Stabilization of Cu/ZnO Based Catalysts by Nickel Additive in Methanol Decomposition

A series of Cu/Zn based catalysts with and without Ni, prepared by the co-precipitation method, has been studied for methanol decomposition. CO and H2 are the major products. The Cu/Zn catalysts show a low initial activity and a poor stability. The formation of the CuZn alloys was observed in the deactivated Cu/Zn catalysts which were used for methanol decomposition at 250 . When small amounts of Ni were added in the catalyst, the Cu/Zn/Ni(molar ratio 5/4/ x) catalysts showed a high activity at a low temperature. The activity and the stability of the catalyst depend on the nickel content. The activity of the Cu/Zn/Ni catalysts was maintained at a. relatively stable value of 78% conversion of methanol with 95% selectivity of H2, 93% selectivity of CO, and a more than 70% yield of hydrogen was obtained at 250 C when x >1. The stability of the Cu/Zn/Ni (molar ratio 5/4/x) catalysts showed the maximum (ca 88%) when x=1. The stabilization effect of nickel on the Cu/Zn based catalysts may lead to the increasin     

A Thermodynamic Model for Square-well Chain Fluid: Theory and Monte Carlo Simulation

A thermodynamic model for the freely jointed square-well chain fluids was developed based on the thermodynamic perturbation theory of Barker-Henderson, Zhang and Wertheim. In this derivation Zhang's expressions for square-well monomers improved from Barker-Henderson compressibility approximation were adopted as the reference fluid, and Wertheim's polymerization method was used to obtain the free energy term due to the bond connectivity. An analytic expression for the Helmholtz free energy of the square-well chain fluids was obtained. The expression without adjustable parameters leads to the thermodynamic consistent predictions of the compressibility factors, residual internal energy and constant-volume heat capacity for dimer, 4-mer, 8-mer and 16-mer square-well fluids. The results are in good agreement with the Monte Carlo simulation. To obtain the MC data of residual internal energy and the constant-volume heat capacity needed, NVT MC simulations were performed for these square-well chain fluids.     

Propylene Polymerization Catalyzed by Bis(R_3-indenyl) Zirconium Dichloride/Aluminoxane──Synthesis of Metallocenes and Influence ofSolvent Polarity on Polymerization

Three unbridged metallocenes, bis(2,4,7-Me3-indenyl)zirconium dichloride(1) , bis(2-Me-4, 7-Et2-indenyl)zirconium dichloride (2) and bis (2, 4, 6-Me3-indenyl) zirconium dichloride (3) were synthesized. The effect of solvent polarity on propylene polymerization catalyzed by the metallocenes in the presence of methylaluminoxane(MAO) and triisobutylaluminum(TIBA) was investigated in the toluene/CH2Cl2 mixed solvent. Changing the solvent polarity was found to influence the catalytic activity, polymer molecular weight and stereospecificity of the catalysts. The changes in the position of the substituents on the ligand caused the different responses of the catalyst to the changes in solvent polarity. The isotactic stereosequence of polypropylene was found to increase with the increase in the polarity of the reaction medium.     

Studies on the Basic Conformation of Lysozyme by Electrospray Ionization-Mass Spectrometry (ESI- MS)

In the present work, 2-mercaptoethanol and dithiothreitol were used to hydrogenise the internal disulfide bond in lysozyme. The experimental results indicate that the charge distribution of the proteins are different in the reaction process. From the calculated molecular weight, the reduction process of the disulfide bond in the molecules can be described, and the number of the disulfide bonds in the molecule can also be determined.     

关于麦克劳林公式中余项的注记

结合具体例子讨论了麦克劳林公式中的余项形式,指出对于给定的麦克劳林多项式,用定义(直接法)获得的余项形式不唯一.利用常见初等函数的麦克劳林公式(间接法)得到的余项形式被讨论,该余项形式可能不是麦克劳林公式中的余项,但具有误差分析的价值.最后,建议在教材中引入“函数的n阶麦克劳林多项式”称谓,用于区别“n次麦克劳林多项式”,补充余项细节,降低学习难度.     

