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91.
Gakhyun Kim Dr. Ranjan Dutta Dr. Won-Young Cha Dr. Seong-Jin Hong Dr. Juwon Oh Dr. Dikhi Firmansyah Hongil Jo Prof. Dr. Kang Min Ok Prof. Dr. Chang-Hee Lee Prof. Dr. Dongho Kim 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(69):16434-16440
π–π Stacking is omnipresent not only in nature but in a wide variety of practical fields applied to our lives. Because of its importance in a performance of natural and artificial systems, such as light harvesting system and working layer in device, many researchers have put intensive effort into identifying its underlying nature. However, for the case of π–π stacked systems composed of antiaromatic units, the understanding of the fundamental mechanisms is still unclear. Herein, we synthesized a new type of planar β,β’-phenylene-bridged hexaphyrin (1.0.1.0.1.0), referred as naphthorosarin which possesses the 24π-electron conjugated pathway. Especially, the corresponding antiaromatic porphyrinoid shows the unique property to form dimeric species adopting the face-to-face geometry which is unprecedented in cases of known annulated naphthorosarins. In order to elucidate the intriguing properties derived from the stacked dimer, the current study focuses on the experimental support to rationalize the observed π–π interactions between the two subunits. 相似文献
92.
Thanh-Hai Le Yuree Oh Prof. Hyungwoo Kim Prof. Hyeonseok Yoon 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(29):6360-6401
The fascinating properties of single-layer graphene isolated by mechanical exfoliation have inspired extensive research efforts toward two-dimensional (2D) materials. Layered compounds serve as precursors for atomically thin 2D materials (briefly, 2D nanomaterials) owing to their strong intraplane chemical bonding but weak interplane van der Waals interactions. There are newly emerging 2D materials beyond graphene, and it is becoming increasingly important to develop cost-effective, scalable methods for producing 2D nanomaterials with controlled microstructures and properties. The variety of developed synthetic techniques can be categorized into two classes: bottom-up and top-down approaches. Of top-down approaches, the exfoliation of bulk 2D materials into single or few layers is the most common. This review highlights chemical and physical exfoliation methods that allow for the production of 2D nanomaterials in large quantities. In addition, remarkable examples of utilizing exfoliated 2D nanomaterials in energy and environmental applications are introduced. 相似文献
93.
In this paper we study a double phase problem with an irregular obstacle. The energy functional under consideration is characterized by the fact that both ellipticity and growth switch between a type of polynomial and a type of logarithm, which can be regarded as a borderline case of the double phase functional with -growth. We obtain an optimal global Calderón–Zygmund type estimate for the obstacle problem with double phase in the borderline case. 相似文献
94.
Armen H. Poghosyan Levon H. Arsenyan Aram A. Shahinyan 《Colloid and polymer science》2014,292(12):3147-3156
In this study, we investigate micelle fission of long-chain alkyl sulfonate molecules using atomistic scale simulation. GROMACS software code with the united atom force field was applied. 0.5-μs parallel molecular dynamics simulation study was conducted for a surfactant/water system consisting of 192 sodium pentadecyl sulfonate and 40,553 water molecules. The large preassembled micelle was ruptured at Krafft above T?=?323-K temperature, and we track two ellipsoid-like micelles over the course of the production run. To estimate the micelle shape, we determined the principal moments of inertia and the eccentricity, which proved that the micelles have a pronounced prolate spheroid shape, which agrees well with our previous experimental data. The mechanism of micelle fission was explored in detail. The aggregation number, ionization degree, and other parameters obtained from simulation were consistent with existing experimental finding. The determined parameters in addition to simple visual inspection of trajectories revealed monomer-micelle exchange—with the estimated relaxation time τ 1?=?10??9s. We assume that the exchange process is conditioned by the unequal size of micelles leading to adjustment of aggregation number. 相似文献
95.
Chang-Ho Kang Sang-Hyun Han YuJin Shin Soo Ji Oh Jae-Seong So 《Applied biochemistry and biotechnology》2014,172(6):2907-2915
Contamination by Cd is a significant environmental problem. Therefore, we examined Cd removal from an environmental perspective. Ureolysis-driven calcium carbonate precipitation has been proposed for use in geotechnical engineering for soil remediation applications. In this study, 55 calcite-forming bacterial strains were newly isolated from various environments. Biomineralization of Cd by calcite-forming bacteria was investigated in laboratory-scale experiments. A simple method was developed to determine the effectiveness of microbially induced calcite precipitation (MICP). Using this method, we determined the effectiveness of biomineralization for retarding the flow of crystal violet through a 25-mL column. When the selected bacteria were analyzed using an inductively coupled plasma optical emission spectrometer, high removal rates (99.95 %) of Cd were observed following incubation for 48 h. Samples of solids that formed in the reaction vessels were examined using a scanning electron microscope. The CdCO3 compounds primarily showed a spherical shape. The results of this study demonstrate that MICP-based sequestration of soluble heavy metals via coprecipitation with calcite may be useful for toxic heavy metal bioremediation. 相似文献
96.
Oh Maengkyo Lee Keunyoung Kim Kwang-Wook Foster Richard I. Lee Chang-Ha 《Journal of Radioanalytical and Nuclear Chemistry》2022,331(6):2495-2501
Journal of Radioanalytical and Nuclear Chemistry - Applicability of uranium peroxide ((UO2)(O2)·4H2O; UO4) precipitation to remove uranium from secondary wastewaters, generated as part of a... 相似文献
97.
Jongmin Park Dr. Sangmi Oh Prof. Seung Bum Park 《Angewandte Chemie (International ed. in English)》2012,51(22):5259-5259
98.
Dr. Anthony J. Kim Dr. Nicholas J. Boylan Dr. Jung Soo Suk Minyoung Hwangbo Tao Yu Benjamin S. Schuster Dr. Liudimila Cebotaru Dr. Wojciech G. Lesniak Joon Seok Oh Pichet Adstamongkonkul Ashley Y. Choi Prof. Dr. Rangaramanujam M. Kannan Prof. Dr. Justin Hanes 《Angewandte Chemie (International ed. in English)》2013,52(14):3985-3988
99.
Elin Julianti Hana Oh Hyi-Seung Lee Dong-Chan Oh Ki-Bong Oh Jongheon Shin 《Tetrahedron letters》2012,53(23):2885-2886
Acremolin (1), a novel modified base, was isolated from the culture broth of the marine fungus Acremonium strictum. Based on combined spectroscopic analyses, the structure of this compound was that of a methyl guanine base containing an isoprene unit. In addition, the presence of a 1H-azirine moiety is unprecedented among natural products. This compound exhibited weak cytotoxicity against an A549 cell line. 相似文献
100.