基于奇异值分解和中位数绝对偏差的拉曼成像数据去噪方法

拉曼成像是一种无损伤、无需标记的光谱成像技术,它可以提供样品的不同组分的分子指纹信息以及空间分布特征,相比其他成像技术有着更重要的应用。但是拉曼散射的截面积小,灵敏度低,加上在很多实验中为了观察某些组分的动态分布而缩短扫描时间,导致最终得到的成像数据被噪声干扰,因此往往需要对信号进行去噪处理。常规的算法一般都是基于一个给定的数学模型对光谱进行处理,容易造成过滤波,使得信号失真;另外,在处理拉曼成像数据时,常规算法往往是对数据进行逐条光谱去噪,从而忽略了多条光谱之间的相互关系,导致最终的拉曼图像仍然受许多噪点干扰。因此,提出了一种基于奇异值分解和中位数绝对偏差的拉曼成像的信号处理方法,用于拉曼成像数据的去噪处理。该方法首先对拉曼成像数据进行奇异值分解,获得一个奇异值矩阵与两个正交矩阵;然后通过中位数绝对偏差法对奇异值矩阵中的各奇异值进行离群值检测,选取前k个被连续标记的离群值作为要保留的奇异值,并将其余的奇异值赋值为零,得到新的奇异值矩阵;最后用新的奇异值矩阵与两个正交矩阵重新求解得到去噪后的拉曼成像数据。实验中,首先验证了中位数绝对偏差法确定前k个奇异值的正确性,其次分别从处理后的图像质量和信号波形两方面对比了该算法与常规算法的去噪效果。结果证明,中位数绝对偏差法可以快速地确定出合理的k值大小,而且,依据该k值处理后的成像数据不仅在成像质量上消除了大量的噪点,使得组分的空间分布特征清晰可见,也在信号波形上较完美地保留了微小谱峰,并恢复光谱信号。该算法不同于常规算法,能同时对整个拉曼成像数据进行处理,并保留光谱之间的统计特征,是一种更加有效的拉曼成像数据的去噪方法。     

3度图的最小顶点覆盖问题的多项式时间算法

最小顶点覆盖问题是图论和组合数学中经典的NP-Hard问题之一,在实际问题中有着广泛的应用.本文首先给出最小顶点覆盖问题的若干性质,然后根据这些性质设计了3度图最小顶点覆盖问题的一个多项式时间算法,并通过2个实例对算法进行了说明.     

纤维增强复合材料层合球壳的应力分析

1. 引言本文对受内压的复合材料球壳应用经典层合理论进行应力应变的分析。由一般球形壳体理论的五个平衡方程、六个几何方程及由层合理论导出的六个物理方程,共有十七个独立的方程可求解十七个未知函数,它们是三个中面位移、三个中面应变、三个曲面的曲率变化、五个应力合力、三个合力矩。应用球形壳体的应力函数U以后,得到二个基本微分方程。如为对称铺设此二基本微分方程可以简化。本文用有限差分法解此二基本微分方程。2. 基本方程的推导球壳的平衡方程如下:     

极坐标有限条法解扁球壳问题

本文用有限条法解扁球壳问题,对于轴对称问题与位移和内力沿环向按cosnθ或sinnθ分布的非轴对称问题,分别推导了三类壳元(圆底壳元,圆孔外无限壳元,圆环底壳元)刚度矩阵的精确解。对于沿环向按cosnθ或sinnθ分布的环形面荷载和环形线荷载推导了单元等价节线荷载的表达式。编制了相应的计算程序,计算了典型例题。结果表明,此法具有计算工作量少而计算精度高的优点。     

A NUMERICAL AND ANALYTICAL STUDY ON A TAIL-FLAPPING MODEL FOR FISH FAST C-START＊

The force production physics and the flow control mechanism of fish fast C-start are studied numerically and theoretically by using a tail-flapping model. The problem is simplified to a 2-D foil that rotates rapidly to and fro on one side about its fixed leading edge in water medium. The study involves the simulation of the flow by solving the two-dimensional unsteady incompressible Navier-Stokes equations and employing a theoretical analytic modeling approach. Firstly, reasonable thrust magnitude and its time history are obtained and checked by fitting predicted results coming from these two approaches. Next, the flow fields and vortex structures are given, and the propulsive mechanism is interpreted. The results show that the induction of vortex distributions near the trailing edge of the tail are important in the time-averaged thrust generation, though the added inertial effect plays an important role in producing an instant large thrust especially in the first stage. Furthermore, dynamic and energetic effects of some kinematic controlling factors are discussed. For enhancing the time-averaged thrust but keeping a favorable ratio of it to time-averaged input power within the limitations of muscle ability, it is recommended to have a larger deflection amplitude in a limited time interval and with no time delay between the to-and-fro strokes. The project supported by the CAS (KJCX-SW-L04)     

Preliminary research on the relationship between long-range correlations and predictability

By establishing the Markov model for a long-range correlated time series (LRCS) and analysing its evolutionary characteristics, this paper defines a physical effective correlation length (ECL) τ, which reflects the predictability of the LRCS. It also finds that the ECL has a better power law relation with the long-range correlated exponent γ of the LRCS: τ= Kexp (-γ/0.3)+Y, (0 < γ < 1) -- the predictability of the LRCS decays exponentially with the increase of γ. It is then applied to a daily maximum temperature series (DMTS) recorded at 740 stations in China between the years 1960--2005 and calculates the ECL of the DMTS. The results show the remarkable regional distributive feature that the ECL is about 10--14 days in west, northwest and northern China, and about 5--10 days in east, southeast and southern China. Namely, the predictability of the DMTS is higher in central-west China than in east and southeast China. In addition, the ECL is reduced by 1--8 days in most areas of China after subtracting the seasonal oscillation signal of the DMTS from its original DMTS; however, it is only slightly altered when the decadal linear trend is removed from the original DMTS. Therefore, it is shown that seasonal oscillation is a significant component of daily maximum temperature evolution and may provide a basis for predicting daily maximum temperatures. Seasonal oscillation is also significant for guiding general weather predictions, as well as seasonal weather predictions.     

2,3-二苯基丙烯酸酯在DTBP/CaCl_2作用下的氧化偶联

多甲氧基菲-9-甲酸及酯是合成娃儿藤生物碱及其类似物的关键中间体。实验发现,以DTBP作为氧化剂,CaCl2存在下,能有效提高分子内氧化偶联合成多甲氧基菲-9-甲酸及酯产率,且反应条件温和,后处理方便,为合成许多重要化合物前体菲提供了一种新的思路。     

芳二醛缩氨基酸Schif碱双核配合物的合成及表征(Ⅰ)

合成了两类芳二醛甘氨酸Ｓｃｈｉｆ碱配体及其Ｃｕ（Ⅱ）、Ｚｎ（Ⅱ）、Ｎｉ（Ⅱ）、Ｃｄ（Ⅱ）双核配合物，并对八种配合物进行了元素分析、红外光谱分析、差热热重分析、紫外可见光谱分析，确证了这些配合物的结构．