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971.
Jun C Xue Y Liu R Wang M 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2011,79(5):1406-1410
The toxic interaction of methanol, ethanol and propanol with bovine hemoglobin (BHb) at protein molecular level was studied by resonance light scattering (RLS), fluorescence, ultraviolet-visible absorption (UV-vis) and circular dichroism (CD) techniques. The experimental results showed that the three alcohols all had toxic effects on BHb and the effects increased along with the increasing alcohol dose. The results of RLS and fluorescence spectroscopy showed that alcohols can denature BHb. They changed the microenvironment of amino acid residues and led to molecular aggregation. The decreasing order of the influence is propanol, ethanol and methanol. The results of UV-vis and CD spectra revealed that alcohols led to conformational changes of BHb, including the loosening of the skeleton structure and the decreasing of α-helix in the second structure. The changes generated by propanol were much larger than those by methanol and ethanol. 相似文献
972.
运用流式细胞仪和膜片钳技术研究La3+,Gd3+,Yb3+三种稀土离子诱导大鼠背根神经元DRG凋亡以及膜上钾离子通道的影响。结果表明:10,100,1000μmol.L-1LaCl3和GdCl3处理DRG神经元96 h,细胞不出现凋亡;YbCl3处理96 h,细胞的凋亡率明显递增。胞外La3+,Gd3+,Yb3+抑制瞬间外向钾电流IA,使IA的激活和失活过程都显著右移,抑制和右移的程度La3+最弱,Gd3+次之,Yb3+最强;胞内的La3+,Gd3+,Yb3+抑制延迟整流钾电流IK,抑制的程度也呈增长趋势。稀土离子在胞内外的结合位点不同;Yb3+较La3+和Gd3+的神经毒性强。 相似文献
973.
铋(Bi)和铅(Pb)都是重元素,有很强的自旋-轨道耦合作用,由于原子半径接近,可形成丰富的原子取代合金结构.尽管对高温合金相有了较深入的研究,但对其低温物相的结构和超导物性的认识还很不全面.本文采用低温共沉积和低温退火的方法,在Si(111)-(7×7)衬底上制备了一种基于Bi(110)单晶结构中部分Bi原子被Pb取代的铅铋合金低温相超薄膜新结构,利用扫描隧道显微术(STM)对其结构和电子学性质进行了表征.通过结构表征,确定了合金薄膜表面呈现21/2×21/2R45°重构的PbBi3合金相,其母体Bi(110)结构中25%的Bi原子被Pb取代了.通过STM谱学测量,发现合金相PbBi3为超导相.变温实验表明, PbBi3相的超导转变温度为6.13 K.在外加垂直磁场下出现的磁通涡旋结构表明PbBi3薄膜是第Ⅱ类超导体,估算出上临界磁场的下限为0.92 T.测量了由Bi(110)-PbBi3组成的共面型和台阶型正常金属-超导体异质结中... 相似文献
974.
Ning Zhang 《中国物理 B》2022,31(7):74212-074212
Optical metasurfaces are two-dimensional arrays of nano-scatterers that modify optical wavefronts at subwavelength spatial resolution. They achieve the effect of focusing through phase control under a subwavelength scale, and are called metalenses. They are poised to revolutionize optics by enabling complex low-cost systems. However, there are severe monochromatic aberrations in the metasurfaces. In this paper, the coma of the long-wave infrared optical system is eliminated through a single-layer metasurface. By changing the phase function, this metalens has a numerical aperture of 0.89, a focal length of 150 μm and a field of view of 120° (0.4@60 line pairs/mm) that enables diffraction-limited monochromatic imaging along the focal plane at a wavelength of 10.6 μm. The designed metasurface maintains a favorable value of the modulation transfer function at different angles. This equipment can be widely used in imaging and industrial processing. 相似文献
975.
Recent advances in two-dimensional layered and non-layered materials hybrid heterostructures 下载免费PDF全文
With the development of Moore's law, the future trend of devices will inevitably be shrinking and integration to further achieve size reduction. The emergence of new two-dimensional non-layered materials (2DNLMs) not only enriches the 2D material family to meet future development, but also stimulates the global enthusiasm for basic research and application technologies in the 2D field. Van der Waals (vdW) heterostructures, in which two-dimensional layered materials (2DLMs) are physically stacked layer by layer, can also occur between 2DLMs and 2DNLMs hybrid heterostructures, providing an alternative platform for nanoelectronics and optoelectronic applications. Here, we outline the recent developments of 2DLMs/2DNLMs hybrid heterostructures, with particular emphasis on major advances in synthetic methods and applications. And the categories and crystal structures of 2DLMs and 2DNLMs are also shown. We highlight some promising applications of the heterostructures in electronics, optoelectronics, and catalysis. Finally, we provide conclusions and future prospects in the 2D materials field. 相似文献
976.
