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61.
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[reaction: see text] The stereoselective synthesis of pyridinones was accomplished by the nucleophilic addition of Grignard reagents to a chiral pyridinium salt derived from 4-methoxypyridine. This methodology was applied to an expedient synthesis of (-)-barrenazine A and B. After N-functionalization and 1,4-reduction of the pyridinone system, the corresponding alpha-amino piperidinones readily undergo dimerization to give the hexahydrodipyridinopyrazine skeleton of the barrenazine alkaloids. 相似文献
63.
Dominik Jacob Kathrin Thüring Aurellia Galliot Virginie Marchand Adeline Galvanin Akif Ciftci Karin Scharmann Michael Stock Jean‐Yves Roignant Sebastian A. Leidel Yuri Motorin Raffael Schaffrath Roland Klassen Mark Helm 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(28):9666-9670
64.
Statistically optimized near field acoustic holography (SONAH) is usually based on the assumption that all sources are on one side of the measurement plane whereas the other side is source free. An extension of the SONAH procedure based on measurement with an array of pressure-velocity probes has recently been suggested. An alternative method uses a double layer array of pressure transducers. Both methods make it possible to distinguish between sources on the two sides of the array and thus suppress the influence of extraneous noise and reflections coming from the "wrong" side. This letter compares the two methods. 相似文献
65.
Dr. Yoko Hasegawa Dr. Thomas Cantin Dr. Jonathan Decaens Dr. Samuel Couve-Bonnaire Prof. Dr. André B. Charette Prof. Dr. Thomas Poisson Prof. Dr. Philippe Jubault 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(47):e202201438
The first diastereo- and enantioselective cyclopropanation reactions of electron-deficient allenes with donor-acceptor and diacceptor diazo reagents are described. The desired enantioenriched alkylidenecyclopropanes (ACPs) were obtained in high yields with high diastereo- and enantioselectivities in the presence of Rh2((S)-TCPTAD)4 or Rh2((R)-BTPCP)4 catalysts (up to 95 % yield, >95 : 5 d.r. and 99 : 1 e.r.). This methodology gave a direct access to ACPs bearing multiple electron-deficient substituents and allows to further expand the availability of ACPs chemistry. Interestingly, during the examination of the scope of this reaction, the asymmetric intramolecular C−H insertion reaction into tert-butyl group was observed as a side reaction with up to 94 : 6 e.r. 相似文献
66.
Jules K. Djoko Virginie S. Konlack Mohamed Mbehou 《Numerical Methods for Partial Differential Equations》2020,36(1):86-117
In this work, we consider the heat equation coupled with Stokes equations under threshold type boundary condition. The conditions for existence and uniqueness of the weak solution are made clear. Next we formulate the finite element problem, recall the conditions of its solvability, and study its convergence by making use of Babuska–Brezzi's conditions for mixed problems. Third we formulate an Uzawa's type iterative algorithm that separates the fluid from heat conduction, study its feasibility, and convergence. Finally the theoretical findings are validated by numerical simulations. 相似文献
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A rearrangement in basic medium of the natural endoperoxide G3-factor extracted from Eucalyptus grandis is described. Evidence to support a 1,2-dioxetane intermediate that decomposes with weak luminescence emission (quantum yield) is presented. 相似文献
70.
Kim DE Kim IS Ratovelomanana-Vidal V Genêt JP Jeong N 《The Journal of organic chemistry》2008,73(20):7985-7989
An efficient asymmetric PKR mediated by Rh(I) catalyst at ambient temperature was developed. The reaction utilizing a Rh(I) catalyst bearing a (R)-3,5-diMeC4H4-BINAP ligand at 18-20 degrees C under a reduced partial pressure of CO (0.1 atm) provided PKR products in high chemical yield as well as high enantioselectivity. 相似文献