Propagation of two optical beams in a two-photon resonant medium

Propagation of two-copropagating or counterpropagating beams is considered in a slab of nonlinear dielectric which is in two-photon resonance with respect to the sum of the laser frequencies. The effects of saturated absorption and dispersion of the beam intensities are studied in detail. The slab transmission is shown to be significantly affected by the induced optical Stark-shift.     

Vibrational properties of crystalline and amorphous Ge1−xSixalloys

A five-atom cluster Bethe lattice method treating the short-range order with proper statistical effects has been proposed for understanding the crystalline and amorphous alloys. Numerical results for Ge_1?xSi_x alloys are in excellent agreement with the experimental data. In the system studied the network is random but the nearest-neighbour coordination should be treated exactly. The long-range coordination is seen to be concentration-dependent in the crystalline alloys but concentration-independent in the amorphous alloys.     

3,4,5-Trihydroxybenzoesäure als Chelatbildner, 1. Mitt.: Praseodym

Stability constants of praseodymium chelates of 3,4,5-trihydroxy sodium benzoate are determined by using Bjerrum-Calvin pH titration technique at constant ionic strength 0.1M-sodium perchlorate and at 28±0.1°C. Values calculated by different methods are in good agreement. The study reveals that during complexation only one proton of the ligand molecule is replaced by the metal and oxygen of adjacent phenolic group acts as a coordinating atom. IR and NMR spectral studies of the ligand reveal that one of the OH groups (in meta position to carboxylic group) remains free while two other phenolic groups are involved in intramolecular hydrogen bonding. One water molecule is found attached in crystalline gallic acid.

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Mit 2 Abbildungen     

Studies on the reaction products of bis(2-furanthiocarboxyhydrazidato)m(II) with pyridine-2- and -4-carboxaldehydes

Condensation of bis(2-furanthiocarboxyhydradatometal(II), M(fth)₂; [M (II) = Mn, Fe, Co, Ni, Cu and Zn] with pyridine-2- and -4-carboxaldehydes gave complexes of the formula M(pfth)₂ [pfth? = pyridine-2-carboxaldehyde-2-furanthiocarboxyhydrazonato], Ni(Ifth)₂, Zn(Ifth)₂, Cu(Ifth) and Co(Ifth)₃, (Ifth? = pyridine-4-carboxaldehyde-2-furanthiocarboxyhydrazonato). The magnetic and electronic spectral studies coupled with photoacoustic or Mössbauer spectra suggested octahedral geometry for the M(II) complexes with low-spin states for Co(Ifth)₃ and Fe(pfth)₂. IR and ¹H NMR spectral studies of diamagnetic complexes suggested bonding through “azomethine” nitrogen and “thiolo” sulphur. IR spectra also showed the involvement of pyridine ring nitrogen in coordination in all the complexes except Cu(Itfh), Co(Ifth)₃, and Zn(Ifth)₂. Some of the compounds possessed antimicrobial activity.     

Pyridine based thorium(IV) phosphate hybrid fibrous ion exchanger

Pyridine based thorium(IV) phosphate (PyThP) has been synthesized by drop-wise addition of the thorium(IV) nitrate with constant stirring into a mixture of pyridine and phosphoric acid. This material has been characterized using X-ray, IR spectra, TG, DTG and SEM studies in addition to its ion exchange capacity, elution and pH titrations. The material has been found amorphous and fibrous in nature on the basis of X-ray diffraction and SEM studies. TG has revealed the changes incurred in the material on thermal treatment and IR spectral studies have shown the presence of various groups in its structure.     

Atmospheric propagation of high-power laser pulses by self-channelling

The atmospheric propagation of a sequence of short, intense laser pulses is considered. The pulses propagate in a self-induced low-density channel, the effectiveness of which depends on a set of three variables. Using a simple model for the laser-atmosphere interaction, the range of successive pulses is determined by numerical solutions to the paraxial wave equation. The dependence of the length, width, and depth of the created channel on the important variables is explored.     

Study of cosmic ray diurnal variation on a day-to-day basis

From a careful examination of the diurnal variation of cosmic ray intensity at high energies and the interplanetary field characteristics, the average characteristics of diurnal variation were recently explained by us in terms of a balance between outward convection and field aligned diffusion, the latter arising out of a positive radial density gradient. In this paper, we extend this new concept to explain the large variability observed in the diurnal variation on a day-to-day basis and further demonstrate that the measurement of diurnal anisotropy characteristic of cosmic ray particles on a day-to-day basis can be used directly to infer the nature and scale sizes of interplanetary field parameters. Comparing with the magnetic field vector, we show that this simple concept holds good on more than 80% of days. On the rest 20% of days which have a predominant morning maxima, the diurnal anisotropy characteristics seem to indicate the presence of a significant component of transverse diffusion current in addition to the normal convection and diffusion flow. Such days are found to be present in the form of trains of consecutive days and are found to be associated with abrupt changes in the interplanetary field direction having scale sizes >4 hr. The value ofK _⊥/K _‖ which is normally about ⩽0.05 is found to be ≈1.0 on non-field aligned days.