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351.
This work describes the electrochemical behavior of copper(II)-bis[5-((4-n-decyloxyphenyl)azo)-N-(nethanol)-salicylaldiminato]film immobilized on the surface of multiwall carbon nanotube glassy carbon electrode and its electrocatalytic activity toward the oxidation of L-cysteine. The surface structure and composition of the sensor was characterized by scanning electron microscopy. Electrocatalytic oxidation of L-cysteine on the surface of modified electrode was investigated with cyclic voltammetry, chronoamperometry and hydrodynamic amperometery methods and the results showed that the Cu-Schiff base film displays excellent electrochemical catalytic activities towards L-cysteine oxidation. The modified electrode indicated reproducible behavior and high level of stability during the electrochemical experiments. 相似文献
352.
Callus culture of Artemisia absinthium L. was established for enhanced production of phenolics and higher antioxidant activity. Callus was induced from seed-derived leaf explants, incubated on to MS media supplemented with thidiazuron (TDZ; 0.5–5.0 mg/l) either alone or in combination with α-naphthalene acetic acid (NAA; 1.0 mg/l). These callus cultures were investigated for their growth kinetics, total phenolic content, and antioxidant activity on weekly basis for a period of 49 days. Maximum dry biomass accumulation of 8.73 g/l was observed on day 42 in response to 1.0 mg/l TDZ and 1.0 mg/l NAA. Furthermore, maximum level of total phenolic content of 8.53 mg GAE/g DW and highest 2,2-diphenyl-1-picrylhydrazyl (DPPH) radical scavenging activity of 72.6 % were observed in calli formed in response to 1.0 mg/l TDZ on day 42. The results showed a positive correlation of total phenolic content and DPPH radical scavenging activity in most of the callus cultures of A. absinthium L. 相似文献
353.
M. H. Ghoncheh S. G. Shabestari M. H. Abbasi 《Journal of Thermal Analysis and Calorimetry》2014,117(3):1253-1261
The aim of this work was to investigate the effect of different cooling rates on the microstructure and solidification parameters of 2024 aluminum alloy. Solidification characteristics are recognized from the cooling curve and its first and second derivative curves which have been plotted using thermal analysis technique. In this study, a mold having high cooling rate was designed and used to simulate the direct-chill casting process. The results of thermal analysis show that the characteristic parameters of Al2024 alloy are influenced by cooling rate. The cooling rates used in the present study range from 0.4 to 17.5 °C s?1. Increasing the cooling rate affects the undercooling parameters both in liquidus and eutectic solidification regions. Investigations showed that solidification parameters such as nucleation temperature, recalescence undercooling temperature, and range of solidification temperature are influenced by variation of cooling rates. Microstructural evaluation was carried out to present the correlation between the cooling rate and dendrite arm spacing. 相似文献
354.
Liquid Crystals Anchored on Mixed Monolayers of Chiral versus Achiral Molecules: Continuous Change in Orientation as a Function of Enantiomeric Excess 下载免费PDF全文
Yiqun Bai Reza Abbasi Dr. Chenxuan Wang Dr. Nicholas L. Abbott 《Angewandte Chemie (International ed. in English)》2014,53(31):8079-8083
The orientations of liquid crystals (LCs) anchored on monolayers formed from mixtures of chiral versus achiral molecules were compared. Changes in the enantiomeric excess of mixed monolayers of chiral dipeptides gave rise to continuous changes in the orientations of nematic LCs, allowing arbitrary tuning of the azimuthal orientations of LCs over a range of ≈100°. In contrast, the same LCs exhibited discontinuous changes in orientation on surfaces presenting mixtures of achiral molecules. These striking differences in the anchoring of LCs on surfaces presenting chiral versus achiral molecules provide insights into the molecular origins of ordering transitions of LCs, and provide new principles based on chiral monolayers for the rational design of surfaces that permit continuous tuning of the orientations of LCs. 相似文献
355.
