由~*-正则半群簇的Mal’cev积生成的簇

本文试图从泛代数的角度来研究*-正则半群．首先,我们定义了*-关系态射,讨论了它的性质;然后,用*-关系态射作为桥梁,刻划了二个*-正则半群簇的Mal’cev积生成的*-正则半群簇．特别地,我们确定了形如〈uog〉〈uoReB〉,〈uoReg〉的*-正则半群簇．     

High-throughput computational material screening of the cycloalkane-based two-dimensional Dion—Jacobson halide perovskites for optoelectronics

Two-dimensional (2D) layered perovskites have emerged as potential alternates to traditional three-dimensional (3D) analogs to solve the stability issue of perovskite solar cells. In recent years, many efforts have been spent on manipulating the interlayer organic spacing cation to improve the photovoltaic properties of Dion—Jacobson (DJ) perovskites. In this work, a serious of cycloalkane (CA) molecules were selected as the organic spacing cation in 2D DJ perovskites, which can widely manipulate the optoelectronic properties of the DJ perovskites. The underlying relationship between the CA interlayer molecules and the crystal structures, thermodynamic stabilities, and electronic properties of 58 DJ perovskites has been investigated by using automatic high-throughput workflow cooperated with density-functional (DFT) calculations. We found that these CA-based DJ perovskites are all thermodynamic stable. The sizes of the cycloalkane molecules can influence the degree of inorganic framework distortion and further tune the bandgaps with a wide range of 0.9—2.1 eV. These findings indicate the cycloalkane molecules are suitable as spacing cation in 2D DJ perovskites and provide a useful guidance in designing novel 2D DJ perovskites for optoelectronic applications.     

分子印迹TiO2纳米管阵列的制备与选择性光电催化降解邻苯二甲酸二乙酯

以邻苯二甲酸二乙酯(DEP)为模板分子,在TiO2纳米管阵列(TNA)上沉积了能识别DEP分子的TiO2纳米颗粒,制备了DEP分子印迹型TNA(DM-TNA)。X射线衍射(XRD)测试表明,DM-TNA的晶体结构是锐钛矿。扫描电镜(SEM)测试显示颗粒大小约为20 nm的TiO2纳米颗粒均匀地涂覆在TNA的管壁上。光电催化降解DEP和2,4-二氯苯酚(DCP)的结果表明,DM-TNA降解DEP的活性高于非分子印迹TNA(NM-TNA),而DM-TNA降解DCP的活性低于NM-TNA。DM-TNA降解DEP的速率常数是NM-TNA的2.76倍。     

熔合碎裂模型和ALADIN多重碎裂数据

我们用非完全熔合碎裂模型分析了600MeV/u的Au与Cu碰撞后弹剩余核多重碎裂的ALADIN实验结果.由于非完全熔合碎裂模型可以将描述热核形成的动力学和描写热核瞬时多重碎裂的统计模型融为一体,所以只需适当调整与激发能有关的模型参数,就能很好地再现ALADIN数据.     

也谈数学美—补美思想的数学应用

也谈数学美—补美思想的数学应用沈山剑（江苏省东台师范学校２２４２００）“美是真理的光辉”，对科学美的完善和追求，常常会为产生新的发明、发现新的理论提供重要线索和有力手段．事实上，当某个理论、某个问题或某个对象，无论是其思想内容，还是其形式方法，尚未完...     

二氧化碳热泵热水器充注量的不动点优化

二氧化碳跨临界循环应用于热泵热水器具有供水温度高、能效高的优点,而最优高压控制是保证其高能效的关键之一。为了避免实际系统最优高压控制的复杂性,提出通过系统设计实现最优充注量近似不变的充注量不动点优化方法,可避免最优高压控制,在保证系统高能效运行的同时极大地简化了系统控制。仿真计算表明,通过调节换热器大小并在气体冷却器出口添加高压储罐,可以使不控高压系统的平均能效衰减减小至-0.8%。     

分子印迹搅拌棒提取-HPLC法测定黄柏中的盐酸小檗碱

以铁丝为磁芯,盐酸小檗碱为目标分子,甲基丙烯酸为功能单体,乙二醇二甲基丙烯酸酯为交联剂聚合成分子印迹搅拌棒,并对搅拌棒的制备条件和测定条件进行了选择。用该搅拌棒提取黄柏中的盐酸小檗碱,并用高效液相色谱法进行测定。盐酸小檗碱质量浓度在10~125 mg/L之间与峰面积A呈良好的线性关系,线性回归方程为:A=3.07×103ρ+1.27×106,相关系数r为0.9993,检出限为2.7 mg/L。加样回收率在94.5%~103.5%之间,RSD为3.3%。     

超音平面叶栅激波损失模型的研究

对超音叶栅极限特征线以前流场特征的分析表明,外伸波系导致的总压损失主要受无量纲前缘半径(R_(le))和来流马赫数(Ma_(∞))影响。通过对理论解的简化,本文建立了计算外伸波系引起的总压损失的经验关系式。相比以前的损失模型,该关系式在0.0074R_(le)0.0148,1.1Maa_(∞)2.1时具有更高的精度。针对超音叶栅由未启动状态向启动状态转变的过渡状态,在分析前缘内伸波的激波形态时,本文认为采用内伸波波阵面和流道内流线始终垂直的处理方式更加符合内伸波波后亚音的流动特征,并依此建立了过渡状态下内伸波损失计算模型。通过和已有模型估算结果以及实验结果的对比可知,在过渡状态下,采用本文提出的内伸波损失模型,能够准确计算超音叶栅的前缘内伸激波损失。     

Thermal Hysteresis in La2/3 Ca1/3 MnO3 Films Grown on Tilted SrTiO3 Substrates and Influence of External Magnetic Field

Thermal hysteresis in the resistivity of La2/3 Cu1/3MnO3 thin films grown on tilted SrTiO3 substrates is simulated by using the random network model on the basis of mixed-phase percolation between metallic and insulating domains, The metallic-insulating transition temperatures during the warming process are lower than those during the cooling process due to the difference in fraction of metallic domains between warming and cooling process. With an external magnetic field, the metallic-insulating transition temperatures shift to a higher value and the resistivities are reduced. The excellent agreement between the simulation and the experimental data further verifies that phase separation plays a crucial role in the transport process of La2/3Ca1/3MnO3 thin films.