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排序方式: 共有659条查询结果,搜索用时 62 毫秒
651.
Guang Yue BAI Hai Ke YAN* Institute of Chemistry the Chinese Academy of Sciences Beijing 《中国化学快报》2000,11(12)
Gemini surfactants, as a new generation of surfactants in 1990's1, are the surfactants with two polar groups and two alkyl chains connected with a spacer. The most widely studied gemini surfactants are as follows: [CmH2m+1N (CH3)2- (CH2)S -N (CH3 )2CmH2m+1] Br2, or Cm-CS-Cm(2Br -where Cs stands for its spacer. Studies on their interesting physico chemical properties2,3 have made much progress, predicting that the repulsive interaction between the two head groups, hydrophobic interactio… 相似文献
652.
1 INTRODUCTIONSulfoxideisknowntoformcoordinationcompoundswithLanthanide(Ⅲ)andtheirsyntheses,propertiesandvariousphysicalcharacteristicshavebeenreport-ed〔1~9〕.However,therearesomanydifficultyinpreparingthekindoflanthanidecomplexesbecausetheanionsuseda… 相似文献
653.
1 INTRODUCTIONThe coordination chemistry oftransition metalcomplexeshasbecomeofremark able interestin recentyears.Sotoftetal.reported the structure of Ni( CH3CN) 6·Zn Cl4 〔1〕.Recently,Shyu etal.reported the structure of〔 Ni( bipy) 3〕〔 Fe( CN) 5 ( NO)〕· 3 H2 O〔2〕.Herein we reportthe structure oftitle complex〔 Ni( bipy) 3〕〔 Zn Cl4 〕 which issimilarto theformertwo complexes.Itisvery interesting to synthesizebimetallic compoundsfor both theoreticalstudy and practicalapp… 相似文献
654.
三甲川菁染料敏化TiO2纳米
结构电极的光电化学 总被引:1,自引:0,他引:1
The
photoelectrochemical behaviors of the TiO2 nanostructured porous film
sensitized by cyanine dye were investigated in this paper.The results showed that the
excitaed state level matched the conduction band edge of TiO2
nanoparticle.Therefore the sensitization of the dye can increase the photocurrent
intensity of the TiO2 nanostructured electrode obviously and results in a
red-shift of optical absorption from the ultra-violet region to the visible.As a
result,the light-to-electricity conversion efficiency was improved evidently,the maximum
value of IPCE has reached 12.1%. 相似文献
655.
ZHENG Yue qing * 《高等学校化学研究》1999,(3)
IntroductionPreviously,wereportedthecrystalstructureofK2[Ni(CO3)2(H2O)4][1],whichcrystallizedinthebaylissitetypestructureandwasfoundtobeisostructuralwithK2[Co(CO3)2(H2O)4][2]andK2Mg(CO3)2·4H2O[3].Inordertosystematicallyinvestigatetheoccurrenceoftheco… 相似文献
656.
IntroductionAmrinon,asyntheticbipyridinederivative,nonglycosideandnoncatecholaminecar-diotonicstimulant,iscurrentlyusedinthetreatmentoftheheartfailureandforcardiovascu-larsupportinpediatricpatients.Itpossessespotentcardiacandbloodvesselspreadingef-fe… 相似文献
657.
1 INTRODUCTIONRecently,anumberofderivativesofbenzothiazepinehavebeenpreparedandstudiedfortheirpharmacologicalactivities〔15〕.Inourpreviouswork,wehaveincorporatedtheβlactamringinto1,5benzothiazepinebyreactionof1,5benzothiazepinewithsomeacylchlorid… 相似文献
658.
PAiRFP1是一种以细菌光敏色素为模板,改造得到的光激活荧光蛋白。与其他光激活荧光蛋白相比,它最大的优势是激发、发射都在近红外区域。本论文围绕该蛋白中含有的8个半胱氨酸残基,开展了定点突变、光谱学检测等工作,发现(1)在8个单突变体中,仅有Cys-29突变改善了光激活蛋白的分子亮度,其它突变都削弱了近红外荧光;(2)伴随着环境氧化、还原条件的改变,C29S突变近红外荧光显著降低,这说明该位点的半胱氨酸残基对于维持该近红外荧光蛋白在氧化还原环境中的稳定性具有重要作用,相关机理尚待深入研究。 相似文献
659.
Weinan E~* Jianfeng LU~ 《数学年刊B辑(英文版)》2007,28(6):665-676
The authors consider the simplest quantum mechanics model of solids,the tight binding model,and prove that in the continuum limit,the energy of tight binding model converges to that of the continuum elasticity model obtained using Cauchy-Born rule.The technique in this paper is based mainly on spectral perturbation theory for large matrices. 相似文献