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101.
Various empirical theories of ultrasonic velocity have been applied to three binary liquid mixtures, under pressures up to
200 MPa and their validity have been tested. A pressure dependent study of ultrasonic velocities has been made at 303.15 K.
The agreement between theory and experiment is found to be quite satisfactory. 相似文献
102.
Ibon Alkorta Fernando Blanco Pere M. Deyà José Elguero Carolina Estarellas Antonio Frontera David Quiñonero 《Theoretical chemistry accounts》2010,126(1-2):1-14
This review covers two aspects concerning cooperativity in multiple weak bonds: a summary of literature results and a theoretical study of a complete series of model complexes. All the 15 combination of five weak bonds were explored: hydrogen bonds, hydric bonds, dihydrogen bonds, halogen bonds and ion–π interactions. Since in several cases there were no examples reported, a systematic exploration has been carried out on simple models at the MP2/aug-cc-pVTZ level. The results thus obtained have been analyzed using the atoms in molecules methodology. 相似文献
103.
We have studied the analytic solutions for modified electron acoustic double layers and solitary waves in a four component plasma system viz. two electrons and two ions, one positive and the other negative. It has been shown that DL solution does not exist when the temperatures of the free and the trapped particles are considered to be same for all the free species. On the other hand, DL solutions are found to exist when the effects of the reflected electrons (hot) are considered. The velocity and thickness of the DL have been valculated. 相似文献
104.
Sanjay Jadhav Gajanan Rashinkar Rajashri Salunkhe Arjun Kumbhar 《Tetrahedron letters》2017,58(33):3201-3204
A simple, efficient and metal-free route for the synthesis of dissymmetric ketones through Suzuki type cross-coupling reaction has been established. This strategy signifies an attractive, cost-effective and operationally convenient tool for the synthesis of a wide range of dissymmetric ketones. Although conventional routes for the synthesis of ketones have been widely used, the potential challenge with these methods is functional group tolerance. The reported metal-free method represents a reaction with moderate functional group tolerance. The procedure is operationally convenient and shows broad substrate scope with good to excellent product yields. 相似文献
105.
106.
Background
Triptolide is a diterpene triepoxide from the Chinese medicinal plant Tripterygium wilfordii Hook F., with known anti-inflammatory, immunosuppressive and anti-cancer properties. 相似文献107.
S. Dey J. P. Gewali A. K. Jha L. Chhaigte Y. S. Jain 《Indian Journal of Physics》2011,85(8):1309-1330
High resolution spectroscopy of doped molecules in 4He nano-droplets and clusters gives a signature of superfluidity in microscopic system, termed as microscopic superfluidity. Ro-vibrational spectrum of 4HeN-M clusters is studied with the help of some important observations, revealed from experiments (viz., localised and orderly arrangement of 4He atoms, although, being free to move in the order of their locations; individual 4He atoms can not be tagged as normal/ superfluid, etc.) and other factors (e.g., consideration that the 4He atoms which happen to fall in the plane of rotation of a molecule, render a equipotential ring and thus, do not take part
in rotation; etc.) which effect the rotational and vibrational spectrum of the system. This helps us in successfully explaining the experimental
findings which state that the rotational spectrum of clusters have sharp peaks (indicating that the molecule rotates like
a free rotor) and moment of inertia and vibrational frequency shift have a non-trivial dependence on N. 相似文献
108.
S.C. Dey 《Journal of luminescence》2011,131(12):2707-424
The article reports a green chemical synthesis of colloidal ZnSe quantum dots at a moderate temperature. The prepared colloid sample is characterised by UV-vis absorption spectroscopy and transmission electron microscopy. UV-vis spectroscopy reveals as-expected blue-shift with strong absorption edge at 400 nm and micrographs show a non-uniform size distribution of ZnSe quantum dots in the range 1-4 nm. Further, photoluminescence and electroluminescence spectroscopies are carried out to study optical emission. Each of the spectroscopies reveals two emission peaks, indicating band-to-band transition and defect related transition. From the luminescence studies, it can be inferred that the recombination of electrons and holes resulting from interband transition causes violet emission and the recombination of a photon generated hole with a charged state of Zn-vacancy gives blue emission. Meanwhile electroluminescence study suggests the application of ZnSe quantum dots as an efficient light emitting device with the advantage of colour tuning (violet-blue-violet). 相似文献
109.
A. Delfino Jishnu Dey Mira Dey M. Malheiro 《The European Physical Journal C - Particles and Fields》2011,71(1):507-514
The models of translationally invariant infinite nuclear matter in the relativistic mean field models are very interesting and simple, since the nucleon can connect only to a constant vector and scalar meson field. Can one connect these to the complicated phase transitions of QCD? For an affirmative answer to this question, one must consider models where the coupling contstants to the scalar and vector fields depend on density in a nonlinear way, since as such the models are not explicitly chirally invariant. Once this is ensured, indeed one can derive a quark condensate indirectly from the energy density of nuclear matter which goes to zero at large density and temperature. The change to zero condensate indicates a smooth phase transition. 相似文献
110.
We study different correlation functions for a spin imbalanced and harmonically trapped Fermi gas in two dimensions described by an attractive Hubbard model. Eigensolutions obtained via numerically solving Bogoliubov de Gennes equations are used to compute the local pairing amplitudes which show significantly different behaviour for the trapped case where the profile is radially modulated in contrast with a spatial modulation extending throughout the lattice geometry when trap effects are switched off. Further, different experimentally accessible quantities, such as pair–pair, density–density correlations and local density fluctuations show characteristic fluctuations for the spin polarized phase, which however wash away as the trapping effects are turned on. A contrasting scenario is presented corresponding to the case when the spin polarization effects are turned off. 相似文献