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71.
Zsombor Gonda Dr. Zoltán Novák 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(47):16801-16806
A new synthetic method was developed for the N‐arylation of pyrazoles using diaryliodonium salts. The transformation does not require any transition‐metal catalyst and provides the desired N‐arylpyrazoles rapidly under mild reaction condition in the presence of aqueous ammonia solution as a mild base without the use of inert atmosphere. The chemoselectivity of unsymmetric diaryliodonium salts was also explored with large number of examples. 相似文献
72.
Hung Truong Ngoc Ádám Adél Varga Gábor Dudás Csilla Kele Zoltán Sipos Pál Pálinkó István 《Structural chemistry》2017,28(2):475-478
Structural Chemistry - 2-Cyano-2-(hydroxyimino)dithioacetic acid was prepared starting from cyanoacetic acid methylester via 2-cyano-2-(hydroxyimino)acetic acid methylester. Before thionation, the... 相似文献
73.
Zoltán-István Szabó Réka Gál Zsolt Gáll Szende Vancea Emőke Rédai Ibolya Fülöp Emese Sipos Gabriella Donáth-Nagy Béla Noszál Gergő Tóth 《Journal of inclusion phenomena and macrocyclic chemistry》2017,88(1-2):43-52
Rufinamide (RUF) was characterized in terms of cyclodextrin (CD) complexation in order to improve its aqueous solubility. Binary systems of RUF with three CDs—β-cyclodextrin (β-CD), randomly methylated-β-cyclodextrin (RAMEB) and sulfobutylether-β-cyclodextrin (SBE-β-CD)—were characterized with a wide variety of analytical techniques. Liquid state characterization was carried out by complementary techniques such as nuclear magnetic resonance spectroscopy (NMR), capillary electrophoresis (CE), mass spectrometry (MS) and phase solubility studies. The latter revealed that the stability of the complexes decreased in the order of RAMEB?>?β-CD?>?SBE-β-CD. AL-type diagrams were obtained in all cases, characteristic of 1:1 stoichiometry, with a maximum of over 15-fold increase in RUF solubility, when complexed with RAMEB. NMR Job plot and MS studies confirmed phase solubility results, regarding the binding stoichiometry. 1H NMR and 2D ROESY investigations revealed the inclusion of the triazole moiety of RUF, confirmed by molecular modeling. Solid state complexation in 1:1 molar ratio was carried out by kneading method and investigated by differential scanning calorimetry (DSC) and infrared spectroscopy (IR). Comparative dissolution studies indicated an over two-fold improvement in dissolution efficacy of the kneaded products, when compared to the pure drug. Results of the present study might pave the way for a drug formulation with improved bioavailability. 相似文献
74.
Ms. Orsolya Tischler Mr. Balázs Tóth Dr. Zoltán Novák 《Chemical record (New York, N.Y.)》2017,17(2):184-199
This account collects the developments and transformations which avoid the utilization of harsh reaction conditions in the field of palladium catalyzed, ortho‐directed C?H activation of aniline derivatives from the first attempts to up‐to‐date results, including the results of our research laboratory. The discussed functionalizations performed under mild conditions include acylation, olefination, arylation, alkylation, alkoxylation reactions. Beside the optimization studies and the synthetic applications mechanistic investigations are also presented. 相似文献
75.
Zoltán Lóránt Nagy 《Journal of Graph Theory》2017,84(4):566-580
We study the existence and the number of k‐dominating independent sets in certain graph families. While the case namely the case of maximal independent sets—which is originated from Erd?s and Moser—is widely investigated, much less is known in general. In this paper we settle the question for trees and prove that the maximum number of k‐dominating independent sets in n‐vertex graphs is between and if , moreover the maximum number of 2‐dominating independent sets in n‐vertex graphs is between and . Graph constructions containing a large number of k‐dominating independent sets are coming from product graphs, complete bipartite graphs, and finite geometries. The product graph construction is associated with the number of certain Maximum Distance Separable (MDS) codes. 相似文献
76.
Mónika Sipiczki Dávid F. Srankó Ákos Kukovecz Zoltán Kónya Pál Sipos István Pálinkó 《Chemical Papers》2011,65(6):840-846
Double hydroxides containing alkaline earth and iron(III) ions were synthesised by the co-precipitation method. The solid
materials obtained were characterised by a range of instrumental methods (powder X-ray diffractometry, thermogravimetry, scanning
electron microscopy, energy dispersive X-ray fluorescence spectrometry, elemental maps, and infrared spectroscopy). It was
found that the Ca(II)Fe(III), Mg(II)Fe(III), and Ba(II)Fe(III) double hydroxides had layered structures, while Sr(II)Fe(III)
had not. The optimum conditions for synthesis of Ca(II)Fe(III)-layered double hydroxides (materials to be used in further
studies) were also elaborated. 相似文献
77.
