全文获取类型
收费全文 | 494篇 |
免费 | 8篇 |
国内免费 | 5篇 |
专业分类
化学 | 278篇 |
晶体学 | 5篇 |
力学 | 12篇 |
数学 | 77篇 |
物理学 | 135篇 |
出版年
2023年 | 4篇 |
2020年 | 6篇 |
2019年 | 9篇 |
2018年 | 5篇 |
2017年 | 4篇 |
2016年 | 7篇 |
2015年 | 5篇 |
2014年 | 7篇 |
2013年 | 27篇 |
2012年 | 11篇 |
2011年 | 22篇 |
2010年 | 21篇 |
2009年 | 13篇 |
2008年 | 17篇 |
2007年 | 30篇 |
2006年 | 11篇 |
2005年 | 17篇 |
2004年 | 8篇 |
2003年 | 8篇 |
2002年 | 11篇 |
2001年 | 18篇 |
2000年 | 10篇 |
1999年 | 9篇 |
1998年 | 11篇 |
1997年 | 4篇 |
1996年 | 7篇 |
1994年 | 10篇 |
1993年 | 12篇 |
1992年 | 13篇 |
1991年 | 4篇 |
1990年 | 15篇 |
1989年 | 7篇 |
1988年 | 11篇 |
1987年 | 8篇 |
1986年 | 8篇 |
1985年 | 14篇 |
1984年 | 9篇 |
1982年 | 4篇 |
1981年 | 10篇 |
1980年 | 8篇 |
1979年 | 6篇 |
1978年 | 5篇 |
1977年 | 3篇 |
1976年 | 6篇 |
1975年 | 6篇 |
1974年 | 4篇 |
1972年 | 4篇 |
1970年 | 4篇 |
1969年 | 3篇 |
1956年 | 3篇 |
排序方式: 共有507条查询结果,搜索用时 92 毫秒
31.
TDPAC experiments on181Ta in various inorganic materials have been performed by using BaF2 crystals as fast -ray scintillators. The use of such sintillators allows reaching a time resolution as low as 600 ps with both high detection efficiency and good energy resolution. 相似文献
32.
S. A. E. Boyer J-P. E. Grolier L. Pison C. Iwamoto H. Yoshida T. Iyoda 《Journal of Thermal Analysis and Calorimetry》2006,85(3):699-706
The
present work deals with the interactions between carbon dioxide, used as pressure
medium, either in the gas state (GCO2) or in the supercritical
state (SCCO2) and amphiphilic di-block copolymers PEOm-b-PMA(Az)n. The effect of
pressure on the isotropic transition of the PEOm-b-PMA(Az)n copolymer was investigated
using scanning transitiometry (ST). The experimental results were compared
with those measured when using ‘relatively inert’ mercury (Hg)
as pressure medium. Morphological observation of a PEOm-b-PMA(Az)n thin film submitted
to SCCO2 was performed by atomic force microscopy (AFM)
to investigate the nano-structure organization. These results indicate the
possibility of modifying the nano-structure in a specific way depending on
the CO2 physical state. 相似文献
33.
Jeffrey S. Boyer 《The Journal of chemical thermodynamics》2003,35(12):1917-1928
The standard molar heat capacity C°p,m of adenine(cr) has been measured using adiabatic calorimetry over the range 6<(T/K)<310 and the results used to derive thermodynamic functions for adenine(cr) at smoothed temperatures. At T=298.15 K, C°p,m=(142.67±0.29) J · K−1 · mol−1 and the third law entropy S°m=(145.62±0.29) J · K−1 · mol−1. The standard molar Gibbs free energy of formation ΔfG°m at T=298.15 K for crystalline adenine was calculated, using the standard molar enthalpy of formation for the compound and entropies of the elements from the literature, and found to be ΔfG°m=(301.4±1.0) kJ · mol−1. The results were combined with solution calorimetry and solubility measurements from the literature to yield revised values for the standard molar thermodynamic properties of aqueous adenine at T=298.15 K: ΔfG°m=(313.4±1.0) kJ · mol−1, ΔfH°m=(129.5±1.4) kJ · mol−1, and Sm°=(217.68±0.44) J · K−1 · mol−1. 相似文献
34.
