首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   16938篇
  免费   2695篇
  国内免费   1920篇
化学   12318篇
晶体学   189篇
力学   1178篇
综合类   141篇
数学   2025篇
物理学   5702篇
  2024年   37篇
  2023年   318篇
  2022年   362篇
  2021年   507篇
  2020年   619篇
  2019年   642篇
  2018年   506篇
  2017年   525篇
  2016年   733篇
  2015年   734篇
  2014年   917篇
  2013年   1139篇
  2012年   1518篇
  2011年   1546篇
  2010年   1058篇
  2009年   939篇
  2008年   1087篇
  2007年   980篇
  2006年   979篇
  2005年   791篇
  2004年   600篇
  2003年   543篇
  2002年   543篇
  2001年   459篇
  2000年   346篇
  1999年   361篇
  1998年   288篇
  1997年   268篇
  1996年   297篇
  1995年   234篇
  1994年   203篇
  1993年   160篇
  1992年   170篇
  1991年   173篇
  1990年   128篇
  1989年   123篇
  1988年   81篇
  1987年   70篇
  1986年   80篇
  1985年   60篇
  1984年   54篇
  1983年   44篇
  1982年   32篇
  1981年   32篇
  1980年   29篇
  1978年   24篇
  1977年   25篇
  1976年   23篇
  1974年   20篇
  1973年   26篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
981.
In this Letter, we demonstrate that nonadiabatic dynamics of molecular scattering from metal surfaces can be efficiently simulated by semiclassical Gaussian wave packet propagation on a local complex potential. The method relies on the wideband limit decoupling of the nuclear equations of motion on different electronic states. If the continuum diabatic potential surfaces are assumed to be parallel, the number of Gaussian wave packets spawned scales at most linearly with propagation time, allowing efficient propagation of nuclear dynamics.  相似文献   
982.
We present first measurements of the phi-meson elliptic flow (v2(pT)) and high-statistics pT distributions for different centralities from radical sNN=200 GeV Au+Au collisions at RHIC. In minimum bias collisions the v2 of the phi meson is consistent with the trend observed for mesons. The ratio of the yields of the Omega to those of the phi as a function of transverse momentum is consistent with a model based on the recombination of thermal s quarks up to pT approximately 4 GeV/c, but disagrees at higher momenta. The nuclear modification factor (R CP) of phi follows the trend observed in the K S 0 mesons rather than in Lambda baryons, supporting baryon-meson scaling. These data are consistent with phi mesons in central Au+Au collisions being created via coalescence of thermalized s quarks and the formation of a hot and dense matter with partonic collectivity at RHIC.  相似文献   
983.
The generation of continuous variable entanglement via atomic coherence in a two-mode three-level cascade atomic system is discussed according to the entanglement criterion proposed by Duan et al. [Phys. Rev. Lett. 84, 2722 (2000)]. Atomic coherence between the top and bottom levels is induced with two photons of a strong external pump field. It shows that entanglement for the two-mode field in the cavity can be generated under certain conditions. Moreover, by means of the input-output theory, we show that the two-mode entanglement could also be approached at the output.  相似文献   
984.
Nanostructures formed in a titanium dioxide (TiO2)–poly(styrene)‐block‐poly(ethyleneoxide) nanocomposite film on top of fluor‐doped tin oxide (FTO) layers are investigated. The combinatorial approach is based on probing a wedge‐shaped FTO‐gradient with grazing incidence small angle X‐ray scattering (GISAXS) in combination with a moderate micro‐focus X‐ray beam. The characteristic lateral length is given by adjacent nanowire‐shaped TiO2 regions. It decreases from 200 nm on the thick FTO layer to 90 nm on the bare glass surface.

  相似文献   

985.
Cheng CY  Wu CM  Liao GB  Cheng WY 《Optics letters》2007,32(5):563-565
A cesium 6S(1/2) --> 8S(1/2) two-photon-transition (TPT)-stabilized 822.5 nm diode laser is reported for the first time to our knowledge. Allan deviation of 4.4 x 10(-13) (60 s) was achieved, and the possible systematic errors were evaluated as smaller than 2 kHz. We demonstrate that the cesium TPT-stabilized diode laser could be a reliable frequency reference at 822.5 nm wavelength.  相似文献   
986.