Bilal H. Abbasi Amanda R. Stiles Praveen K. Saxena Chun-Zhao Liu 《Applied biochemistry and biotechnology》2012,168(7):2057-2066
Gibberellic acid (GA3) is reported to have diverse effects on hairy root cultures of many plant species; therefore, the effects of GA3 on the growth, secondary metabolite production (caffeic acid derivatives and lignin), phenylalanine ammonia lyase (PAL) activity, and free radical scavenging activity of light-grown Echinacea purpurea L. hairy roots were investigated. Eight concentrations of GA3, ranging from 0.005 to 1.0 μM, were added to shake flask cultures. The moderate GA3 concentration, 0.025 μM, resulted in the highest concentrations of cichoric acid, caftaric acid, and chlorogenic acid, as well as increased PAL activity, cell viability, and free radical scavenging activity, while higher and lower GA3 concentrations resulted in reduced levels compared to the control (lacking GA3). The moderate GA3 concentration also affected root morphogenesis; supplementation with 0.025 μM GA3 resulted in the development of thick, dense, purple-colored roots, while roots exposed to the higher and lower concentrations of GA3 were thin and off-white. This study demonstrates that supplementation with GA3 may be an excellent strategy to optimize the production of secondary metabolites from E. purpurea hairy root cultures; however, the GA3 concentration is a critical factor. 相似文献
356.
Yasar Arafat Abbasi Akbar Ali Muhammad Haleem Khan Muhammad Mufazzal Saeed Kashif Naeem 《Journal of Radioanalytical and Nuclear Chemistry》2012,292(1):277-283
The extraction behavior of nalidixic acid (HNA) in CH2Cl2 has been studied for various di- and trivalent metal ions such as Cu(II), Fe(II), Ni(II), Mn(II), Sb(II), Co(II), Sc(III),
Y(III), Nd(III) and Eu(III) from aqueous buffer solutions of pH 1–7 with 0.1 mol dm−3 nalidixic acid in dichloromethane. Separation factors of Sc(III) from these metals has shown that its clean separation is
possible at pH 3.4–4. The parameters affecting the extraction of Sc(III) were optimized. The composition of the extracted
adduct was determined by slope analysis method that came out to be Sc(NA)3. Extraction of Sc(III) was studied in the presence of various cations and anions. Among the anions studied only fluoride,
citrate and oxalate have significant interference whereas, Fe(III) has reduced the extraction to 53% that can be removed by
using ascorbic acid as reducing agent. The proposed extraction system proved good stability up to six extraction-stripping
stages for the extraction of Sc(III). 相似文献
357.
The growth of Cu3(BTC)2 (BTC = 1,3,5-benzenetricarboxylate), also known as CuBTC and HKUST-1, Metal-Organic Framework (MOF) nanostructures on silk fibers were achieved by layer-by-layer technique in alternating bath of Cu(OAc)2·2H2O and H3BTC solutions under ultrasound irradiation. The effect of pH, reaction time, ultrasound irradiation and sequential dipping steps in growth of the CuBTC Metal-Organic Framework nanostructures has been studied. These systems depicted a decrease in the size accompanying a decrease in the sequential dipping steps. In addition, dense coating of silk fibers with CuBTC MOF results in decrease the emission intensity of silk fibers. The silk fibers containing CuBTC Metal-Organic Framework exhibited high antibacterial activity against Escherichia coli and Staphylococcus aureus. The samples were characterized with powder X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) spectra and scanning electron microscopy (SEM). XRD analyses indicated that the prepared CuBTC MOF nanostructures on silk fibers were crystalline. 相似文献
358.
The growth of silver bromide nanoparticles on polyester fiber was achieved by sequential dipping steps in alternating bath of potassium bromide and silver nitrate under ultrasound irradiation. The effects of ultrasound irradiation, concentration and sequential dipping steps in growth of the AgBr nanoparticles have been studied. Particle sizes and morphology of nanoparticle are depending on power of ultrasound irradiation, sequential dipping steps and concentration. These systems depicted a decrease in the particles size accompanying an increase in the sonication power. Results suggest that an increasing of sequential dipping steps and concentration led to an increasing of particle size. The physicochemical properties of the nanoparticles were determined by powder X-ray diffraction (XRD) and scanning electron microscopy (SEM). 相似文献
359.
The polyethylene fibers containing Ag nanoparticles were prepared through the chemical reduction under ultrasound irradiation. The effect of reducing reagent, power of ultrasound irradiation, reaction time and temperature in growth of the nanometric Ag were studied. Particle sizes and morphology of nanoparticle are depending on power of ultrasound irradiation. Results show a decrease in the particles size as increasing power of ultrasound irradiation. Also, an increase in temperature led to increase of particle size. The polyethylene fibers containing Ag nanoparticles were characterized with powder X-ray diffraction (XRD) and scanning electron microscopy (SEM). 相似文献
360.