Special issue on global flow instability and control

This special issue is the second on the topic of “Global Flow Instability and Control,” following the first in 2011. As with the previous special issue, the participants of the last two symposia on Global Flow Instability and Control, held in Crete, Greece, were invited to submit publications. These papers were peer reviewed according to the standards of the journal, and this issue represents a snapshot of the progress since 2011. In this preface, a sampling of important developments in the field since the first issue is discussed. A synopsis of the papers in this issue is given in that context.     

Three dimensional combined fracture–plastic material model for concrete

This paper describes a combined fracture–plastic model for concrete. Tension is handled by a fracture model, based on the classical orthotropic smeared crack formulation and the crack band approach. It employs the Rankine failure criterion, exponential softening, and it can be used as a rotated or a fixed crack model. The plasticity model for concrete in compression is based on the Menétrey–Willam failure surface, the plastic volumetric strain as a hardening/softening parameter and a non-associated flow rule based on a nonlinear plastic potential function. Both models use a return-mapping algorithm for the integration of constitutive equations. Special attention is given to the development of an algorithm for the combination of the two models. The suggested combination algorithm is based on a recursive substitution, and it allows for the two models to be developed and formulated separately. The algorithm can handle cases when failure surfaces of both models are active, but also when physical changes such as crack closure occur. The model can be used to simulate concrete cracking, crushing under high confinement and crack closure due to crushing in other material directions. The model is integrated in a general finite element package ATENA and its performance is evaluated by comparisons with various experimental results from the literature.     

Examination of the Spatial Distribution of Dyes and Polymers in Thin Films by Two-Photon Microscopy

Summary.  Two-photon absorption induced fluorescence microscopy was used as a tool for the examination of the spatial distribution of a thin dye film. The two-photon absorption induced fluorescence signal is essentially the same as that produced by excitation with a single photon of equivalent energy. When femtosecond pulses are focused into a sample there is an intrinsic spatial selectivity of the two-photon emission signal, since it is dependent upon the square of the light intensity. This has tremendous implications in fluorescence microscopy. Since two-photon absorption is confined in a small region at the focal waist of an objective lens, photodamage and photobleaching of the sample are significantly reduced. In addition, the two-photon signal has inherent z-axis spatial resolution, which facilitates the construction of 3-D images. In the present work an application of this technique to a thin film of a dye is presented. The method can generally be applied to thin films made from photonic polymers. Received June 23, 2000. Accepted (revised) July 31, 2000     

Vibrational spectra of spinels with cation ordering on the octahedral sites

Infrared and Raman spectra are reported for compounds with 1 : 1, 1 : 3, and 1 : 2 mixed ordering on the octahedral sites of the spinel structure. The spectra of the superstructures are complex with many more bands observed than occur in the parent spinel structure, although less than were predicted by group theoretical analysis. A qualitative interpretation of the spectra can be made through the large Brillouin zone concept.     

A network model for the permeability of condensable vapours through mesoporous media

The paper aims at introducing a discrete (network) approach to modelling transport of condensable vapours in mesoporous structures. Such models possess the potential for improving the understanding of the mechanisms responsible for the observed transport behaviour. The basic elements of a typical pore network representing a mesoporous medium are summarized and the current state concerning the simulation of the related phenomena is given. The main processes involved (adsorption, mass diffusion, surface flow, capillary condensation) are simulated over the entire range of relative pressure. Finally, the effects of material structural parameters (average pore radius, pore size distribution and standard deviation, pore connectivity) and other relevant factors (relative pressure, temperature, resistance to surface flow, total pressure drop) on vapour permeability are presented and the future research directions are pointed out.     

Impact of protein flexibility on hydride-transfer parameters in thermophilic and psychrophilic alcohol dehydrogenases

The hydride transfer catalyzed by thermophilic alcohol dehydrogenase (htADH) exhibits sharply different kinetic and activation parameters from that catalyzed by the more flexible psychrophilic alcohol dehydrogenase (psADH). In addition, the hydride transfer in htADH is affected by mutating two distal residues that are suggested to be responsible for the decreased local protein flexibility in htADH. These observations provide support for the view that protein dynamics is tightly coupled to the hydrogen-transfer processes in these enzymes.     

Comparative analysis of ancient ceramics by neutron activation analysis,inductively coupled plasma-optical-emission spectrometry,inductively coupled plasma-mass spectrometry,and X-ray fluorescence

The accurate measurement of the maximum possible number of elements in ancient ceramic samples is the main requirement in provenance studies. For this reason neutron activation analysis (NAA) and X-ray fluorescence (XRF) have been successfully used for most of the studies. In this work the analytical performance of inductively coupled plasma-optical-emission spectrometry (ICP-OES) and inductively coupled plasma-mass spectrometry (ICP-MS) has been compared with that of XRF and NAA for the chemical characterization of archaeological pottery. Correlation coefficients between ICP techniques and XRF or NAA data were generally better than 0.90. The reproducibility of data calculated on a sample prepared and analysed independently ten times was approximately 5% for most of the elements. Results from the ICP techniques were finally evaluated for their capacity to identify the same compositional pottery groups as results from XRF and NAA analysis, by use of multivariate statistics.     

Ion exchange of Pb(2+), Cu(2+), Fe(3+), and Cr(3+) on natural clinoptilolite: selectivity determination and influence of acidity on metal uptake

In the present study ion exchange of Pb(2+), Cu(2+), Fe(3+), and Cr(3+) on natural Greek clinoptilolite was examined in terms of selectivity toward the above heavy metals in single- and multicomponent solutions in batch systems. Also examined are the influence of clinoptilolite on solution acidity and the effect of acidity on the ion exchange process. Clinoptilolite increases solution acidity due to the exchange of H(+) cations with the cations initially present in its structure. H(+) cations should be considered as competitive ones in ion exchange processes, and consequently ion exchange of metals is favored at high acidity values. Cu(2+) and Cr(3+) are the most sensitive cations with respect to acidity. Selectivity determination demonstrates that the selectivity at total concentration 0.01 N and acidity 2 in both single- and multicomponent solutions is following the order Pb(2+)>Fe(3+)>Cr(3+) > or =Cu(2+). This order is set since the first days of equilibration. However, Cu(2+) shows remarkable changes in selectivity and generally its uptake and selectivity are increasing with time. On the other hand selectivity in single metal solutions where acidity is not adjusted is following the order Pb(2+)>Cr(3+)>Fe(3+) congruent with Cu(2+).     

A facile preparation of 1-(6-hydroxyindol-1-yl)-2,2-dimethylpropan-1-one

An effective synthesis of 1-(6-hydroxyindol-1-yl)-2,2-dimethylpropan-1-one (4) was developed starting from 1H-indole (2). The key step involved suitable utilization of 4-(1-pyrrolidino)pyridine for the removal of the chloroacetyl moiety from chloroacetic acid 1-(2,2-dimethylpropionyl)-1H-indol-6-yl ester (3); a possible mechanism is, also, presented. Compound 4 might lead to selectively substituted derivatives, either on the phenolic-OH or the indolyl-NH, with putative biological interest. In this respect, we found that the core structure of 1H-indol-6-ol (1) possesses a degree of aldose reductase inhibitory potential, at a concentration of 100 microM.