35.
36.
Raymond F. Boyer 《高分子科学杂志,A辑:纯化学与应用化学》2013,50(7):1411-1434
A formal history of styrene and polystyrene from 1839 through 1952 appears in the Styrene monograph edited by Boundy and writer but now out of print. Updating of the story by several teams of Dow writers appeared in the Kirk-Othmer Encyclopedia, the Encyclopedia of Polymer Science and Technology, and the SPE Award address of Amos. We propose a more personalized history written from the perspective of one whose 40-year professional career was involved in scientific and technological aspects of the subject. We view this history as a complex interplay of science, technology, industrial activity, management decisions, legal and patent activities, people, and the vagaries of World War II. Germany had an early industrial lead prior to 1941 with a monomer process and mass polymerization techniques. Original work on styrene-butadiene elastomers was another first. Germany also had a scientific lead as academic scientists such as Staudinger, Kern, Schulz, Jenckel, and Ueberreiter became involved in the chemistry and physics of styrene and polystyrene (PS). Mark was first in industry and then in the university. Several United States companies were active with styrene and PS, also prior to 1941. Involvement of the United States in World War II lead to a government decision to produce SBR. This catapulted styrene into a major synthetic chemical. The lead passed from Germany to the United States, especially with the large excess capacity for monomer after 1945. Management decisions encouraged diverse large-scale polymer uses for styrene, aided by the low price for the monomer. Through a bizarre series of events (war, people, and legal action), proprietary industrial knowledge in both Germany and the United States had diffused into the domain of public knowledge. Styrene and PS now face the problems of any petrochemical product. 相似文献
37.
A Beckmann Rearrangement/Friedel-Crafts strategy was utilized to prepare 5-amidotetralones in high yield. 相似文献
38.
Aïcha Mbarek Geneviève Chadeyron Daniel Avignant Damien Boyer Mohieddine Fourati Daniel Zambon 《Journal of Sol-Gel Science and Technology》2013,68(2):193-203
The sol–gel chemistry route has successfully been used to prepare samples of LnP5O14 (Ln = La, Gd) pentaphosphates from lanthanides chlorides and phosphorous pentoxide dissolved in isopropanol. Crystallized powders of single phase were obtained after calcination of gels at 350 °C. The structural characterizations of materials were investigated by means of X-ray diffraction as well as infrared and Raman spectroscopies, whereas their thermal behavior has been studied by differential thermal analyse and thermogravimetric analyses. Powders morphology was analyzed by means of scanning electron microscopy and laser granulometry. The photoluminescence properties of the Eu3+ ions in sol–gel derived LaP5O14 and GdP5O14 samples were investigated and compared with homologous samples synthesized by the conventional solid state reaction. 相似文献
39.
Zilong Wu Kenward Jung Cyrille Boyer 《Angewandte Chemie (International ed. in English)》2020,59(5):2013-2017
This contribution details an efficient and controlled photopolymerization regulated by far‐red (λ=680 nm) and NIR (λ=780 and 850 nm) light in the presence of aluminium phthalocyanine and aluminium naphthalocyanine. Initiating radicals are generated by photosensitization of peroxides affording an effective strategy that provides controlled polymerization of a variety of monomers with excellent living characteristics. Critically, long wavelength irradiation provides penetration through thick barriers, affording unprecedented rates of controlled polymerization that can open new and exciting applications. Furthermore, a more optimized approach to performing solar syntheses is presented. By combining the narrow Q‐bands of these photocatalysts with others possessing complementary absorptions, layered, independent polymerizations and organic transformations may be performed in parallel under a single broadband emission source, such as sunlight. 相似文献
40.