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排序方式: 共有224条查询结果,搜索用时 46 毫秒
61.
This paper deals with the separation and characterization of alkyl phenol formaldehyde resins demulsifier by infrared spectrometry and nuclear magnetic resonance spectroscopy after separation of the different surfactants and low molecular additives by adsorption chromatography. Firstly, the types of surfactants are identified by methylene blue chloride-chloroform test method and the elemental analysis such as Ca, K, Mg, Na, P, S and N. Then, the different surfactants and low molecular components are separated by adsorption chromatography after parts of low molecular components are dried in an oven, and the molecular weight distribution is measured by gel permeation chromatography also. Finally, the separated surfactants are determined by Fourier transform infrared (FTIR) spectrometry and nuclear magnetic resonance (NMR) spectroscopy. The distortionless enhancement by polarization transfer (DEPT), H, C correlated spectroscopy (H, C-COSY), H, H correlated spectroscopy (H, H-COSY) and heteronuclear multiple-bond correlation (HMBC) spectroscopy are applied to determine the molecular structures. 相似文献
62.
Biwu Chu Yuan Liu Hao Li Yongcheng Jia Jun Liu Qing Cao Tianzeng Chen Peng Zhang Qingxin Ma Prof. Xiao Cheng Zeng Prof. Joseph S. Francisco Prof. Hong He 《Angewandte Chemie (International ed. in English)》2023,62(25):e202304017
N2O5 is an important intermediate in the atmospheric nitrogen cycle. Using a flow tube reactor, N2O5 was found to be released from the TiO2 surface during the photocatalytic oxidation of NO2, revealing a previously unreported source of N2O5. The rate of N2O5 release from TiO2 was dependent on the initial NO2 concentration, relative humidity, O2/N2 ratio, and irradiation intensity. Experimental evidence and quantum chemical calculations showed that NO2 can react with the surface hydroxyl groups and the generated electron holes on the TiO2, followed by combining with another NO2 molecule to form N2O5. The latter was physisorbed on TiO2 and had a low adsorption energy of −0.13 eV. Box model simulations indicated that the new source of N2O5 released from TiO2 can increase the daytime N2O5 concentration by up to 20 % in urban areas if abundant TiO2-containing materials and high NOx concentrations were present. This joint experimental/theoretical study not only demonstrates a new chemical mechanism for N2O5 formation but also has important implications for air quality in urban areas. 相似文献
63.
Shao C She Z Guo Z Peng H Cai X Zhou S Gu Y Lin Y 《Magnetic resonance in chemistry : MRC》2007,45(5):434-438
We report the unambiguous assignments of the (1)H and (13)C NMR spectra of one new natural product, namely, 6,8-di-O-methyl versiconol (1) together with one known anthraquinone aversin (2) and two xanthones 5-methoxysterigmatocystin (3) and sterigmatocystin (4). These compounds were all isolated from the mangrove endophytic fungus ZSUH-36 from the South China Sea. 1D and 2D NMR experiments including COSY, HMQC and HMBC were used to elucidate the structures. Variations in the (1)H NMR spectrum of 6,8-di-O-methyl versiconol (1) were also observed in the temperature range 25-75 degrees C. In addition, the plausible biogenetic path from 1 to 2 is discussed. 相似文献
64.
We report a new method to synthesize monodisperse zinc blende HgTe nanocrystals at room temperature in noncoordinating solvent-octadecene. Thiol was needed to control the reaction at a suitable nucleation and growth speed. In the early stage of the reaction, HgTe nanocrystals formed aggregates, and then the aggregates were dispersed and individual dot-shaped nanocrystals were formed with stronger photoluminescence emitting. UV-vis, photoluminescence, and TEM have been used to study the properties of as-prepared HgTe nanocrystals. 相似文献
65.
Geng Z Yan P Wang Y Yao X Han Y Liang J 《The journal of physical chemistry. A》2007,111(39):9961-9968
A computational study of the platinum-catalyzed cyclopropanation reaction with olefin is presented. The model system is formed by an ethylene molecule and the active catalytic species, which forms from a CH2 fragment and the Cl2Pt(PH3)2 complex. The results show that the active catalytic species is not a metal-carbene of the type (PH3)2Cl2Pt=CH2 but two carbenoid complexes which can exist in almost two degenerate forms, namely (PH3)2Pt(CH2Cl)Cl (carbenoid A) and (PH3)Pt(CH2PH3)Cl2 (carbenoid B). The reaction proceeds through three pathways: methylene transfer, carbometalation for carbenoid A, and the reaction of a monophosphinic species for carbenoids (A and B). The most favored reaction channel is methylene transfer pathway for (PH3)Pt(CH2PH3)Cl2 (carbenoid B) species with a barrier of 31.32 kcal/mol in gas phase. The effects of dichloromethane, THF, and benzene solvent are investigated with PCM method. For carbenoid A, both methylene transfer and carbometalation pathway barriers to reaction become remarkably lower with the increasing polarity of solvent (from 43.25 and 52.50 kcal/mol for no solvent to 25.36 and 38.53 kcal/mol in the presence of the dichloromethane). In contrast, the reaction barriers for carbenoid B via the methylene transfer path hoist 6.30 kcal/mol, whereas the barriers do not change significantly for the reaction path of a monophosphinic species for carbenoids (A and B). 相似文献
66.
