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651.
Nine new fluorine containing 5-amino-1,3-disubstituted pyrazoles have been synthesized and characterized by spectral studies. Condensation reactions of these 5-amino-1,3-disubstituted pyrazoles with fluorinated 1,3-diketones in the presence of glacial acetic acid have been studied and the structures of the resulting 1H-pyrazolo[3,4-b]pyridines have been confirmed by ir, pmr and 19F nmr spectral studies.  相似文献   
652.
Sorption of NpO2 + on silicate (10.00 g/l) particles dispersed in sodium perchlorate media was studied as a function of pcH and ionic strength at 298 K. The sorption increased with increased pcH in the range of ∼6.5 to 9.2, above which saturation was observed. An increase in ionic strength from 0.20M to 1.00M (NaClO4), increased the NpO2 + sorption, which then decreased at 1.50M (NaClO4) for 7<pcH<8.5. The effects of different types of ligands on the sorption of NpO2 + to suspended silicate were investigated. The types of ligands included: (i) inorganic anions (fluoride, carbonate, phosphate (ii) N-donors (ethylenediamine, 1,10 phenanthroline (iii) carboxylic acids (oxalic acid, citric acid, iminodiacetic acid, ethylenediaminetetraacetic acid) and (iv) humic acid. A synergistic enhancement in sorption to the suspended silicate was observed for phosphate, oxalate, ethylenediaminetetraacetic acid, ethylenediamine, 1,10 phenanthroline (5<pcH<8) and humic acid (6.5<pcH<8.8). This behavior was attributed to the formation of ternary NpO2 +/silicate/ligand complexes. The effects of Ca(II) (1.00·10−3M) and Eu(III) (1.00·10−4 and 1.00·10−3M) ions on NpO2 + sorption to suspended silicate were also investigated. On leave from Radiochemistry Division, Bhabha Atomic Research Centre, Trombay, Mumbai-400 085, India.  相似文献   
653.
A coupled methodology for simulating the simultaneous growth and motion of equiaxed dendrites in solidifying melts is presented. The model uses the volume-averaging principles and combines the features of the enthalpy method for modeling growth, immersed boundary method for handling the rigid solid–liquid interfaces, and the volume of fluid method for tracking the advection of the dendrite. The algorithm also performs explicit–implicit coupling between the techniques used. A two-dimensional framework with incompressible and Newtonian fluid is considered. Validation with available literature is performed and dendrite growth in the presence of rotational and buoyancy driven flow fields is studied. It is seen that the flow fields significantly alter the position and morphology of the dendrites.  相似文献   
654.
Recently Yang et al. (Int. J. Theor. Phys. 48:516, 2009) have shown that an unknown qubit can be teleported by using a particular GHZ-like state as quantum channel. However, there are several errors in the calculation which lead to incorrect conclusions. The errors have been indicated and corrected. It is also noted that their scheme and the independently proposed teleportation scheme of Zhang et al. (Int. J. Theor. Phys. 48:3331, 2009) uses quantum channel from the same family and any state of that family may be used for teleportation.  相似文献   
655.
656.
By exploiting recent advances in the understanding of both pheromone biosynthesis pathways and the detection of molecules in the insect nervous system, we are developing a new class of technology for biosynthetic infochemical communication. Here we present a prototype instrument that comprises an integrated chemotransmitter, an odour pathway and a chemoreceiver controlled by a laptop computer. Our initial studies show that the system can transmit, receive and decode a set of volatiles commonly found in fruits. The system is capable of ratiometrically encoding information by releasing complex blends of compounds in specific ratios, detecting the transmitted blends with a sensor array and decoding the infochemical information using neuromorphic algorithms representing ratio processing in the macroglomerular complex (MGC) of the antennal lobe of the moth (e.g. Manduca sexta).  相似文献   
657.
Dielectrics, polarizing optical microscopic and electro-optical measurements have been carried out on a core/shell quantum dot Cd1?xZnxS/ZnS dispersed ferroelectric liquid crystal (FLC). In the present study, quantum dots were dispersed into two different concentrations of 0.1 and 0.25 wt./wt.% in pure FLC. The electro-optical parameters of pure and QDs dispersed FLC were carried out as a function of applied voltage. A significant improvement in optical response time of QDs dispersed FLC system is one of the major finding of the present study which may be useful for fabrication of faster liquid crystal system.  相似文献   
658.
The activities of the working group took place under two broad subgroups: Collider Physics subgroup and Flavour Physics subgroup. Reports on some of the projects undertaken are included. Also, some of the leading discussions organized by the working group are summarized.   相似文献   
659.
A new mechanism is proposed to explain the origin of negative differential resistance (NDR) in a strongly coupled single molecule-metal junction. A first-principles quantum transport calculation in a Fe-terpyridine linker molecule sandwiched between a pair of gold electrodes is presented. Upon increasing the applied bias, it is found that a new phase in the broken symmetry wave function of the molecule emerges from the mixing of occupied and unoccupied molecular orbitals. As a consequence, a nonlinear change in the coupling between the molecule and the lead is evolved resulting in NDR. This model can be used to explain NDR in other classes of metal-molecule junction devices.  相似文献   
660.
Intrinsic curvature of biopolymers is emerging as an essential feature in various biological phenomena. Examples of polymers with intrinsic curvature are microtubule in eukaryotic cells or FtsZ filaments in prokaryotic cells. We consider the general model for polymers with intrinsic curvature. We aim to study both equilibrium and dynamic properties of such polymers. Here we report preliminary results on the equilibrium distribution function P(R) of the end-to-end distance R. We employ transfer matrix method for this study.   相似文献   
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