Synthesis and Structure of E-2-(2,4,6-tri tert butylphenylphosphinyl)-2-〔N-(tert-butyldimethylsilyl)-N-(p-chrolophenyl)〕amino-1-(2,4,6-tri tert-butyl-phenyl)phosphacthylene

1　INTRODUCTIONItwaswellknown thatelementsofthesecondary and higherrow are in generaldifficulty to form multiplebondsin which apπ hybridized stateisinvolved〔1〕.Thus,simple compounds containing multiple phosphorus carbon bonds,such as methyl dynephosphine( HC≡P) 〔2 - 3〕 and methylenephosphine( H2 C=PH〔4〕,are notstableat room temperature.Three methods to stabilize compounds containing double ormultiple bond involving phosphorusatom in the pπ hybridized state are often used.The f…     

代数数与超越数简介

人们在建立数系的过程中,自引入无理数之后,数系就从有理数集扩展到实数集。由于无理数的引入首先是通过对2~(1/2)的研究来实现的,因此人们很容易认识到3~(1/5)、7~(1/4)、… …103~(1/n)、……都是无理数。但是,往往会造成一种错觉,即错误地认为一切无理数都是用根式     

碳前驱体CH3ArCH2NH2的热解性能及动力学研究

通过密闭压力容器法、常压DSC、高压DSC及紫外分光光度定量分析法等实验手段，对液相沉积法制碳/碳复合材料用碳前驱体CH     

Two New Compounds from Goniothalamus Cheliensis Hu

Goniothalamus cheliensis Hu (Annonaceace) is a small tree or shrub in Yunnan Province, southwest of China. Acetogenins, styryllactones and alkaloids1-3 from the genus were reported in the previous literature and many of them showed strong cytotoxic activities against a number of human cancer cell lines4. The titled plant has been the subject of our investigation due to the impressive cytotoxicity of its organic extract against mouse lymphocytic leukemia cells in preliminary pharmacological s…     

Cosolvent Effect on the Tautomerism of Ethyl Acetoacetate in Supercritical CO_2

There are some unique advantages for chemical reactions in SCFs. For example, reaction rates, yields, and selectivity can be tuned by pressure or small amount of cosolvent. SCFs can be used to replace environmentally undesirable solvents. It is not surprised that in recent years the use of SCFs as solvents for chemical reaction media has received much attention. However, mechanism for the effect of pressure and cosolvents on chemical reactions is not very clear. Tautomeric reactions are id…     

氢、氘和氚离子在固体表面上的反射

本文应用最近发展的离子输运双群模型计算了氢,氘和氚离子在固体表面的反射系数。与有关的实验资料和Monte-Carlo计算比较表明,双群模型所取得的结果是合理的、可用的。同时也表明了双群模型有可能成为研究离子在固体表面反射的有效的理论方法。 关键词：     

吸收光谱光路的设计与误差

固体、液体和气体物质的吸收光谱是大学普物、光学专业的一个基本实验．如何在普通的设备和实验条件下，较为准确地测量吸收系数？本文从朗伯定律出发，介绍一种“对数测量法”光路．并对实验中出现的“负吸收系数”等误差作了分析．文中还介绍了消除材料样品对探测光的反射误差的固体、液体样品架．     

Photochemical Reduction of Aromatic Imines by 2-Phenyl-N, N-dimethylbenzimidazoline

Reduction of C=N double bonds has been recognized as an important reaction both in organic chemistry and bio-chemistry1. Hantzsch 1,4-dihydropyridine (HEH, one of NADH model compounds) has been reported as a reductive reagent for imines2. However, application of dihydropyridines as practical reducing reagents in organic synthesis is limited because of their instability3. Like NADH models, 2-phenyl-N, N-dimethylbenzimidazoline (PDMBI) is an efficient electron and hydrogen donor (Eox = 0…     

两种吸血蛭类光感受器的超微结构

运用透射电镜技术对采自浙江的日本医蛭和天目山蛭的光感受器-眼的超微结构进行了比较研究.发现两者的主要差别在于前者眼的色素杯浅,且宽度与深度较为接近,透光体微绒毛可卷曲;后者眼的色素杯深,其深度明显大于宽度,透光体微绒毛未见卷曲.天目山蛭感光细胞中由微绒毛组成的感光膜表面积远大于日本医蛭,因此陆生蛭类的感光能力比水生种类强,这与陆地环境的复杂性有一定关系.     

新题征展(97)

A 题组新编 　　1.(侯雪花)若a,b是正数,且a+b=1. 　　(1)求证:(a+1/a-1)(b+1/b-1)≥9/4; 　　(2)求证:(a+1/a-1)2+(b+1/b-1)2≥9/2; 　　(3)求证:(a+1/a-2)(b+1/b-2)≤1/4; 　　(4)求证:(a+1/a-2)2+(b+1/b-2)2≥1/2.……