This note is devoted to a generalization of the Strassen converse. Let gn:R∞→[0,∞], n?1 be a sequence of measurable functions such that, for every n?1, and for all x,y∈R∞, where 0<C<∞ is a constant which is independent of n. Let be a sequence of i.i.d. random variables. Assume that there exist r?1 and a function ?:[0,∞)→[0,∞) with limt→∞?(t)=∞, depending only on the sequence such that lim supn→∞gn(X1,X2,…)=?(Er|X|) a.s. whenever Er|X|<∞ and EX=0. We prove the converse result, namely that lim supn→∞gn(X1,X2,…)<∞ a.s. implies Er|X|<∞ (and EX=0 if, in addition, lim supn→∞gn(c,c,…)=∞ for all c≠0). Some applications are provided to illustrate this result. 相似文献
67.
The mechanism of ethylene insertion reactions catalyzed by cationic δ‐alkyl platinum complexes has been studied at the B3LYP level of density functional theory. The initial steps of the reactions proceed via the coordination of ethylene to the reactants L2Pt(II)R+, where L2=none, (NH3)2, (CHNH)2; R=H, CH3, C2H5 in which ethylene coordinates strongly to the complexes PtCH+3 and PtC2H+5 (coordination energies (CE) are 296.52 and 229.28 kJ/mol, respectively), while nitrogen‐containing ligands decrease the energies: Pt(NH3)2CH+3 (CE: 180.04 kJ/mol), Pt(NH3)2C2H+5 (CE: 97.86 kJ/mol), Pt(CHNH)2CH+3 (CE : 176.31 kJ/mol) and Pt(CHNH)2C2H+5 (CE: 91.00 kJ/mol). Moreover, ethylene insertion into the Pt‐alkyl bond, which is the rate‐determining step, is endothermic with barrier heights for L2PtCH3(C2H4)+ decreasing in the order: PtCH+3 (164.18 kJ/mol)>(NH3)2 PtCH+3 (129.95 kJ/mol)>(CHNH)2 PtCH+3 (115.27 kJ/mol), which has the same tendency for the ethyl case. The insertion product will continually undergo β‐hydride elimination, which is exothermic. On the other hand, the effects of solvent (dichloromethane, THF and benzene) are investigated with PCM method, but the inclusion of the effects in the computations only slightly affects the results. Beside that, a complete catalytic cycle for ethylene dimerization is studied in detail and the calculations agree well with known energetic and recognized tendencies. 相似文献
68.
Yijun Zhang Caihong Bu Yongcheng Wang Zhihua Wang Xiaoquan Lu Xiuhui Liu 《Electroanalysis》2012,24(9):1817-1823
In this paper, a novel current oscillatory phenomenon for Cu2+ at the water/1,2‐dichloroethane interface is reported with cyclic voltammetry and potential‐step chronoamperometry. The small irregular current spikes were only observed near the site of the oxidation peak of CuCl2? and were mainly related to the Cu2+concentration in the aqueous phase. Our experimental results demonstrated that the current oscillation is caused by specific adsorption of ion pairs at the W/DCE interface between Cu2+ in the aqueous phase and TPB? in the organic phase. Therefore, a specific adsorption of ion pair model has been formulated for the current oscillation at the liquid/liquid interface. The DFT calculation method was used to explain the mechanism of ion pair formation. The calculation results suggested that the TPB?Cu2+TPB? ion pair has the lowest‐energy state, thus providing qualitative support for the ion pair model. A probable mechanism for the observed current oscillation was also discussed in this paper. At the same time, a spectrophotometric experiment was performed to evidence a strong attractive interaction between Cu2+ and TPB?. 相似文献
69.
A new furanocoumarin, 5-methyl-8-(3-methylbut-2-enyl) furanocoumarin (1), together with seven known compounds, sterequinone C (2), cyclo(6,7-en-Pro-L-Phe) (3), bergapten, scopoletin, umbelliferone, 1,7-dihydroxyxanthone and 3,5-dimethoxybiphenyl, was isolated from the mangrove endophytic fungus, Penicillium sp. ZH16 obtained from the South China Sea. Their structures were determined by analysis of spectroscopic data. Compound 1 exhibited cytotoxicity against KB and KB(V)200 cells in?vitro with IC(50) values 5 and 10?μg?mL(-1), respectively. 相似文献
70.