王国超颜树华杨俊林存宝魏春华杜志广 《光学学报》2015,(4):167-175
飞秒光梳的出现为实现高精度绝对距离测量提供了诸多有效方法,并有望直接应用于激光雷达、卫星编队飞行和空间引力测量等空间探测任务。从未来空间精密测距的精度需求出发,提出在飞行时间法辅助测距的基础上利用光学脉冲互相关分析技术将目标距离测量直接溯源到光梳重复频率的测量方法,建立了飞秒光梳测距基本模型,进行了飞秒脉冲互相关理论分析,并开展了互相关及测距仿真实验。仿真结果表明,在目标距离为10 km以及重复频率扫描精度0.01 Hz条件下,进行非模糊量程内线性测距的测量精度优于450 nm,测距残余误差的峰谷(PV)值为780 nm,验证了该方法实现亚微米级甚至纳米量级大量程空间精密测距的可行性。 相似文献
977.
Foam consolidation and drainage 总被引:1,自引:0,他引:1
A theoretical model of foam as a consolidating continuum is proposed. The general model is applied to foam in a gravity settler. It is predicted that liquid drainage from foam in a gravity settler begins with a slow drainage stage. Next, a stage with faster drainage occurs where the drainage rate doubles compared to the initial stage. The experiments conducted within the framework of this work confirmed the theoretical predictions and allowed measurements of foam characteristics. Foams of three different concentrations of Pantene Pro-V Classic Care Solutions shampoo were studied, as well as the addition of polyethylene oxide (PEO) in one case. The shampoo's main foaming components are sodium lauryl sulfate and sodium laureth sulfate. It is shown to what extent foam drainage is slowed down by using higher shampoo concentrations and how it is further decreased by adding polymer (PEO). 相似文献
978.
Bei Zhang Yan Fang Zhao Xin Zhai Wei Jie Fan Jun Ling Ren Chun Fu Wu Ping Gong 《中国化学快报》2012,23(8):915-918
A new series of diaryl urea derivatives bearing N-acylhydrazone moiety were designed and synthesized.All the target compounds were evaluated for their antiproliferative activities against human leukemia cell line(HL-60),human lung adenocarcinoma epithelial cell line(A549) and human breast cancer cell line(MDA-MB-231) in vitro by standard MTT assay.The pharmacological results indicated that some compounds exhibited promising antitumor activities.Compound 1j showed the most potent antiproliferative activity against the tested three cell lines with IC values of 0.13 mmol/L,0.7 mmol/L and 0.5 mmol/L,respectively. 相似文献
979.
The binary random in-chain silyl-hydride multi-functionalized poly(styrene/butadiene/isoprene and dimethyl[4-(1-phenylvinyl) phenyl]silane)(PS-DPESiH,PB-DPESiH,PI-DPESiH) copolymers were successfully synthesized.These functionalized copolymers were prepared in hexane with n-BuLi as the initiator at 50℃for 4 h.The silyl-hydride groups were introduced into polymer backbones quantitatively by living anionic polymerization.The copolymers were determined through ’H NMR,size exclusion chromatography(SEC) and differential scanning calorimetry(DSC) techniques,while the number of silyl-hydride groups was calculated and discussed. 相似文献
980.
Xing Li Zhang Yang Yang Liu Jian He Wei Yun Yang Zheng Zhang Jun Qing Huang Huai Qiong Chen Yu Jun Liu 《中国化学快报》2012,23(6):727-730
We used whole-tree agarwood-induction technology to produce agarwood from Aquilaria sinensis trees within 20 months,and evaluated the quality of this agarwood.The results showed its characteristics were similar to those of high-grade wild agarwood in terms of texture,chemical constituents,essential oil content,and ethanol-soluble extract content,with the lattermost quality far surpassing the requirement of traditional Chinese medicine agarwood,as indicated in Chinese Pharmacopoeia 2010.To the best of our knowledge,this is first study to show that high-quality agarwood can be produced in whole A.sinensis trees via a chemically induced technology. 相似文献