稀土掺杂LaF3超小发光纳米晶的合成及癌细胞靶向上转换发光成像研究

采用溶剂热法合成了超小尺寸三氟化镧（LaF₃）纳米晶. 利用XRD、TEM等对其进行结构与形貌表征,结果显示制得的纳米颗粒为LaF₃纳米晶,且具有高度均一的尺寸分布和良好的结晶度,颗粒尺寸为6±0.4 nm. 通过共掺杂镱铒两种稀土元素,所得材料在近红外光激发下（980 nm）可发射出明亮的绿光;发光光谱显示,在524,544,655 nm等位置有较强的发射峰. 利用聚琥珀酰亚胺高分子（PSI）对油溶性的纳米颗粒表面进行功能化修饰,将其成功转移水相. 利用叶酸对其进行进一步生物标记,可与肝癌细胞表面叶酸受体特异性识别,成功地实现了肝癌细胞上转换绿色发光成像研究.     

聚己内酯/聚酯丙烯酸酯共混物的辐射交联及其形状记忆行为

研究了聚酯丙烯酸酯 (PEA)类多官能团物质与聚己内酯 (PCL)共混物的辐射交联效应 .分别考察了多官能团PEA的用量、官能团数目、辐射交联剂量等因素对聚己内酯的辐射交联规律、动态力学性能、形状记忆行为等性能的影响 .结果表明 ,PCL PEA共混物的辐射交联规律不再遵从Charlesby Pinner关系式 ,而是符合陈欣方 刘克静 唐敖庆关系式 .多官能团PEA的加入可以显著提高PCL辐射交联的效率 ;相同剂量时 ,官能团数目越多、用量越大的样品 ,生成的凝胶含量越多 ,强化辐射交联效应越大 .DMA分析表明 ,PCL强化辐照交联后的弹性模量和耐热性能显著提高 .强化交联PCL在其熔点以上都呈现出高弹态平台 ,可以实现形状记忆 .且交联度较高 ,形状记忆恢复速率较快 .     

Asymmetric Cyclopropanation Catalyzed by Four Stereoisomers of a Copper-(Schiff-base) Complex with Double Chiral Centers

Catalytic asymmetric cyclopropanation of diazoacetates with olefins has attracted much attention. Those catalysts containing various metals and optically active ligands have been employed for this reaction1,2. The first catalytic asymmetric cyclopropanation reaction was reported in 1966 by Nozaki et al.3. The author used the copper(II) complex 1 bearing a salicyladimine ligand as catalyst though with a low e.e. value of 6%. Aratani and his coworkers designed the copper-(Schiff-base) comp…     

LIMIT CYCLES AND BIFURCATION CURVES FOR THE QUADRATIC DIFFERENTIAL SYSTEM(III)_(m=0)HAVING THREE ANTI-SADDLES(II)

ＬＩＭＩＴＣＹＣＬＥＳＡＮＤＢＩＦＵＲＣＡＴＩＯＮＣＵＲＶＥＳＦＯＲＴＨＥＱＵＡＤＲＡＴＩＣＤＩＦＦＥＲＥＮＴＩＡＬＳＹＳＴＥＭ（ＩＩ）ｍ＝０ＨＡＶＩＮＧＴＨＲＥＥＡＮＴＩＳＡＤＤＬＥＳ（Ｉ）ＹＥＹＡＮＱＩＡＮＡｂｓｔｒａｃｔＡｓａｃｏｎｔｉ...     

Synthesis and Crystal Structure of α-( N-Protected a mino)β- lactam Derivative of 1 ,5-Benzothiazepine

１　ＩＮＴＲＯＤＵＣＴＩＯＮＲｅｃｅｎｔｌｙ,ａｎｕｍｂｅｒｏｆｄｅｒｉｖａｔｉｖｅｓｏｆｂｅｎｚｏｔｈｉａｚｅｐｉｎｅｈａｖｅｂｅｅｎｐｒｅｐａｒｅｄａｎｄｓｔｕｄｉｅｄｆｏｒｔｈｅｉｒｐｈａｒｍａｃｏｌｏｇｉｃａｌａｃｔｉｖｉｔｉｅｓ〔１５〕．Ｉｎｏｕｒｐｒｅｖｉｏｕｓｗｏｒｋ,ｗｅｈａｖｅｉｎｃｏｒｐｏｒａｔｅｄｔｈｅβｌａｃｔａｍｒｉｎｇｉｎｔｏ１,５ｂｅｎｚｏｔｈｉａｚｅｐｉｎｅｂｙｒｅａｃｔｉｏｎｏｆ１,５ｂｅｎｚｏｔｈｉａｚｅｐｉｎｅｗｉｔｈｓｏｍｅａｃｙｌｃｈｌｏｒｉｄ…     