Preparation of optical active polydiacetylene through gelating and the control of supramolecular chirality

Achiral diacetylene 10,12-pentacosadinoic acid (PCDA) and a chiral low-molecular-weight organogelator could form co-gel in organic solvent and it could be polymerized in the presence of Zn(II) ion or in the corresponding xerogel under UV-irradiation. Optically active polydiacetylene (PDA) were subsequently obtained. Supramolecular chirality of PDA could be controlled by the chirality of gelators. Left-handed and right-handed helical fibers were obtained by using Land D-gelators in xerogels respectively, and...     

马尔科夫链在高等数学教学效果评价中的应用

马尔科夫链是研究事物在随机过程中不同状态之间变化规律的一种分析方法.利用常用类型的马尔科夫链的稳定性理论,构建了一种把学习过程中的"进步程度"作为主要依据对学生群体进行形成性评价的数学模型,同时对于不同教学方式下的两个学生群体在高等数学课程中的未来学术表现进行了比较性的预测和评价,分析了在大众化教育时代"实验班"这种精英教育模式的有效性,也为任课教师提前采取恰当的教学干预提供了科学依据.     

旋转内接悬臂梁的刚柔耦合动力学特性分析

对固结于旋转刚环上内接柔性梁的刚柔耦合动力学特性进行了研究. 在精确描述柔性梁非线性变形基础上, 利用Hamilton变分原理和假设模态法, 在计入柔性梁由于横向变形而引起的轴向变形二阶耦合量的条件下, 推导出一次近似耦合模型. 忽略柔性梁纵向变形的影响,给出一次近似简化模型,引入无量纲变量, 对简化模型做无量纲化处理. 首先分析在非惯性系下内接悬臂梁的动力学响应, 并与外接悬臂梁进行比较; 其次研究内接悬臂梁的稳定性;最后分析内接悬臂梁失稳临界转速的收敛性. 研究发现, 与外接悬臂梁存在动力刚化效应不同,内接悬臂梁存在着动力柔化效应; 给出了内接悬臂梁无条件稳定的临界径长比以及失稳的临界转速的计算方法; 若第一阶固有频率随转速增大而减小,则该内接悬臂梁处于有条件稳定; 随着模态截断数的增加,内接悬臂梁失稳的临界转速减小且有收敛值. 关键词： 内接悬臂梁 一次近似简化模型 动力柔化 临界转速     

氢负离子在变形球面附近的光剥离

利用理论模型成像方法, 对氢负离子在变形球面附近的光剥离进行了研究. 首先, 推导出了光剥离电子通量的计算公式, 然后对电子通量分布和光剥离截面进行了计算.结果表明: 平面效应只在一定范围内对氢负离子的光剥离过程产生影响. 在距离z轴比较近的区域, 球面效应起主要作用, 电子通量分布和光剥离截面与只有球面存在的情况一致, 此时平面效应可以忽略; 距离z轴较远的区域, 平面效应和球面效应共同起作用, 此时变形球面对光剥离过程会产生比较大的影响. 当球面半径和氢负离子到球面之间的距离给定, 随着入射光子的能量增大, 光剥离电子通量的振幅先增大后减小, 然后又慢慢增大, 振荡频率增大.当固定球面与氢负离子之间的距离, 随着球面半径的增大, 光剥离电子的通量趋向于只存在球面的情况.因此, 可以通过改变入射光子能量和球面的半径对氢负离子的光剥离进行调控. 本文的结果对于研究负离子体系在曲面附近的光剥离及光剥离 显微问题的实验研究具有一定的参考价值. 关键词： 理论模型成像方法 光剥离电子通量 光剥离截面 变形球面     

(1+1)维非局域非线性介质的边界对表面孤子的影响

对非局域非线性介质中, (1+1)维表面亮孤子进行了研究, 主要考虑了边界对孤子的影响. 首先, 在归一化系统中, 对于给定的边界条件, 求出了表面孤子的解析解, 得到了表面孤子的临界功率和平衡位置. 其次, 在数值模拟中, 发现当样品宽度太小时, 受到边界影响而很难形成表面孤子, 只有当样品宽度足够大时, 边界对孤子的影响可以忽略, 从而形成稳定传输的孤子, 并与解析的结果相似. 此外, 还考虑了在光束偏离平衡位置入射的情况下, 边界对孤子的影响, 发现此时光束在边界附近做周期性震荡, 相当于体介质中双光束相互作用的结果, 两者运动轨迹与震荡周期完全符合. 关键词： 非局域非线性 边界 样品宽度 周期震荡