Sintering behaviour of the spinel ferrite system Ni0.65Zn0.35Fe2−xCuxO4

A series of samples of the system Ni_0.65Zn_0.35CuxFe_2–xO₄ (x=0, 0.1, 0.2, 0.3, 0.4, 0.5 and 0.6) are prepared by the usual ceramic technique. X-ray analysis shows that they are cubic spinel (single phase). The lattice parameter, theoretical density (D _x), bulk density (D) and the porosity (P) are measured for the samples. The vacancy concentration of oxygen is an important parameter in the sintering process of spinel ferrites. The decrease in the population of Fe³⁺ ion in the octahedral sites with the introduction of Cu²⁺ results in the decrease of lattice parameter. The DTA tracing shows a strong exothermic peak at 90°C.

---

Zusammenfassung Mittels herkömmlicher keramikchemischer Verfahren wurde eine Reihe von Proben des Systemes Ni_0.65Zn_0.35Cu_xFe_2–xO₄ (x=0, 0.1, 0.2, 0.3, 0.4, 0.5 und 0.6) hergestellt. Röntgendiffraktionsanalyse zeigt kubisches Spinell (eine Phase). Es wurden die Gitterkonstanten, die theoretische DichteDx, die RaumdichteD und die PorositätP dieser Proben gemessen. Die Gitterleerstellenkonzentration von Sauerstoff ist ein wichtiger Parameter beim Sintern von Spinellferriten. Die Abnahme der Besetzung mit Fe³⁺-Ionen bei der Einbringung von Cu²⁺ führt zu kleineren Gitterkonstanten. DTA-Kurven zeigen einen starken exothermen Peak bei 90°C.

---

---

The measurements were carried out at the Solid-state Physics Laboratory, Faculty of Science, Tanta University.

---

The authors are grateful to the technical assistance of the Central Laboratory of Tanta and Manoufia University for X-ray and DTA facilities.     

The brightness distribution of the sum of two correlated speckle patterns

The probability density function of the sum of two correlated (partially coherent) speckle patterns is investigated.     

Single exposure photography applied to a slow flow field

A speckle photography technique has been applied to measuring the velocity profiles of laminar and turbulent flow through pipes of circular cross-section. A single exposure photography technique has been used to visualize slow fluid flow. The fluids used were seeded with tracer particles whose size range from 20 to about 120 μm in diameter. A mathematical expression representing the recorded intensity is presented. A single exposure with a long exposure time was taken on a holographic film material. The recorded intensity was represented by the convolution product of the image formed and a rectangular function representing a one-dimensional continuous motion. The analysis shows that the intensity distribution of the Fourier spectrum of the diffracted image follows a sinc² function on a noise background representing the scattered light of the tracer particles.     

Intensity correlations in the presence of additive background noise

The mean value of the intensity correlation function and intensity spectrum of a bar object are evaluated when a spatialy random intensity is added to the deterministic object. The mean value of both functions depends upon two terms in addition to the usual term involving the deterministic object, one involves the mean and the other involves the covariance of the random background intensity.     

1,1'-(3-methyl-4-phenylthieno[2,3-b]thiophene-2,5-diyl)diethanone as a building block in heterocyclic synthesis. Novel synthesis of some pyrazole and pyrimidine derivatives

A series of new bis(heterocycles) featuring thieno[2,3-b]thiophene rings was synthesized in a combinatorial manner. Intramolecular cyclization of enaminone derivatives with appropriate N-nucleophiles afforded the target compounds. All compounds were characterized by 1H-, 13C-NMR, GCMS, IR, and UV-Vis spectrometry. These compounds represent a new class of sulfur- and nitrogen-containing heterocycles that should also be of interest as new materials.     