Synthesis and Crystal Structure of Dicesium trans Dicarbonatotetraaquomagnesium, Cs_2[Mg(CO_3)_2(H_2O)_4]

ＩｎｔｒｏｄｕｃｔｉｏｎＰｒｅｖｉｏｕｓｌｙ,ｗｅｒｅｐｏｒｔｅｄｔｈｅｃｒｙｓｔａｌｓｔｒｕｃｔｕｒｅｏｆＫ２［Ｎｉ（ＣＯ３）２（Ｈ２Ｏ）４］［１］,ｗｈｉｃｈｃｒｙｓｔａｌｌｉｚｅｄｉｎｔｈｅｂａｙｌｉｓｓｉｔｅｔｙｐｅｓｔｒｕｃｔｕｒｅａｎｄｗａｓｆｏｕｎｄｔｏｂｅｉｓｏｓｔｒｕｃｔｕｒａｌｗｉｔｈＫ２［Ｃｏ（ＣＯ３）２（Ｈ２Ｏ）４］［２］ａｎｄＫ２Ｍｇ（ＣＯ３）２·４Ｈ２Ｏ［３］．Ｉｎｏｒｄｅｒｔｏｓｙｓｔｅｍａｔｉｃａｌｌｙｉｎｖｅｓｔｉｇａｔｅｔｈｅｏｃｃｕｒｒｅｎｃｅｏｆｔｈｅｃｏ…     

三甲川菁染料敏化TiO2纳米 结构电极的光电化学

The photoelectrochemical behaviors of the TiO₂ nanostructured porous film sensitized by cyanine dye were investigated in this paper.The results showed that the excitaed state level matched the conduction band edge of TiO₂ nanoparticle.Therefore the sensitization of the dye can increase the photocurrent intensity of the TiO₂ nanostructured electrode obviously and results in a red-shift of optical absorption from the ultra-violet region to the visible.As a result,the light-to-electricity conversion efficiency was improved evidently,the maximum value of IPCE has reached 12.1%.     

A Fluorescence Optical Fiber Sensor for Amrinon Using a New Oxazole Compound

ＩｎｔｒｏｄｕｃｔｉｏｎＡｍｒｉｎｏｎ,ａｓｙｎｔｈｅｔｉｃｂｉｐｙｒｉｄｉｎｅｄｅｒｉｖａｔｉｖｅ,ｎｏｎｇｌｙｃｏｓｉｄｅａｎｄｎｏｎｃａｔｅｃｈｏｌａｍｉｎｅｃａｒ－ｄｉｏｔｏｎｉｃｓｔｉｍｕｌａｎｔ,ｉｓｃｕｒｒｅｎｔｌｙｕｓｅｄｉｎｔｈｅｔｒｅａｔｍｅｎｔｏｆｔｈｅｈｅａｒｔｆａｉｌｕｒｅａｎｄｆｏｒｃａｒｄｉｏｖａｓｃｕ－ｌａｒｓｕｐｐｏｒｔｉｎｐｅｄｉａｔｒｉｃｐａｔｉｅｎｔｓ．Ｉｔｐｏｓｓｅｓｓｅｓｐｏｔｅｎｔｃａｒｄｉａｃａｎｄｂｌｏｏｄｖｅｓｓｅｌｓｐｒｅａｄｉｎｇｅｆ－ｆｅ…     

The Elastic Continuum Limit of the Tight Binding Model

The authors consider the simplest quantum mechanics model of solids,the tight binding model,and prove that in the continuum limit,the energy of tight binding model converges to that of the continuum elasticity model obtained using Cauchy-Born rule.The technique in this paper is based mainly on spectral perturbation theory for large matrices.