(bipy)]}2·3H2O(pn=1,3-丙二胺,bipy=2,2′-联吡啶)的合成与结构

以[Fe(CN)₄(bipy)]^2-为建筑块和[Ni(pn)₂]²⁺在水溶液中反应,合成了{[Ni(pn)₂][Fe(CN)₄(bipy)]}₂·3H₂O(pn=1,3-丙二胺)。通过X-射线单晶衍射确定了其晶体结构。该配合物属单斜晶系,P2₁/n空间群,晶胞参数为:a     

Koszul-like algebras and modules

In this paper, the notion of Koszul-like algebra is introduced; this notion generalizes the notion of Koszul algebra and includes some Artin-Schelter regular algebras of global dimension 5 as special examples. Basic properties of Koszul-like modules are discussed. In particular, some necessary and sufficient conditions for KL(A) = L(A) are provided, where KL(A) and L(A) denote the categories of Koszul-like modules and modules with linear presentations (see [1]–[3], etc.) respectively, and A is a Koszul-like algebra. We construct new Koszul-like algebras from the known ones by the “one-point extension.” Some criteria for a graded algebra to be Koszul-like are provided. Finally, we construct many classical Koszul objects from the given Koszul-like objects.     

钩刺山羊草Aegilops triuncialis籽粒硬度主效基因的克隆与表达

根据小皮Pin a，Pin b，GSP基㈥的保守序列，设计合成了3对特异性引物，对四倍体钩刺山羊草Aegilopstriumialis的基因组DNA和胚乳RNA进行Pin a，Pin b，CSP基因扩增、克降、序列测定和表达分析，发现了两个新型Pin a等位堆因、一个新刑Pin b等化基因和一个新型GSP等位基因，基因序列均与六倍体小麦的同源基因存在较大的差异，Southern Blot分析结果表明，该材料巾含有2个拷贝Pin a。基因，5个拷贝Pin b基因，2个拷贝GSP基因．RT-PCR和Western Blot都证实了Pin a，Pin b，GSP基因在籽粒胚乳中的表达．研究结果显示由羊草可以为小麦分子育种提供有用的遗传资源。     

含剪力销(锥)螺栓法兰连接结构非线性特性

连接结构广泛应用于航空航天、化工装备和核电站等大型工业装备中。对于轴弯剪组合作用下的连接结构,需要螺栓、法兰和剪力销的联合工作以抵抗外力。本文针对含剪力销(锥)的螺栓法兰连接结构的动力学问题开展研究,将该类结构抽象为三自由度的质量-双线性弹簧系统,建立非线性动力学模型的数学列式,并进行数值求解。重点研究该系统在横向冲击(剪力)下的动力学特性。通过理论分析与数值计算,指出该非线性系统存在3个方向自由度全耦合的振动现象,并阐述该系统自由度的解耦条件;对纵向振动与横向错动的耦合振动频率关系进行讨论并分析其相互联系;研究剪力销倾角对螺栓最大轴向拉力的影响规律并给出关系曲线,指出其最佳设计角度区间。     

Bayesian networks applied to credit scoring

Email: kchang{at}gmu.eduEmail: RobertFung{at}Fairlsaac.comEmail: alan.lucas{at}hotmail.com^¶Email: BobOliver{at}Fairlsaac.com^||Email: NShikaloff{at}Fairlsaac.com The objectives of this paper are to apply the theory and numericalalgorithms of Bayesian networks to risk scoring, and comparethe results with traditional methods for computing scores andposterior predictions of performance variables. Model identification,inference, and prediction of random variables using Bayesiannetworks have been successfully applied in a number of areas,including medical diagnosis, equipment failure, informationretrieval, rare-event prediction, and pattern recognition. Theability to graphically represent conditional dependencies andindependencies among random variables may also be useful incredit scoring. Although several papers have already appearedin the literature which use graphical models for model identification,as far as we know there have been no explicit experimental resultsthat compare a traditionally computed risk score with predictionsbased on Bayesian learning algorithms. In this paper, we examine a database of credit-card applicantsand attempt to ‘learn’ the graphical structure ofthe characteristics or variables that make up the database.We identify representative Bayesian networks in a developmentsample as well as the associated Markov blankets and cliquestructures within the Markov blanket. Once we obtain the structureof the underlying conditional independencies, we are able toestimate the probabilities of each node conditional on its directpredecessor node(s). We then calculate the posterior probabilitiesand scores of a performance variable for the development sample.Finally, we calculate the receiver operating characteristic(ROC) curves and relative profitability of scorecards basedon these identifications. The results of the different modelsand methods are compared with both development and validationsamples. Finally, we report on a statistical entropy calculationthat measures the degree to which cliques identified in theBayesian network are independent of one another.     

PHOTOLUMINESCENCE STUDY ON Hg1-xCdxTe THIN FILM IMPLANTED WITH As ION

Photoluminescence spectra of a series of MBE-grown Hg_1-xCd_xTe samples with the same mole fraction of about x≈0.39 have been measured at different temperatures from 5 to 100 K. By aid of the temperature and exciting laser power dependence of photoluminescence peak energy and relative intensity, as well as of the comparison with other measurements, four main structures dominating in the photoluminescence spectra are attributed to band to band, D^oX, A^oX and D^oA^o transitions. A deep donor state level located at about 8.5meV below the bottom of the conduction band has been observed and is determined to be due to the arsenic-occupied mercury vacancies. Two acceptor levels located at about 14.5 meV and about 31.5 meV above the top of the valance band have also been found from the measuements, which are identified as the mercury vacancies and As in anion site, respectively.     

QCD Correction to σ(e+e-→ZH→Zbb)

We study the QCD corrections to the calculated values of σ(e⁺e^-→ZH→Zbb), and find that for M_H<100 GeV, the process can be measured at the LEP energy to extract information of Higgs and the QCD corrections are negligible, namely the tree-level calculation is sufficiently aciurate for the energy range, while for M_H > 100 GeV, the Higgs-involved subprocess can only be investigated at NLC, and then the QCD correction becomes as large as 45%. For M_H > 2mt, considering the subprocess e⁺e^-→ZH→Ztt, the QCD corrections are also important and must be taken into account for the cross section evaluation.