The purpose of this study was to test whether an empirical mathematical model (EMM) of dynamic contrast-enhanced magnetic resonance imaging (DCE-MRI) can distinguish between benign and malignant breast lesions. A modified clinical protocol was used to improve the sampling of contrast medium uptake and washout. T(1)-weighted DCE magnetic resonance images were acquired at 1.5 T for 22 patients before and after injection of Gd-DTPA. Contrast medium concentration as a function of time was calculated over a small region of interest containing the most rapidly enhancing pixels. Then the curves were fitted with the EMM, which accurately described contrast agent uptake and washout. Results demonstrate that benign lesions had uptake (P<2.0 x 10(-5)) and washout (P<.01) rates of contrast agent significantly slower than those of malignant lesions. In addition, secondary diagnostic parameters, such as time to peak of enhancement, enhancement slope at the peak and curvature at the peak of enhancement, were derived mathematically from the EMM and expressed in terms of primary parameters. These diagnostic parameters also effectively differentiated benign from malignant lesions (P<.03). Conventional analysis of contrast medium dynamics, using a subjective classification of contrast medium kinetics in lesions as "washout," "plateau" or "persistent" (sensitivity=83%, specificity=50% and diagnostic accuracy=72%), was less effective than the EMM (sensitivity=100%, specificity=83% and diagnostic accuracy=94%) for the separation of benign and malignant lesions. In summary, the present research suggests that the EMM is a promising alternative method for evaluating DCE-MRI data with improved diagnostic accuracy.  相似文献   
987.
Liposomes composed of cell‐penetrating peptide derivatives increased transport across the cell membrane. Conjugating rhodamine to a cell‐penetrating peptide increased the toxicity of rhodamine in E. coli and zebrafish embryos. A similar total protein inhibition pattern with different intensities, indicating that the interaction pathways of the rho‐KTTKS‐CONH2 monomer and liposomes were the same. It suggests that the rho‐KTTKS‐CONH2 liposomes showed higher toxicity because better transport across the cell membrane increased the effective concentration inside cells. The staining of zebrafish embryos using rho‐KTTKS‐CONH2 liposomes showed a longer retention time, suggesting that it can penetrate deeper tissues or organs in zebrafish.  相似文献   
988.
Sun  Xiaodong  Ding  Wen  Chen  Cheng  Yu  Tao  Chen  Qin  Yang  Ke 《Chromatographia》2021,84(5):499-505
Chromatographia - In this study, a poly(glycidyl methacrylate) nanoparticle (PGMA NP)-coated column system with two antibiotics as selector was constructed for enantioseparation. The PGMA NP...  相似文献   
989.
In this paper, an electrochemical aptamer sensor was proposed for the highly sensitive detection of mercury ion (Hg2+). Carbon nanofiber (CNF) was prepared by electrospinning and high‐temperature carbonization, which was used for the loading of platinum nanoparticles (PtNPs) by the hydrothermal method. The Pt@CNF nanocomposite was modified on the surface of carbon ionic liquid electrode (CILE) to obtain Pt@CNF/CILE, which was further decorated by gold nanoparticles (AuNPs) through electrodeposition to get Au/Pt@CNF/CILE. Self‐assembling of the thiol‐based aptamer was further realized by the formation of Au‐S bond to get an electrochemical aptamer sensor (Aptamer/Au/Pt@CNF/CILE). Due to the specific binding of aptamer probe to Hg2+ with the formation of T‐Hg2+‐T structure, a highly sensitive quantitative detection of Hg2+ could be achieved by recording the changes of current signal after reacting with Hg2+ within the concentration range from 1.0 × 10?15 mol/L to 1.0 × 10?6 mol/L and the detection limit of 3.33 × 10?16 mol/L (3σ). Real water samples were successfully analyzed by this method.  相似文献   
990.
A series of diamide derivatives containing α-amino acids were designed and synthesized. These compounds were evaluated for their insecticidal activities against Plutella xylostella, Mythimna separate, Myzus persicae, and Tetranychus cinnabarinus. Most of the title compounds containing an l -phenylglycine skeleton were endowed with good activities at the concentration of 500 mg·L−1. Compounds ( R)-A6 showed a potential value for further optimization as an insecticidal lead with the LC50 value of 86.8 mg·L−1.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号