Effect of a radial temperature gradient on the stability of the flow of a second-order fluid between two co-axial cylinders

Summary It has been found that the effect of a radial temperature gradient on the Taylor stability problem for a viscoelastic fluid and for a Newtonian fluid is the same.

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Résumé On montre que l'effet d'un gradient de la température radial sur le problème de stabilité de Taylor pour un fluide viscoélastique est semblable à celui d'un fluide Newtonien.

     

Exciton system heating in ZnSe single crystals under laser excitation

The way to determine the effective temperature of the excitonic system from the study of the edge luminescence high energy region is motivated. Experimental data on the exciton heating in ZnSe single crystals under laser excitation are presented. The effective temperature of excitons T_x has reached 158 K at the lattice temperature T_L = 77 and the peak excitation intensity 2.7 MW cm^?2 (hv₀ = 3.50), while the excess temperature of the excitons (T_x ? T_L) increases as a square root of the pump intensity. Exciton-hot-electron, exciton-hot-photon, exciton-exciton interactions and excitonic Auger process are considered as possible causes of the exciton system heating.     

New strategies for exploring RNA's 2'-OH expose the importance of solvent during group II intron catalysis

The 2'-hydroxyl group contributes inextricably to the functional behavior of many RNA molecules, fulfilling numerous essential chemical roles. To assess how hydroxyl groups impart functional behavior to RNA, we developed a series of experimental strategies using an array of nucleoside analogs. These strategies provide the means to investigate whether a hydroxyl group influences function directly (via hydrogen bonding or metal ion coordination), indirectly (via space-filling capacity, inductive effects, and sugar conformation), or through interactions with solvent. The nucleoside analogs span a broad range of chemical diversity, such that quantitative structure activity relationships (QSAR) now become possible in the exploration of RNA biology. We employed these strategies to investigate the spliced exons reopening (SER) reaction of the group II intron. Our results suggest that the cleavage site 2'-hydroxyl may mediate an interaction with a water molecule.     

Molality as a unit of measure for expressing 1H MRS brain metabolite concentrations in vivo

Absolute concentrations of cerebral metabolite in in vivo 1H magnetic resonance spectroscopy studies (1H-MRS) are widely reported in molar units as moles per liter of tissue, or in molal units as moles per kilogram of tissue. Such measurements require external referencing or assumptions as to local water content. To reduce the scan time, avoid assumptions that may be invalid under specific pathologies, and provide a universally accessible referencing procedure, we suggest that metabolite concentrations from 1H-MRS measurements in vivo be reported in molal units as moles per kilogram of tissue water. Using internal water referencing, a two-compartment water model, a simulated brain spectrum for peak identification, and a spectroscopic bi-exponential spin-spin relaxation segmentation technique, we measured the absolute concentrations for the four common 1H brain metabolites: choline (Cho), myo-inositol (mIno), phosphocreatine + creatine (Cr), and N-acetyl-aspartate (NAA), in the hippocampal region (n = 26) and along the Sylvian fissure (n = 61) of 35 healthy adults. A stimulated echo localization method (20 ms echo time, 10 ms mixing time, 4 s repetition time) yielded metabolite concentrations, uncorrected for metabolite relaxation or contributions from macromolecule resonances, that were expectantly higher than with molar literature values. Along the Sylvian fissure the average concentrations (coefficient of variation (CV)) in mmoles/kg of tissue water were 17.6 (12%) for NAA, 14.2 (9%) for Cr, 3.6 (13%) for Cho, and 13.2 (15%) for mIno. Respective values for the hippocampal region were 15.7 (20%), 14.7 (16%), 4.6 (19%), and 17.7 (26%). The concentrations of the two regions were significantly different (p 相似文献   

Eigenvalues of Random Power law Graphs

Many graphs arising in various information networks exhibit the "power law" behavior -the number of vertices of degree k is proportional to k^-# for some positive #. We show that if # > 2.5, the largest eigenvalue of a random power law graph is almost surely(1+ o(1))?m (1+ o(1))\sqrt{m} where m is the maximum degree. Moreover, the klargest eigenvalues of a random power law graph with exponent # have power law distribution with exponent 2# if the maximum degree is sufficiently large, where k is a function depending on #, mand d, the average degree. When 2<#< 2.5, the largest eigenvalue is heavily concentrated at cm^3-# for some constant c depending on # and the average degree. This result follows from a more general theorem which shows that the largest eigenvalue of a random graph with a given expected degree sequence is determined by m, the maximum degree, and [(d)\tilde] \tilde{d} , the weighted average of the squares of the expected degrees. We show that the k-th largest eigenvalue is almost surely (1+ o(1))?{m_k} (1+ o(1))\sqrt{m_k} where m_k is the k-th largest expected degree provided m_k is large enough. These results have implications on the usage of spectral techniques in many areas related to pattern detection and information retrieval.     

