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111.
112.
113.
114.
We consider equilibrium configurations ofn identical particles in three dimensions interacting via two-body potentials depending only on the distance. The symmetry group of a given configuration is defined as the subgroup of isometries which leaves it invariant, up to permutations of the particles. We prove the stability of the symmetry in the following sense: the symmetry group of an equilibrium configuration is the same for the neighboring equilibria arising from any small enough perturbation of the initial potential. Furthermore, for a large class of realistic potentials, the existence of nontrivial symmetries is proved, thus giving a completely geometrical, although partial, approach to the classical crystal problem. 相似文献
115.
Moshe Katz 《Israel Journal of Mathematics》1971,9(1):53-72
Let ℬ(m) be the set of all then-square (0–1) matrices containingm ones andn
2−m zeros, 0<m<n
2. The problem of finding the maximum ofs(A
2) over this set, wheres(A
2) is the sum of the entries ofA
2,A ∈ ℬ (m) is considered. This problem is solved in the particular casesm=n
2 −k
2 andm=k
2,k
2>(n
2/2).
This paper forms part of a thesis in partial fulfillment of the requirements for the degree of Doctor of Science at the Technion-Israel
Institute of Technology. The author wishes to thank Professor B. Schwarz and Dr. D. London for their help in the preparation
of this paper. 相似文献
116.
117.
We have derived a precise thermodynamic definition of the standard free energy to form a cluster which is used in nucleation theory. The results [Eq. (9)] have a form differing slightly from the form usually used in nucleation theory and show that the Lothe-Pound correction factor is based on a misconception concerning the standard states involved. 相似文献
118.
119.
Two different compounds were simultaneously adsorbed on a silver colloid, and Raman spectra were taken. One, which does not fulfil the resonance condition (in solution), showed the usual large (SERS) enhancement. The other compound, which (in solution) absorbs the light used, showed no net enhancement compared to the first. The extent of surface electric field amplification is discussed. 相似文献
120.
We investigate theoretically and via computer simulation the stationary nonequilibrium states of a stochastic lattice gas under the influence of a uniform external fieldE. The effect of the field is to bias jumps in the field direction and thus produce a current carrying steady state. Simulations on a periodic 30 × 30 square lattice with attractive nearest-neighbor interactions suggest a nonequilibrium phase transition from a disordered phase to an ordered one, similar to the para-to-ferromagnetic transition in equilibriumE=0. At low temperatures and largeE the system segregates into two phases with an interface oriented parallel to the field. The critical temperature is larger than the equilibrium Onsager value atE=0 and increases with the field. For repulsive interactions the usual equilibrium phase transition (ordering on sublattices) is suppressed. We report on conductivity, bulk diffusivity, structure function, etc. in the steady state over a wide range of temperature and electric field. We also present rigorous proofs of the Kubo formula for bulk diffusivity and electrical conductivity and show the positivity of the entropy production for a general class of stochastic lattice gases in a uniform electric field.Supported in part by National Science Foundation Grant DMR81-14726 and NATO Grant 040.82.Work supported in part by a Lafayette College Junior Faculty Leave Grant.Work supported in part by a Heisenberg fellowship of the Deutsche Forschungsgemeinschaft. 相似文献