Two kinds of organic sulfonic acids, i.e., p-toluenesulfonic acid (PTSA) and sulfosalicylic acid (SSA), were used as doping acid to prepare the polyaniline-deposited functional cellulosic paper, and both the conductivity and flame retardancy of the functional cellulosic paper were investigated. The results indicated that both the conductivity and the flame retardancy of the paper composite had a close relationship with the incorporation of doping acid. Both the conductivity and the oxygen index (OI) value increased with the increase of the acid concentration. SSA performed much better than PTSA and the inorganic acids studied previously for both the conductivity and the OI value of functional cellulosic paper. The conductivity of the paper doped with SSA was more stable than that of the paper doped with PTSA, and the OI value only decreased about 1 % within 40 days for the functional cellulosic paper doped with the two doping acids. Compared with the polyaniline-deposited paper doped with PTSA, both the much higher doping level and the much smaller and more compact polyaniline particles deposition were probably responsible for the significantly better conductivity and flame retardancy of the polyaniline-deposited paper doped with SSA. 相似文献
Consider the nonparametric regression modelY=go(T)+u, whereY is real-valued,u is a random error,T is a randomd-vector of explanatory variables ranging over a nondegenerated-dimensional compact setC, andgo(·) is the unknown smooth regression function, which ism (0) times continuously differentiable and itsmth partial derivatives
satisfy the Hölder condition with exponent(0,1], wherei1, ...,id are nonnegative integers satisfying
k=1/dik=m. The piecewise polynomial estimator ofgo based onM-estimates is considered. It is proved that the rate of convergence of the underlying estimator is
under certain regular conditions, which is the optimal global rate of convergence of least square estimates for nonparametric regression studied in [10–11].This work is partly supported by the National Natural Science Foundation of China. 相似文献
The research of anti-counterfeiting and encryption has always been a subject of universal concern all over the world. Herein, lanthanide metal–organic framework (Eu-MOF) and CH3NH3PbBr3 (MAPbBr3) perovskite were introduced onto pulp fibers (PFs) to prepare fluorescent anti-counterfeiting and encryption papers. Eu-MOF@PFs paper emitted red fluorescence at 254 nm UV excitation. The optimum preparation conditions of Eu-MOF@PFs were 2.5 mmol of Eu(NO3)3, 4 h of reaction time and room temperature. When MABr ink was written on Pb/Eu-MOF@PFs paper, the green fluorescent handwriting and red fluorescent paper were observed under 365 nm and 254 nm UV excitation, respectively. The appropriate addition amount of lead nitrate was 0.6 mmol. Pb/Eu-MOF@PFs paper was immersed in MABr solution to prepare MAPbBr3@Pb/Eu-MOF@PFs paper. Under 254 nm and 365 nm UV irradiations, MAPbBr3@Pb/Eu-MOF@PFs paper emitted red-green double fluorescence and the quantum yields of which were 3.11% and 2.48%, respectively. The crystal structure of MAPbBr3 was easily destroyed by polar solution, which realized on/off switching of the luminescence signal for multistage information encryption. The above paper-based fluorescence materials were potential for advanced anti-counterfeiting and encryption applications.
Abstract. This article discusses the problem of the detection of influential cases in nonlinear re-productive dispersion models (NRDM). A diagnostic based on case-deletion approach in esti-mating equations is proposed. The relationships between the generalized leverage defined byWei et al. in 1998, statistical curvature, and the local influence of the response vector perturba-tions are investigated in NRDM. Two numerical examples are given to illustrate the results. 相似文献