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排序方式: 共有720条查询结果,搜索用时 453 毫秒
41.
Pathak Madhvesh Bohra Rakesh Mehrotra Ram C. Lorenz Ingo-Peter Piotrowski Holger 《Transition Metal Chemistry》2003,28(2):187-192
Reactions of cis-dialkoxy-bis(acetylacetonato)titanium(IV), [(acac)2Ti(OR)2] (R = Et, Pr
i
) with alkoxyalkanols (ROCH2CH2OH) (R = Me, Et, n-Bu) in 1:1 and 1:2 molar ratios in refluxing benzene under anhydrous conditions yield [(acac)2Ti(OR)2–n
(OCH2CH2OR)
n
] (n = 1 or 2) complexes, which were purified by distillation under reduced pressure. On the basis of i.r. and n.m.r. (1H- and 13C-) spectral studies, a cis-octahedral environment around TiIV is proposed. On keeping the distilled dark brown-red viscous liquid [(acac)2Ti(OEt)(OCH2CH2OBu)] for 2 weeks, orange yellow crystals of [(acac)2TiO]2 were obtained. A single crystal X-ray diffraction study suggests the product is a new modification of [(acac)2TiO]2. 相似文献
42.
Several novel glycofuranoses disaccharides related to mycobacterial cell wall polysaccharides were synthesized regio- and stereoselectively using 2,3,5-tri-O-benzoyl-alpha-D-arabinofuranosyl trichloroacetimidate as a glycosyl donor. 相似文献
43.
N. Pathak G. K. Mahanti T. K. Sinha Mahapatra 《International Journal of Infrared and Millimeter Waves》2007,28(11):953-960
In this paper, we present a new method based on real-coded Genetic Algorithm (GA) with elitist model for optimal design of
a reconfigurable symmetrical dual-beam uniformly spaced linear isotropic antenna array with phase-only control of quantized
phase shifters. The problem is to find a common amplitude distribution that will generate a pencil beam with zero phases and
a flat-top beam with discrete phases of a six-bit discrete phase shifter, without or with pre-fixing the value of dynamic
range ratio (|I
max/I
min|) of excitation current amplitude distribution equal to or less than five. 相似文献
44.
Chandra Kanta Ghosh Anirban Ray Amarendra Patra 《Journal of heterocyclic chemistry》2001,38(6):1459-1463
The title aldehyde 1 in the presence of ammonia gives the pyridine derivatives 9‐11 respectively with acetylacetone, diethyl malonate and ethyl cyanoacetate, and ethyl (or methyl)‐l‐benzopyrano[4,3‐b]pyri‐dine‐3‐carboxylate 22 (or 23 ) with ethyl (or methyl) acetoacetate. Acetylacetone pretreated with ammonia condenses with 1 giving the fused pyridine 24 . Ammonia converts the ester 6 to the pyridine 13 or 14 . Chromic acid oxidation of 22 and 23 affords the coumarinopyridines 25 and 26 , respectively. 相似文献
45.
Nadler’s contraction principle has led to fixed point theory of set-valued contraction in non-linear analysis. Inspired by the results of Nadler, the fixed point theory of set-valued contraction has been further developed in different directions by many authors, in particular, by Reich, Mizoguchi–Takahashi, Feng–Liu and many others. In the present paper, the concept of generalized contractions for set-valued maps in metric spaces is introduced and the existence of fixed point for such a contraction are guaranteed by certain conditions. Our first result extends and generalizes the Nadler, Feng–Liu and Klim–Wardowski theorems and the second result is different from the Reich and Mizoguchi–Takahashi results. As a consequence, we derive some results related to fixed point of set-valued maps satisfying certain conditions of integral type. 相似文献
46.
Subhash P. Chavan Mahesh Thakkar Ashok B. Pathak Mohan M. Bhadbhade 《Tetrahedron》2005,61(15):3873-3879
The first enantiospecific synthesis of (+)-β-herbertenol, from naturally occurring R-(+)-citronellal, employing Taber's diazo decomposition protocol as the key step, is described. 相似文献
47.
