自制数字式检流计

本文介绍一种自制的数字式检流计。仪器具有精度高、性能稳、调节方便、造价低、不易损坏等特点。     

Investigation on Noise Pollution Comprehensive Treatment of Distribution Transformer in Living Area

In the current paper, which deals with the noise pollution excited by distribution transformers in the living area, a comprehensive treatment scheme is put forward for the purpose of reducing the sound pressure level emitting into the environment. In accordance with the associated test standard, the sound pressure levels of distribution transformer and surrounding environment are not only tested but analyzed as well. The measurements were carried out with the frequency analysis of the 1/3 octave resolution, with the center frequencies at 125 Hz, 250 Hz, 400 Hz, and 500 Hz. As illustrated, on the basis of the measurement results, the frequency of noise at 500 Hz of distribution transformer causes the major noise pollution in the surrounding environment. This measurement result is in line with the noise frequency characteristics of distribution transformer. There are two transmission routes of noise: i) the noise excited by distribution transformer transmits by means of the wall of distribution room, and ii) part of noise spreads through the ground of distribution room. Accordingly, acoustic shield and vibration isolation device are applied for the reduction of the low frequency noise emitted through the above two paths. Aimed at applying the appropriate acoustic material and vibration mounting, the evaluation of the noise reduction and vibration absorption is carried out in accordance with the sound and vibration insulation theory. Following the noise treatment, the transformer and environment noise are measured again. The corresponding findings shed light on the fact that the sound level satisfied the requirement of limits of the ordinance. The proposed noise treatment scheme can be applied to the existing power distribution facilities for controlling the sound levels that reach a point where it is comparatively more unobjectionable.     

A regularized strong duality for nonsymmetric semidefinite least squares problem

The nonsymmetric semidefinite least squares problem (NSDLS) is to find a nonsymmetric semidefinite matrix which is closest to a given matrix in Frobenius norm. It is an extension of the semidefinite least squares problem (SDLS) and has important application in the area of robotics and automation. In this note, by developing the minimal representation of the underlying cone with the linear constraints, we obtain a regularized strong duality with low-dimensional projection for NSDLS. Further, we study the generalized differential properties and nonsingularity of the first order optimality system about the dual problem. These theoretical results demonstrate that we can solve NSDLS as good as the current Lagrangian dual approaches to SDLS.     

体视显微镜与CCD成像系统在高阶贝塞尔光束光斑测量中的应用

主要对光学测量仪器体视显微镜与CCD成像系统在高阶贝塞尔光束光斑测量中的应用进行分析,通过以非相干LED绿光经过螺旋相位板和轴棱锥产生的高阶贝塞尔(Bessel)光束为例,模拟出沿轴向不同距离处的截面光强分布图,并与相应的实验参数(如:最大无衍射距离、中心暗斑直径等)进行比较。实验结果表明,体视显微镜与CCD成像系统的测量结果相吻合,但是体视显微镜测量误差较大会影响测量结果的准确度。     

Escape from Hydrofunctionalization: Palladium Hydride-Enabled Difunctionalization of Conjugated Dienes and Enynes

Palladium hydrides are traditionally employed in hydrofunctionalization (i.e. monofunctionalization) of conjugated dienes and enynes, owning to its facile protic hydropalladation of electron-rich (or neutral) unsaturated bonds. Herein, we report a mild PdH-catalyzed difunctionalization of conjugated dienes and enynes. This protocol is enabled by the chemoselectivity switch of the initial hydropalladation step achieved by visible light enhancement of hydricity of PdH species. This method allows for cascade annulation of dienes and enynes with various easily available and abundant substrates, such as acrylic acids, acrylic amides, and Baylis–Hillman adducts, toward a wide range of alkenyl or alkynyl lactones, lactams, and tetrahydrofurans. This protocol also provides an easy access to complex spiro-fused tricyclic frameworks.     

Modular construction for the programmed assembly of molecular crystals and liquid crystals

This research aims to develop schemes for the programmed assembly of molecular materials. The underlying premise guiding this work is that structural information stored in the molecular constituents dictates their condensed phase organization (i.e. through the sum of all non-covalent interactions). The challenge then is to design molecular building blocks that encode this information in a decipherable manner. Our approach has relied on the use of organic nanoarchitectures, which we believe will serve as “modular units” for programmed assembly. Large molecules of well defined constitution and geometry offer the advantage that a high level of information can be incorporated into a single unit. The design and synthesis of nanoscale macrocyclics and macrobicyclics for this purpose has been achieved. Studies on the solution aggregation of the macrocyclics have provided a unique opportunity to glimpse some of the interactions which may influence solid state ordering. These building blocks are being used for the rational design of novel materials such as porous organic crystals and tubular mesophases.