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991.
The unsteady magnetohydrodynamic flow of an electrically conducting viscous incompressible non-Newtonian Bingham fluid bounded by two parallel non-conducting porous plates is studied with heat transfer considering the Hall effect. An external uniform magnetic field is applied perpendicular to the plates and the fluid motion is subjected to a uniform suction and injection. The lower plate is stationary and the upper plate moves with a constant velocity and the two plates are kept at different but constant temperatures. Numerical solutions are obtained for the governing momentum and energy equations taking the Joule and viscous dissipations into consideration. The effect of the Hall term, the parameter describing the non-Newtonian behavior, and the velocity of suction and injection on both the velocity and temperature distributions are studied. 相似文献
992.
A simple and reproducible method for the rapid extraction and determination of trace amounts of copper(Ⅱ) ions using octadecyl-bonded silica membrane disks modified by 1,5-diphenylcarbazide (DPC) and atomic absorption spectrometry was presented, which was based on complex formation on the surface of the ENVI-18 DISK^TM disks followed by stripping of the retained species by minimum amounts of appropriate organic solvents. The elution was efficient and quantitative. The effect of potential interfering ions, pH, ligand amount, stripping solvent, and sample flow rate were also investigated. Under the optimal experimental conditions, the break-through volume was found to be about 1000 mL providing a preconcentration factor of 400. The maximum capacity of the disks was found to be (255±5) lag for Cu^2+, and the limit of detection of the proposed method was 5 ng per 1000 mL. The method was applied to the extraction and recovery of copper in different water samples. 相似文献
993.
In this paper we extend the Tikhonov-Browder regularization scheme from monotone to rather a general class of nonmonotone
multivalued variational inequalities. We show that their convergence conditions hold for some classes of perfectly and nonperfectly
competitive economic equilibrium problems. 相似文献
994.
Ali M. ASlam Laver Murray L. Biermann Christopher J. Krahmer Robert L. Sproull Robert D. 《Applied biochemistry and biotechnology》1990,24(1):75-86
High-density carbon pellets (HDCP) produced from Douglas-fir bark could provide an alternate source of carbon for industry. The production of HDCP in vertical retorts is discussed. Scanning electron microscopy (SEM), atomic absorption spectroscopy (AAS), carbon elemental analysis, and other analytical methods were used to characterize HDCP. HDCP produced from Douglas-fir bark in this work have 90% fixed carbon, an average density of 1.3 g/mL, and 1.18% average ash content with negligible metal impurities. These pellets should be particularly suited for use in the production of adsorbents, high-grade carbons, reductants, carbon black, carbon electrodes, and activated carbons.
相似文献995.
A simple and rapid liquid-liquid extraction of palladium has been studied involving ion-pairing of bromocomplexes of palladium(II) with hexadecylpyridinium bromide (HDPB) dissolved in chloroform. The stoichiometry and distribution of (HDP)2PdBr4 between the aqueous and organic phase was investigated by spectrophotometric mole ratio method. The extraction efficiency of palladium(II) by HDPB was studied as a function of several variables: acid, salt, surfactant concentration and equilibrium time. The results showed that PdBr4(2-) extraction could be explained by assuming the formation of (HDP)2PdBr4 complexes in the aqueous solution and transfer to organic phase. The extraction was fast and the shaking time was only a few min. The average recovery of palladium(II) from an aqueous solution containing 10 microg/ml of analyte was 99% with an RSD% of 0.95. The percentage recovery of 0.2 microg/ml palladium(II) was 96%. 相似文献
996.
Ali M. Ali Ayman H. Ahmed Tarek A. Mohamed Bassem H. Mohamed 《Transition Metal Chemistry》2007,32(4):461-467
New copper(II), nickel(II), iron(III) and palladium(II) Schiff base complexes derived from o-tolidine and selected aldehydes, namely salicyaldehyde and 2-hydroxynaphthaldehyde have been synthesized and characterized
by a combination of elemental analyses, magnetic moments, spectral (u.v.–vis., i.r.) and thermal (tg, dtg) mesurements. The
corrosion inhibition of aluminium and copper in 1 M HCl and chromium–nickel steel in crude oil using N,N′bis(salicyledene)-o-tolidine have been studied by weight loss method. 相似文献
997.