We discuss several techniques which have the potential to decrease the computational expenses of high-order coupled-cluster (CC) methods with a reasonable loss in accuracy. In particular, the CC singles, doubles, and triples (CCSDT) as well as the CC singles, doubles, triples, and perturbative quadruples [CCSDT(Q)] methods are considered, which are frequently used in high-precision model chemistries for the calculation of iterative triples and quadruples corrections. First, we study the possibilities for using active spaces to decrease the computational costs. In this case, an active space is defined and some indices of cluster amplitudes are restricted to be in the space. Second, the application of transformed virtual orbitals is investigated. In this framework, to reduce the computation time the dimension of the properly transformed virtual one-particle space is truncated. We have found that the orbital transformation techniques outperform the active-space approaches. Using the transformation techniques, the computational time can be reduced in average by an order of magnitude without significant loss in accuracy. It is demonstrated that high-order CC calculations are possible for considerably larger systems than before using the implemented techniques. 相似文献
78.
Kilár A Dörnyei Á Bui A Szabó Z Kocsis B Kilár F 《Journal of mass spectrometry : JMS》2011,46(1):61-70
The structural variations in the rough-type endotoxins [lipopolysaccharides (LPSs)] of Shigella sonnei mutant strains (S. sonnei phase II-4303, R41, 562H and 4350) were investigated by Matrix-assisted laser desorption/ionization time-of-flight mass spectrometry (MALDI-TOF-MS) and tandem MS. A series of S. sonnei mutants had previously been the subject of analytical studies on the biosynthesis of heptose components in the core oligosaccharide region of LPSs. This study gives a complete overview on the structures of the full core and lipid A of S. sonnei mutant strains by MS. We found that the LPSs of the isogenic rough mutants were formed in a step-like manner containing 0:1:2:3 heptose in the deep core region of 4350, 562H, R41 and 4303, respectively, and the longest LPS from the mutant S. sonnei 4303 contained also five hexoses. The structural variations in the lipid A moiety and in the oligosaccharide part of the intact LPS were followed by MALDI-TOF-MS/MS. For the dissolution and the ionization of the samples, 2,5-dihydroxybenzoic acid in citric acid solution was applied as matrix. The detailed evaluation of the mass spectra indicates heterogeneity in the lipid part due to the differences in the phosphate and fatty acid composition. 相似文献
79.
Molnár A Kapros A Párkányi L Mucsi Z Vlád G Hermecz I 《Organic & biomolecular chemistry》2011,9(19):6559-6565
The palladium-catalyzed Suzuki-Miyaura cross-coupling reactions of halo derivatives of 4H-pyrido[1,2-a]pyrimidin-4-one with (het)arylboronic acids allow easy access to (het)aryl and vinyl derivatives of this bicycle in good to excellent yields, even from chloro derivatives. The sequence of reactivity of the halogen in the different positions of the ring system was also investigated. 6-Phenyl-4H-pyrido[1,2-a]pyrimidin-4-one could be prepared by thermal cyclization of isopropylidene (6-phenylpyrid-2-ylamino)methylenemalonate, together with a small amount of 7-phenyl-1,4-dihydro-1,8-naphthyridin-4-one. 相似文献
80.
A question of Yves Meyer motivated the research concerning “time” subordinations of real functions. Denote by B1a{\mathcal {B}}_{1}^{\alpha} the metric space of functions with Lipschitz constant 1 defined on [0,1], equipped with the complete metric defined via the
supremum norm. Given a function g ? B1ag\in {\mathcal {B}}_{1}^{\alpha} one obtains a time subordination of g simply by considering the composite function Z=g○f, where f∈ℳ:={f:f(0)=0, f(1)=1 and
f
is a continuous nondecreasing function on [0,1]}. The metric space Ea=M×B1a\mathcal {E}^{\alpha}=\mathcal {M}\times {\mathcal {B}}_{1}^{\alpha} equipped with the product supremum metric is a complete metric space. In this paper for all α∈[0,1) multifractal properties of g○f are investigated for a generic (typical) element (f,g)∈ℰ
α
. In particular we determine the generic H?lder singularity spectrum of g○f. 相似文献