Domadia PN Bhunia A Ramamoorthy A Bhattacharjya S 《Journal of the American Chemical Society》2010,132(51):18417-18428
Lipopolysaccharide (LPS) provides a well-organized permeability barrier at the outer membrane of Gram-negative bacteria. Host defense cationic antimicrobial peptides (AMPs) need to disrupt the outer membrane before gaining access to the inner cytoplasmic membrane or intracellular targets. Several AMPs are largely inactive against Gram-negative pathogens due to the restricted permeation through the LPS layer of the outer membrane. MSI-594 (GIGKFLKKAKKGIGAVLKVLTTG) is a highly active AMP with a broad-spectrum of activities against bacteria, fungi, and virus. In the context of LPS, MSI-594 assumes a hairpin helical structure dictated by packing interactions between two helical segments. Residue Phe5 of MSI-594 has been found to be engaged in important interhelical interactions. In order to understand plausible structural and functional inter-relationship of the helical hairpin structure of MSI-594 with outer membrane permeabilization, a mutant peptide, termed MSI-594F5A, containing a replacement of Phe5 with Ala has been prepared. We have compared antibacterial activities, outer and inner membrane permeabilizations, LPS binding affinity, perturbation of LPS micelles structures by MSI-594 and MSI-594F5A peptides. Our results demonstrated that the MSI-594F5A has lower activities against Gram-negative bacteria, due to limited permeabilization through the LPS layer, however, retains Gram-positive activity, akin to MSI-594. The atomic-resolution structure of MSI-594F5A has been determined in LPS micelles by NMR spectroscopy showing an amphipathic curved helix without any packing interactions. The 3D structures, interactions, and activities of MSI-594 and its mutant MSI-594F5A in LPS provide important mechanistic insights toward the requirements of LPS specific conformations and outer membrane permeabilization by broad-spectrum antimicrobial peptides. 相似文献
48.
Indigo is one of the oldest dyes manufactured chemically and is mostly used in textile, food, and pharmaceutical industries.
However, owing to the environmental hazards posed by the chemical production, the present scenario in the field stipulates
a biosynthesis alternative for indigo production. The present study describes an indigenously isolated naphthalene-degrading
strain Pseudomonas sp. HOB1 producing a blue pigment when indole was added in the growth medium. This blue pigment was analyzed by high-pressure
thin-layer chromatography and other spectroscopic techniques which revealed it to be the indigo dye. Pseudomonas sp. HOB1 showed ability to produce 246 mg indigo liter−1 of the medium. The K
m for the enzyme naphthalene dioxygenase which is involved in indigo formation is 0.3 mM, and V
max was as high as 50 nmol min−1 mg dry biomass−1. The bacterial indigo dye was further successfully applied for dyeing cotton fabrics. The high indigo productivity of Pseudomonas sp. HOB1 using naphthalene as growth substrate and its applicability on cotton fabrics, therefore, stems the probability
of using this culture for commercial indigo production. 相似文献
49.
R. D. Bhanushali Sachin S. Pathak I. C. Pius S. K. Mukerjee 《Journal of Radioanalytical and Nuclear Chemistry》2010,284(3):647-651
Based on the Linssi database and UniSampo/Shaman software, an automated analysis platform has been setup for the analysis
of large amounts of gamma-spectra from the primary coolant monitoring systems of a CANDU reactor. Thus, a database inventory
of gaseous and volatile fission products in the primary coolant of a CANDU reactor has been established. This database is
comprised of 15,000 spectra of radioisotope analysis records. Records from the database inventory were retrieved by a specifically
designed data-mining module and subjected to further analysis. Results from the analysis were subsequently used to identify
the reactor coolant half-life of 135Xe and 133Xe, as well as the correlations of 135Xe and 88Kr activities. 相似文献
50.
Gautam Prasanna Kar Anirban Karmakar Jubaraj B. Baruah 《Journal of chemical crystallography》2010,40(8):702-706