VA-90氢化物发生-原子吸收光谱法测定食品中痕量铅

本文研究了用氢化物发生－原子吸收光谱法测定食品中痕量铅的方法。该法简便、快速,扩大了火焰原子吸收的分析范围,具有良好的精密度和准确度。测定结果的相对标准偏差为２．３９％,平均回收率为９２．４６％。     

利用拉曼孤子实现宽带拉曼脉冲压缩

从拉曼散射方程的出发,研究了利用拉曼孤子实现宽带拉曼脉冲压缩的机制,发现孤子脉冲的宽度随拉曼增益的增加减小,并与 运光的脉冲形状及相位结构有关。实验中利用ＸｅＣｌ激光／Ｈ２系统初步实现了５０％的压缩率,并将实验结果与理论进行了比较。     

拉曼链系统用空间滤波器设计的实验研究

进行了惯性约束聚变（ＩＣＦ）准分子激光拉曼链工程的基础研究工作。为给出拉曼链中所用空间滤波器的设计要求和可靠性,进行了详细的设计实验判断性研究。给出研究过程和结果,并对设计结论和优化方法进行了基础分析。还据实验结果讨论了适用于高功率激光系统的空间滤波器的设计中面临的焦距和滤波小孔孔径选择的不确定性、滤长和光束功率密度对选择小孔的影响等问题。     

PEEK塑料摩擦销的温度场理论计算

按照一维稳态条件,给出了塑料销的温度分布的分析解.考虑了径向和轴向的二维情况,对塑料销进行了稳态与非稳态数值分析.结果表明,数值解及分析解均与实测结果具有很好的一致性     

Structural classification and a binary structure model for superconductors

Based on structural and bonding features, a new classification scheme of superconductors is proposed to classify them into three classes: three-dimensional, two-dimensional and molecule-assembled superconductors. The sandwich model' for the high-T_c cuprates is extended to a `binary structure model': i.e., the crystal structure of most superconductors can be partitioned into two parts, a superconducting active component and a supplementary component. Partially metallic covalent bonding is found to be a common feature in all superconducting active components, and the electron states of the atoms in the active components usually make a dominant contribution to the energy band near the Fermi surface. Possible directions to explore new superconductors are discussed based on the structural classification and the binary structure model.     

PtRuMo/C催化剂的制备及其对甲醇的电催化氧化作用

阳极甲醇氧化;电催化剂;PtRuMo/C催化剂的制备及其对甲醇的电催化氧化作用     

Application of retrospective time integration scheme to the prediction of torrential rain

The retrospective time integration scheme presented on the principle of the self-memory of the atmosphere is applied to the mesoscale grid model MMS,constructing a mesoscale self-memorial model SMMS, and then the shortrange prediction experiments of torrential rain are performed in this paper. Results show that in comparison with MM5 the prediction accuracy of SMM5 is obviously improved due to its utilization of multiple time level past observations,and the precipitation area and intensity predicted by SMM5 are closer to observational fields than those by MM5.     

弹簧振子在定常干摩擦阻尼作用下的振动

首先给出了弹簧振子在定常干摩擦阻尼作用下的振动微分方程,并通过分段求解,归纳出其在各个阶段的解的一般形式,然后分析了振动的基本规律,作出了振动的图象。     

NixZry(x:y=1∶2或2∶1)团簇的量子化学研究

根据化学键理论和拓扑学原理,设计了非晶态团簇NixZry(x:y=1∶2 或2∶1, x+y≤9)的几十种可能的构型,并应用量子化学从头算方法对它们的几何构型进行了优化,分析比较了这些构型的能量和稳定性。结果表明对于NixZry(x:y=1∶2)低对称性的平面构型最稳定,而NixZry(x:y=2∶1)三棱柱构型最稳定。这可能是由于两者外层价电子的数量差异所致： Zr仅有4个价电子,较适宜配位数低的平面构型,而Ni（4s23d8),更适宜立体构型。     

用光纤光栅的啁啾效应实现温度不敏感的弯曲传感

本文首次将光纤布喇格光栅在梯度分布的应变作用下产生的啁啾效应应用于弯曲传感,提出了一种新颖的光纤光栅弯曲传感方法.由于传感量为光纤光栅的带宽,传感测量完全避开了温度的交叉敏感效应,实验测量得到了很好的线性响应.基于光谱分析仪0.1nm的光谱分辨率,实验的曲率分辨率为0.036m^-1,测量范围可达4m^-1.