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81.
82.
The coupling reaction of N-methylindole with alkyl and aryl phosphonate is described. The reaction works in the presence of 10 mol % of indium triflate and furnished bis(indolyl)methane phosphonates in good yield and high selectivity. 相似文献
83.
Hasan budak Ahmet Bulut Naziye etin Canan Kazak 《Acta Crystallographica. Section C, Structural Chemistry》2005,61(1):m1-m3
The crystal structure of the first acesulfame–metal complex, namely tetraaquabis[6‐methyl‐1,2,3‐oxathiazin‐4(3H)‐onato 2,2‐dioxide‐κN]cobalt(II), [Co(C4H4NO4S)2(H2O)4], is reported. The CoII ion resides on a twofold axis and is coordinated by four aqua ligands defining the basal plane and by two monodentate acesulfamate ligands, via their ring N atoms, in the axial positions. Two intra‐ and three intermolecular hydrogen‐bonding interactions stabilize the crystal structure and form an infinite three‐dimensional lattice. 相似文献
84.
Phthalocyanines with four naphthyl-malonic ester groups on the periphery were synthesized by cyclotetramerization of 4-(1,1-dicarbethoxy-2-(1-naphthyl)-ethyl)-phthalonitrile.
The new compounds were characterized by spectroscopic methods. The electronic spectra exhibit intense π–π* transitions from
the naphthyl moiety together with the characteristic Q and B bands of the phthalocyanine core. The electrochemical properties
of the 2,9,17,23-tetra-(1,1-(dicarbethoxy)-2-(1-naphthyl)-ethyl) phthalocyaninato copper(II) complex were studied by cyclic
voltammetry. 相似文献
85.
Alinur Büyükaksoy Ahmet Demir 《Zeitschrift für Angewandte Mathematik und Physik (ZAMP)》2005,56(4):694-717
A rigorous solution is presented for the problem of diffraction of plane harmonic sound waves by a cavity formed by a terminated rigid cylindrical waveguide of finite length whose interior surface is lined by an acoustically absorbent material. The solution is obtained by a modification of the Wiener-Hopf technique and involve an infinite series of unknowns, which are determined from an infinite system of linear algebraic equations. Numerical solution of this system is obtained for various values of the parameters of the problem and their effects on the diffraction phenomenon are shown graphically.Received: December 12, 2001 相似文献
86.
Aydan Dag Hakan Durmaz Emrah Demir Gurkan Hizal Umit Tunca 《Journal of polymer science. Part A, Polymer chemistry》2008,46(20):6969-6977
The double click reactions (Cu catalyzed Huisgen and Diels–Alder reactions) were used as a new strategy for the preparation of well‐defined heterograft copolymers in one‐pot technique. The synthetic strategy to the various stages of this work is outlined: (i) preparing random copolymers of styrene (St) and p‐chloromethylstyrene (CMS) (which is a functionalizable monomer) via nitroxide mediated radical polymerization (NMP); (ii) attachment of anthracene functionality to the preformed copolymer by the o‐etherification procedure and then conversion of the remaining ? CH2Cl into azide functionality; (iii) by using double click reactions in one‐pot technique, maleimide end‐functionalized poly(methyl methacrylate) (PMMA‐MI) via atom transfer radical polymerization (ATRP) of MMA and alkyne end‐functionalized poly (ethylene glycol) (PEG‐alkyne) were introduced onto the copolymer bearing pendant anthryl and azide moieties. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 6969–6977, 2008 相似文献
87.
Ahmet ?ener Nurettin Menge? Mehmet Akkurt Orhan Büyükgüngör 《Tetrahedron letters》2008,49(17):2828-2831
Oxalacetic acid and pyruvic acid derivatives have been synthesized efficiently in high yields by the treatment of 4-ethoxycarbonyl-5-phenyl-2,3-furandione and 4-benzoyl-5-phenyl-2,3-furandione with 2-phenylindole at room temperature and converted to simple derivatives such as an ester or a hydrazone. 相似文献
88.
Selçuk Demir Hamide Merve Çepni Małgorzata Hołyńska Muammer Kavanoz Fatih Yilmaz Yunus Zorlu 《Journal of Coordination Chemistry》2017,70(19):3422-3433
Via an oxidation reaction of Cu(I) iodide with pyridine-2,6-dicarboxylic acid (H2L) in DMF three copper(II) complexes, [(CH3)2NH2]2[CuL2] (1), K2[CuL2]?H2L?H2O (2) and [Cu(L)(H2O)]n (3), were synthesized and characterized. The structures of 1–3 were determined by single crystal X-ray diffraction studies. In-situ DMF decomposition produces dimethylamine base under solvothermal conditions and a proton transfer reaction takes place for the complex formation of 1. 3-D networks are stabilized in 1 and 2 via hydrogen bonds. Complex 3 is a 1-D coordination polymer with Cu-O semi-coordination bonds. Thermal decomposition of the complexes results in the corresponding metal oxides. Also, the electrochemical behavior of 1 was determined to be a metal-centered and diffusion-controlled, one-electron reduction process. 相似文献
89.
Zeynep Ustaoglu Iyigundogdu Okan Demir Ayla Burcin Asutay Fikrettin Sahin 《Applied biochemistry and biotechnology》2017,181(3):1155-1166
In conjunction with an increasing public awareness of infectious diseases, the textile industry and scientists are developing hygienic fabrics by the addition of various antimicrobial and antiviral compounds. In the current study, sodium pentaborate pentahydrate and triclosan are applied to cotton fabrics in order to gain antimicrobial and antiviral properties for the first time. The antimicrobial activity of textiles treated with 3 % sodium pentaborate pentahydrate, 0.03 % triclosan, and 7 % Glucapon has been investigated against a broad range of microorganisms including bacteria, yeast, and fungi. Moreover, modified cotton fabrics were tested against adenovirus type 5 and poliovirus type 1. According to the test results, the modified textile goods attained very good antimicrobial and antiviral properties. Thus, the results of the present study clearly suggest that sodium pentaborate pentahydrate and triclosan solution-treated textiles can be considered in the development of antimicrobial and antiviral textile finishes. 相似文献
90.
Afsin Y. Cetinkaya Oguz Kaan Ozdemir Ahmet Demir Bestami Ozkaya 《Applied biochemistry and biotechnology》2017,182(2):468-481
Microbial fuel cells (MFCs) convert electrochemical energy into electrical energy immediately and have a big potential usage for the same time wastewater treatment and energy recovery via electro-active microorganisms. However, MFCs must be efficiently optimized due to its limitations such as high cost and low power production. Finding new materials to increase the cell performance and reduce cost for MFC anodes is mandatory. In the first step of this study, different inoculation sludges such as anaerobic gum industry wastewater, anaerobic brewery wastewater and anaerobic phosphate were tested, and MFC that was set up with anaerobic gum industry wastewater inoculation sludge exhibited the highest performance. In the second step of this study, various wastewaters such as chocolate industry, gum industry and slaughterhouse industry were investigated for anode bacteria sources. Several electrochemical techniques have been employed to elucidate how wastewaters affect the MFCs’ performance. Among all the mentioned wastewaters, the best performance was achieved by the MFCs fed with slaughterhouse wastewater; this device produced a maximum power density of 267 mW·m?2. 相似文献