Small Complete Arcs in Projective Planes

In the late 1950s, B. Segre introduced the fundamental notion of arcs and complete arcs [48,49]. An arc in a nite projective plane is a set of points with no three on a line and it is complete if cannot be extended without violating this property. Given a projective plane , determining , the size of its smallest complete arc, has been a major open question in finite geometry for several decades. Assume that has order q, it was shown by Lunelli and Sce [41], more than 40 years ago, that . Apart from this bound, practically nothing was known about , except for the case is the Galois plane. For this case, the best upper bound, prior to this paper, was O(q ^3/4) obtained by Sznyi using the properties of the Galois field GF(q).In this paper, we prove that for any projective plane of order q, where c is a universal constant. Together with Lunelli-Sces lower bound, our result determines up to a polylogarithmic factor. Our proof uses a probabilistic method known as the dynamic random construction or Rödls nibble. The proof also gives a quick randomized algorithm which produces a small complete arc with high probability.The key ingredient of our proof is a new concentration result, which applies for non-Lipschitz functions and is of independent interest.* Research supported in part by grant RB091G-VU from UCSD, by NSF grant DMS-0200357 and by an A. Sloan fellowship.Part of this work was done at AT&T Bell Labs and Microsoft Research     

Quantum impurities and the neutron resonance peak in YBa2Cu3O7: Ni versus Zn

The influence of magnetic (S=1) and nonmagnetic (S=0) impurities on the spin dynamics of an optimally doped high temperature superconductor is compared in YBa2(Cu0.97Ni0.03)3O7 (Tc=80 K) and YBa2(Cu0.99Zn0.01)3O7 (Tc=78 K). In the Ni-substituted system, the magnetic resonance peak (which is observed at Er approximately 40 meV in the pure system) shifts to lower energy with a preserved Er/Tc ratio while the shift is much smaller upon Zn substitution. By contrast Zn, but not Ni, restores significant spin fluctuations around 40 meV in the normal state. These observations are discussed in the light of models proposed for the magnetic resonance peak.     

Synthesis of multi-walled carbon nanotubes for NH3 gas detection

It has been recently demonstrated that carbon nanotubes (CNTs) represent a new type of chemical sensor capable of detecting a small concentration of molecules such as CO, NO₂, NH₃.In this work, CNTs were synthesized by chemical vapor deposition (CVD) on the SiO₂/Si substrate by decomposition of acetylene (C₂H₂) on sputtered Ni catalyst nanoparticles. Their structural properties are studied by atomic force microscopy, high-resolution scanning electron microscopy (HRSEM) and Raman spectroscopy. The CNTs grown at 700 °C exhibit a low dispersion in size, are about 1 μm long and their average diameter varies in the range 25–60 nm as a function of the deposition time. We have shown that their diameter can be reduced either by annealing in oxygen environment or by growing at lower temperature (less than 600 °C).We developed a test device with interdigital Pt electrodes on an Al₂O₃ substrate in order to evaluate the CNTs-based gas sensor capabilities. We performed room temperature current–voltage measurements for various gas concentrations. The CNT films are found to exhibit a fast response and a high sensitivity to NH₃ gas.     

RF generation of the plasma jet channel for the jet PCVD

Breakdown conditions for creation of the hollow cathode discharge in the nozzle passed through the rf powered electrode and creation of the plasma jet channel in PCVD reactor are studied. Pure nitrogen is used for measurements. The creation of jet channel is easier for smaller rf electrodes. The breakdown depends on the pressure and on the gas inflow rate. The plasma potential and the self-bias potential is influenced by the covering of reactor walls and the rf electrode by a dielectric layer.