Syntheses and structures of novel heteroarene-fused coplanar pi-conjugated chromophores

We have synthesized a series of novel coplanar chromophores in which heteroarenes, namely, thiophene, benzothiophene, and carbazole, were fused to neighboring phenylene ring(s) through intramolecular annulation via sp(3)-hybridized carbon atoms bearing two p-tolyl groups as peripheral substituents. The molecular configurations of the pi-conjugated backbones were determined by X-ray crystallographic analysis; the heteroarene-fused molecular frameworks of these novel molecules exhibit nearly coplanar conformations. [structure: see text]     

Simple real rank zero algebras with locally Hausdorff spectrum

Let be a unital, simple, separable -algebra with real rank zero, stable rank one, and weakly unperforated ordered group. Suppose, also, that can be locally approximated by type I algebras with Hausdorff spectrum and bounded irreducible representations (the bound being dependent on the local approximating algebra). Then is tracially approximately finite dimensional (i.e., has tracial rank zero).

Hence, is an -algebra with bounded dimension growth and is determined by -theoretic invariants.

The above result also gives the first proof for the locally case.

     

Cross-phase modulation instability in photonic crystal fibers

We report on the observation of cross-phase modulation instability in a highly nonlinear photonic crystal fiber. In such fibers the presence of higher orders of dispersion results in a complex phase-matching curve. We are able to observe this behavior experimentally and obtain excellent agreement between the measured and predicted shifts.     

Cascaded optical parametric oscillation with a dual-grating periodically poled lithium niobate crystal

We demonstrate continuous-wave cascaded optical parametric oscillation in which the signal field of the primary parametric oscillator internally pumps the secondary parametric oscillator. Wavelength tuning is achieved with temperature tuning and a fan-out grating structure of a dual-grating periodically poled lithium niobate crystal. Above the secondary threshold the primary signal power is clamped, and all the other output powers increase linearly with the input pump power, in accordance with theory. Cascaded parametric oscillation offers a convenient and efficient way to generate multiple tunable outputs.     

Lyapunov’s inequality on timescales

The purpose of this work is to establish the timescale version of Lyapunov’s inequality as follows: Let $x\left(t\right)$ be a nontrivial solution of ${\left(r\left(t\right)x^{\Delta }\left(t\right)\right)}^{\Delta }+p\left(t\right)x^{\sigma }\left(t\right)=0\text{on }[a,b]$ satisfying $x\left(a\right)=x\left(b\right)=0$. Then, under suitable conditions on $p$, $r$, $a$ and $b$, we have ${\int }_a^b{p}_{+}\left(t\right)\Delta t\ge \{\begin{array}{cc}\frac{r\left(a\right)}{r\left(b\right)}\frac{b-a}{f\left(d\right)}\text{,}& \text{if }r\text{ is increasing}\text{,}\\ \frac{r\left(b\right)}{r\left(a\right)}\frac{b-a}{f\left(d\right)}\text{,}& \text{if }r\text{ is decreasing}\text{,}\end{array}$ where $p_{+}\left(t\right)=max\{p\left(t\right),0\},f\left(t\right)=(t-a)(b-t)$ and $d\in \mathbb{T}$ satisfies $|\frac{a+b}{2}-d|=min\{|\frac{a+b}{2}-s|\mid s\in [a,b]\cap \mathbb{T}\}$ if $\frac{a+b}{2}\in \mathbb{T}$. Here $\mathbb{T}$ is a timescale (see below).     

Preparative isolation of hydrolysable tannins chebulagic acid and chebulinic acid from Terminalia chebula by high-speed counter-current chromatography

As a chromatographic column, the high-speed counter-current chromatography system was equipped with a preparative HPLC series, enabling the successful isolation of hydrolysable tannins from the fruits of Terminalia chebula, a traditional Chinese medicine. The two-phase solvent system was composed of n-hexane-ethyl acetate-methanol-water (1:20:1:20 v/v). As a result, 33.2 mg chebulagic and 15.8 mg chebulinic acids were obtained in one step from 300 mg of crude extract. Their purities were determined by HPLC to be 95.3 and 96.1%, respectively. The chemical structures were identified by their MS and 1H NMR spectra.     

Structure and dynamics of liquid crystalline pattern formation in drying droplets of DNA

We investigate the formation of ringlike deposits in drying drops of DNA. In analogy with the colloidal "coffee rings," DNA is transported to the perimeter by the capillary flow. At the droplet edge, however, DNA forms a lyotropic liquid crystal (LC) with concentric chain orientations to minimize the LC elastic energy. During the final stages of drying, the contact line retracts, and the radial stress causes undulations at the rim that propagate inward through the LC and form a periodic zigzag structure. We examine the phenomenon in terms of a simple model based on LC elasticity.     

Uniform asymptotics of some q-orthogonal polynomials

Uniform asymptotic formulas are obtained for the Stieltjes-Wigert polynomial, the q⁻¹-Hermite polynomial and the q-Laguerre polynomial as the degree of the polynomial tends to infinity. In these formulas, the q-Airy polynomial, defined by truncating the q-Airy function, plays a significant role. While the standard Airy function, used frequently in the uniform asymptotic formulas for classical orthogonal polynomials, behaves like the exponential function on one side and the trigonometric functions on the other side of an extreme zero, the q-Airy polynomial behaves like the q-Airy function on one side and the q-Theta function on the other side. The last two special functions are involved in the local asymptotic formulas of the q-orthogonal polynomials. It seems therefore reasonable to expect that the q-Airy polynomial will play an important role in the asymptotic theory of the q-orthogonal polynomials.     

Properties of certain semigroups and their potential as platforms for cryptosystems

In this paper, we study some properties of semigroups with presentation 〈a,b ; a ^p =b ^r ,a ^q =b ^s 〉. We will also study their potential as platforms for the Diffie-Hellman key exchange protocol.     

On the oscillation of third order nonlinear difference equations

Some new criteria for the oscillation of third order nonlinear difference equations $$\begin{array}{l}\Delta^{2}\bigl(\frac{1}{a(k)}(\Delta x(k))^{\alpha}\bigr)+q(k)f(x[g(k)])=0\quad\mbox{and}\\[6pt]\Delta^{2}\bigl(\frac{1}{a(k)}(\Delta x(k))^{\alpha}\bigr)=q(k)f(x[g(k)])+p(k)h(x[\sigma(k)])\end{array}$$ are established.