The synthesis of a Δ1-carbapenem and two β-lactams possessing a Br-atom at the N-substituting center not involved in the lactam ring and bearing the carboxyl group is described. The β-lactams having this kind of Br-substitution are more susceptible to nucleophilic attack than those having a conjugated double bond with the N-atom of the β-lactam ring. DBU is found to be an excellent reagent for the elimination of the silyloxy function. Moreover, a simple method for the addition of diethyl phosphite to an α, β-unsaturated double bond using a catalytic amount of NaH is described. 相似文献
998.
Mohammad Shakirullah Imtiaz Ahmad Habibur Rahman M. Arsala Khan M. Ishaq Amjad Ali Shah 《中国化学会会志》2006,53(5):1059-1066
This paper demonstrates the spectral analysis of some distillates obtained from asphalt cracking in the presence of a conventional expensive catalyst, i.e., HZSM‐5, and local cheap and readily available clay, i.e., UTIMAC. Each distillate was fractionated into pentane soluble (PI) and pentane insoluble (PI) fractions based on solubility in n, pentane. Both PS and PI obtained in the case of HZSM‐5 and UTIMAC were analyzed by 1H‐NMR spectrophotometry using CDCl3 as dissolving solvent and tetramethylsilane (TMS) as internal standard. It is evident from the profiles that both catalysts caused the generation of some peaks ascribed to methylene and methene configurations in the aliphatic region. Bands corresponding to aromatic configurations were also generated. The results indicate that the cheap local catalyst used has comparable suitability with the conventional expensive catalyst in terms of asphalt cracking. 相似文献
999.
Polycyclic aromatic hydrocarbons (PAHs) precipitation is one of the major problems in the hydrocracking units. In this investigation, pyrene and phenanthrene were selected because they were found to be in higher concentrations in the feed to hydrocracking units. Their solubilities were investigated in toluene solvent mixture of iso-octane and heptane over a temperature range from 293 to 323 K. The experimental solubility data were used to predict the interaction parameters for seven different solid–liquid equilibrium models. The following activity coefficient models were used; Wilson, NIBS/Redlich–Kister, UNIQUAC, modified UNIFAC, modified UNIFAC (Dortmund), Flory–Huggins and Sheng. The interaction parameters were expressed as a second-order polynomial function in temperature. In order to test the models, the average absolute deviation percentage (AADP) was used. The overall AADP was found to range from approximately 7 to 14%. The models can be arranged according to their accuracy in a descending order based on AADP as follows: NIBS/Redlich–Kister, Wilson, UNIQUAC, Sheng, Flory–Huggins, modified UNIFAC (Dortmund) and finally modified UNIFAC. All models used in this work gave reasonable results; however, the group contribution models can also be used as a predictive tool for the solubility measurement of pyrene and phenanthrene in other solvents containing the same groups of the solvents used in this study. 相似文献
1000.
Nonlinear Galerkin methods and mixed finite elements:
two-grid algorithms for the Navier-Stokes equations 总被引:14,自引:0,他引:14
Summary.
A nonlinear Galerkin method using mixed finite
elements is presented for the two-dimensional
incompressible Navier-Stokes equations. The
scheme is based on two finite element spaces
and for the approximation of the velocity,
defined respectively on one coarse grid with grid
size and one fine grid with grid size and
one finite element space for the approximation
of the pressure. Nonlinearity and time
dependence are both treated on the coarse space.
We prove that the difference between the new
nonlinear Galerkin method and the standard
Galerkin solution is of the order of $H^2$, both in
velocity ( and pressure norm).
We also discuss a penalized version of our algorithm
which enjoys similar properties.
Received October 5, 1993 / Revised version received November
29, 1993 相似文献