Deformation of styrene—divinylbenzene copolymers and hypercrosslinked polystyrenes during solvent adsorption and desorption

An automated procedure was developed for monitoring fast changes in the size of spherical samples of polymers during their contact with a solvent or drying. The kinetics of bulk deformation in these processes was studied for a series of cross-linked polymers, viz., gel-type and porous styrene—divinylbenzene copolymers and poly(divinylbenzenes), and hypercrosslinked polystyrenes. Gel, macroporous, and hypercrosslinked polystyrenes are substantially different in the rate, mechanism, and degree of swelling, which is associated with the principal differences in their physical structures. An unusual effect of a sharp decrease followed by a temporary increase in the volume of porous polystyrene and poly(divinylbenzene) materials were observed during desorption (evaporation) of organic solvents. Water desorption is accompanied by an excessive bulk compression of porous granules giving rise to negative deformations, which gradually relax to the state equilibrium for the dry polymer. The results of dynamic desorption porometry (for water desorption) are indicative of a bimodal size distribution of micropores in hypercrosslinked polystyrene. Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 467–476, March, 2007.     

Relations for extrema of the work of aggregation in micellar solutions

Exact relations for the dependence of the positions of extrema of the aggregation work on the aggregation number axis on the surfactant monomer concentration are found for a dilute micellar solution. Relations for the half-widths of the vicinities of the extrema of the aggregation work are determined also. These half-widths are determined by the condition that, within the boundaries of their values, the aggregation work deviates from its extreme values by a thermal unit. The relations derived are illustrated by calculations based on the droplet and quasi-droplet models of spherical aggregates of nonionic surfactant. Some important applications of the obtained results to the theory of relaxation in micellar solutions are considered.     

Formation of coherent spatial structures in the reaction-diffusion atmospheric system under the action of a planetary wave

On the example of the effect of an atmospheric wave with given amplitude on the density oscillations of minor gas constituents near the mesopause (at heights 80–90 km, we consider the influence of the quasi-resonant periodic spatial transport on a distributed system responding subharmonically to a periodic external action (diurnal sunlight variations). Numerical modeling revealed the formation of a coherent horizontal distribution of the dynamical variables (i.e., the concentrations of small constituents). Application of this effect to the mesopause conditions is discussed.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Radiofizika, Vol. 47, No. 9, pp. 739–752, September, 2004.     

Practical OR for Undergraduates in the Swinburne Course

Much of the debate over OR education over the last ten years has been confined to the relevance of the content and style of programmes at the postgraduate level. This paper focuses on the undergraduate level and discusses the way in which practical elements have been successfully incorporated at this level in Australia. These elements include the use of case study material from the literature, case problem solving groups, industrial projects and 12 months paid employment through a co-operative education programme. The use of each of the above and the context with which they fit into the programme is covered as are the benefits and problems associated with the programme.     

Diffraction of normal shock wave by yawed wedges

The diffraction of normal shock with yawed wedges of small angles have been considered in this paper. Vorticity distribution of the fluid particle over the diffracted shock has been determined for several Mach numbers of the shock wave. The Mach reflection effects have also been investigated when the bend is concave to the flow.     

Attractors of the sine-Gordon equation in the field of a quasiperiodic external force

The well-known sine-Gordon equation, supplemented with small damping and small quasiperiodic external force, is studied under the zero Dirichlet boundary conditions at the endpoints of a finite interval. The main assumption is that all frequencies of the external force are in 1:1 resonance with certain eigenfrequencies of the unperturbed equation; i.e., the socalled fundamental multifrequency resonance is observed. It is shown that in this case, by an appropriate choice of the parameters of the external force, one can make it so that the boundary value problem has a stable invariant torus of any finite dimension that bifurcates from zero on any preassigned finite set of spatial modes. It is also shown (by numerical analysis) that in a number of cases the above-mentioned torus coexists with a chaotic attractor.     

Two-limit problems for almost semicontinuous processes defined on a Markov chain

We consider almost upper-semicontinuous processes defined on a finite Markov chain. The distributions of functionals associated with the exit of these processes from a finite interval are studied. We also consider some modifications of these processes. __________ Translated from Ukrains’kyi Matematychnyi Zhurnal, Vol. 59, No. 4, pp. 555–565, April, 2007.     

Variations on the theme of solvability by radicals

We discuss the problem of representability and nonrepresentability of algebraic functions by radicals. We show that the Riemann surfaces of functions that are the inverses of Chebyshev polynomials are determined by their local behavior near branch points. We find lower bounds on the degrees of equations to which sufficiently general algebraic functions can be reduced by radicals. We also begin to classify rational functions of prime degree whose inverses are representable by radicals.     

Constraint incorporation in optimization

Numerical methods for solving constrained optimization problems need to incorporate the constraints in a manner that satisfies essentially competing interests; the incorporation needs to be simple enough that the solution method is tractable, yet complex enough to ensure the validity of the ultimate solution. We introduce a framework for constraint incorporation that identifies a minimal acceptable level of complexity and defines two basic types of constraint incorporation which (with combinations) cover nearly all popular numerical methods for constrained optimization, including trust region methods, penalty methods, barrier methods, penalty-multiplier methods, and sequential quadratic programming methods. The broad application of our framework relies on addition and chain rules for constraint incorporation which we develop here.