Characterizing Serre Quotients with no Section Functor and Applications to Coherent Sheaves

We prove an analogon of the the fundamental homomorphism theorem for certain classes of exact and essentially surjective functors of Abelian categories $\mathcal{Q}:\mathcal{A} \to \mathcal{B}$ . It states that $\mathcal{Q}$ is up to equivalence the Serre quotient $\mathcal{A} \to \mathcal{A} / \ker \mathcal{Q}$ , even in cases when the latter does not admit a section functor. For several classes of schemes X, including projective and toric varieties, this characterization applies to the sheafification functor from a certain category $\mathcal{A}$ of finitely presented graded modules to the category $\mathcal{B}=\mathfrak{Coh}\, X$ of coherent sheaves on X. This gives a direct proof that $\mathfrak{Coh}\, X$ is a Serre quotient of $\mathcal{A}$ .     

ICP-AES分析光谱条件对中药蒲公英无机元素吸收的影响

在全密闭植物工厂中水培种植中药蒲公英,以发射不同波段光谱的荧光灯及LED灯作为药材生长光源,并结合ICP–AES技术分析了不同光谱条件对蒲公英无机元素吸收和积累的影响。结果表明:(1)相近的光合有效辐射(PAR)条件下,单一红光R及混合光FLRB有利于水培蒲公英可食生物量的积累,单一蓝光B处理下可食生物量最低;(2)荧光灯FL条件下蒲公英地上部分常量无机元素含量比值为K∶Ca∶P∶Mg∶Na=79.74∶32.39∶24.32∶10.55∶1.00,微量无机元素含量比值为Fe∶Mn∶B∶Zn∶Cu=9.28∶9.71∶3.82∶2.08∶1.00;(3)峰值为660nm的红光有利于蒲公英对Ca,Fe,Mn,Zn元素的吸收,Cu元素含量受光谱条件的影响不明显;(4)蒲公英地上部分对Ca,Na,Mn,Zn四种元素的积累量均在纯红光R下最高,而对其余六种元素的积累量以混合光FLRB条件下最高。     

Gamma induced changes in Makrofol/CdSe nanocomposite films

We applied an ex-situ casting procedure to prepare a nanocomposite (NCP) from Makrofol polycarbonate (PC) and CdSe nanoparticles. The CdSe nanoparticles were prepared by a thermolysis procedure in the presence of N₂ gas flow. Rietveld refinement of x-ray data illustrated that the CdSe adopts a cubic zinc blend structure of 6.057 Å lattice parameter and 2 nm typical grain size. Samples from the prepared NCP were exposed to γ dosages (20 kGy-250 kGy). The modifications induced in the NCP films owing to γ dosages have been studied. The γ irradiation (50 kGy-250 kGy) causes crosslinks that reduce the optical bandgap from 4.15 eV to 3.81 eV, associated with an increase in dielectric parameters and refractive index. This is attributed to an increase in the mass fraction of the disordered regions as specified by x-ray diffraction. The PC-CdSe NCP was found to have a reaction to color modification which makes it suitable for saleable reproduction on a printing press.     

Polymerization of glycolide promoted by ω-Al-alkoxide poly(ϵ-caprolactone) macro-initiators and formation of stable colloidal dispersions

Block polymerization of glycolide (GA) and ϵ-caprolactone (ϵ-CL) has been initiated with aluminum alkoxides, such as Al(OⁱPr)₃ and Et₂AlOCH₂X (where X = -CH₂-Br and -CH₂O-C(O)-C(Me)=CH₂), in THF at 40°C. Structure and composition of block copolyesters have been characterized with respect to the molecular weight by NMR spectroscopy and thermal analysis. Copolymerization is typically living, so that block copolyesters have been synthesized with predictable molecular weight and composition. The inherent insolubility of polyglycolide block is responsible for the heterogeneity of the polymerization medium and formation of stable, non-aqueous colloidal dispersions. This effect is especially pronounced at high GA/ϵ-CL molar ratios. Colloidal dispersions have been analyzed by transmission electron microscopy (TEM) and photocorrelation spectroscopy (PCS).