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21.
Vesna Vasić Katarina Krinulović Danijela Krstić Tatjana Momić Anica Horvat 《Monatshefte für Chemie / Chemical Monthly》2004,135(5):605-614
Summary. The possibility of using synaptic plasma membrane (SPM) enzymes Na+/K+-ATPase and Mg2+-ATPase, isolated from rat brain, as a biological component of multi-response sensing system for detection of different compounds (alkaline and heavy metal salts, organic compounds) was studied. The method is based on the spectrophotometric determination of inorganic ortho-phosphate (Pi) that serves as a measure of the enzymatic activity in the presence of various analytes. The concentration of Pi, liberated by enzyme catalysed hydrolysis of adenosinetriphosphate (ATP), was followed spectrophotometrically, by single exposure to analytes or in the mixture. Pi was dose dependent on the analyte concentration. Alkaline elements (Na, K, Mg), heavy metals (Pb, Cd, Hg, Cu, Fe, Co, Zn), toxic organic compounds (pyridine, urea, chlorpyrifos), and some drugs (digoxin, gitoxin) showed diverse effects, inducing the inhibition or stimulation of the enzymes activity. Development of simple test method for simultaneous detection of the investigated analytes based on the variation of medium assay composition was discussed. 相似文献
22.
Miroslav Ćirić Tatjana Petković Stojan Bogdanović 《Southeast Asian Bulletin of Mathematics》2001,25(1):47-60
In this paper we introduce a generalization of direct families of algebras and we study their limits and sums. In the case of generalized direct families of algebras carried by idempotent algebras we investigate some subdirect decompositions of their sums. The results that we obtain generalize various results given by J.L. Chrislock and T. Tamura [2], M. iri and S. Bogdanovi [3-7], H. Mitsch [13], M. Petrich [14-16], B.M. Schein [23-24] and others.Supported by Grant 04M03B of RFNS through Math. Inst. SANU 相似文献
23.
Variation of the total mean curvature of piecewise smooth surfaces in Euclidean 3-spaces under infinitesimal bending is discussed and reduced to a sum of line integrals of a rotation vector field. 相似文献
24.
The determination of surface-active substances (SAS) during the evolution of a phytoplankton bloom in a model plankton ecosystem was done by electrochemical methods. The separation and characterization of the organic material present were also done on XAD-8 resin columns. It was found that large amounts of the SAS, predominantly of the humic (fulvic) type, were present from the beginning of the experiment and partly masked the effects of organic substances released by phytoplankton. Although the transformation of the organic matter (consumption and/or excretion) was obvious, no general trend in the amount or type of surface-active matter was observed during the experiment. 相似文献
25.
Violeta D. Mitic Snezana D. Nikolic Vesna P. Stankov-Jovanovic 《Central European Journal of Chemistry》2010,8(3):559-565
A kinetic spectrophotometric method for hydrazine determination in the range of 9.36×10−7 to 4.37×10−5 mol dm−3, based on the inhibitory effect of hydrazine on the oxidation of Victoria Blue 4- R by KBrO3, was developed and validated. Kinetic parameters are reported for both the indicating and the inhibiting reaction. The detection
limit was established as 9.98×10−8 mol dm−3. The selectivity of the proposed method was tested considering the influence of different ions that may be present in real
samples. The method was successfully applied for hydrazine determination in various samples (very pure water from the water-steam
system of a power plant and Isoniazid tablets, a pharmaceutical product).
相似文献
26.
ANDREAS TUTIĆ 《The Journal of mathematical sociology》2014,38(3):219-232
The mixed-strategy equilibrium applied to the volunteer's dilemma (Diekmann, 1985) predicts that the probability that at least 1 bystander volunteers decreases, if the number of bystander increases. I argue that this prediction lacks empirical support and demonstrate that an alternative solution concept from the literature on bounded rationality, the procedurally rational equilibrium (Osborne &; Rubinstein, 1998), yields alternative predictions. I supply some empirical evidence that the alternative solution concept fares better in explaining observed behavior in the volunteer's dilemma. 相似文献
27.
JPC – Journal of Planar Chromatography – Modern TLC - The behavior of 5,5-disubstituted hydantoin derivatives has been studied using four chromatographic systems, two normal-phase... 相似文献
28.
This paper is a continuation of [11]. Here we study all identities which induce decompositions into nil-extensions of a union
of groups and identities which induce various special types of these decompositions.
Supported by Grant 0401A of SF Servia through Math. Inst. SANU. 相似文献
29.
Mirjana Popsavin Miloš Svir?evLjilja Torovi? Gordana Bogdanovi?Vesna Koji? Dimitar JakimovSaša Spai? Lidija Aleksi?Velimir Popsavin 《Tetrahedron》2011,67(36):6847-6858
Synthesis of four new tiazofurin analogues has been accomplished starting from d-glucose. The key step of the synthesis was the three-step cascade that enabled an efficient hydrogen sulfide mediated one-pot conversion of 2-azido-3-O-acyl-ribofuranosyl cyanides to the corresponding 2-alkylamido ribofuranosyl thiocarboxamides. The resulting key intermediates were first converted to protected tiazofurin derivatives by cyclocondensation with ethyl bromopyruvate, and finally to target C-nucleosides by treatment with ammonia in methanol. In vitro cytotoxicities of tiazofurin analogues against a number of human tumour cell lines were recorded and compared with those observed for the parent molecule (tiazofurin), as well as the commercial antitumour agent doxorubicin (DOX). Analogues 2b-d have shown a potent in vitro cytotoxic activity against human myelogenous leukaemia K562. Among solid tumour cell lines, HT29 was sensitive only to 2d, while HeLa cells were sensitive to 2a, 2b and 2d. Only analogue 2a was highly cytotoxic against MCF-7 cells. No tiazofurin analogue exhibits any significant cytotoxicity towards normal foetal lung MRC-5 cells. Downregulation of Bcl-2, activation of caspase-3 and presence of cleavage product of PARP suggest that the cytotoxic effects of tiazofurin analogues 2a-d in K562 might be mediated by apoptosis in a caspase-dependent way. On the contrary, tiazofurin did not induce apoptosis of K562 cells, which suggests a different mechanism of action, most probably through the inhibition of IMPDH. Flow cytometry and Western blot analysis data agreed well with the results of MTT assay, and enabled identification of analogue 2c as the most promising antitumour agent that preferentially target cancer cells over normal cells and thus represents a new lead for further optimization. 相似文献
30.
Glavnik Vesna Simonovska Breda Vovk Irena Pavlović Dragana Mutavdžić Ašperger Danijela Babić Sandra 《平面色谱法杂志一现代薄层色谱法》2011,24(6):482-486
JPC – Journal of Planar Chromatography – Modern TLC - Validation of a method for the quantification of (−)-epicatechin and procyanidin B2 in chocolates is reported. After a simple... 相似文献