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Annamaria Varga Valentin Zaharia Mihály Nógrádi László Poppe 《Tetrahedron: Asymmetry》2013,24(21-22):1389-1394
Ethyl (S)-3-hydroxy-3-phenylpropionate (S)-2 was obtained by the asymmetric reduction of ethyl 3-phenyl-3-oxopropionate 1 with the yeast Saccharomyces cerevisiae (ATCC 9080). The kinetic resolution of racemic ethyl 2-acetoxy-3-phenyl-propionate rac-3 with the same microorganism, gave after hydrolysis ethyl (R)- and (S)-3-hydroxy-3-phenylpropionates (R)-2 and (S)-2 which were converted by a straightforward series of reactions to the enantiomers of 3-amino-3-phenyl-propionic acids (S)-6 and (R)-6. The asymmetric reduction and hydrolytic kinetic resolution were also tested with several other whole cell systems under a variety of conditions. 相似文献
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Benjamin H. Strudwick Mark A. J. Koenis Hans J. Sanders Valentin P. Nicu Sander Woutersen Prof. Wybren Jan Buma 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(54):12560-12566
Vibrational circular dichroism (VCD) studies are reported on a chiral compound in which a fullerene C60 moiety is used as an electron acceptor and local VCD amplifier for an alanine-based peptide chain. Four redox states are investigated in this study, of which three are reduced species that possess low-lying electronic states as confirmed by UV/Vis spectroelectrochemistry. VCD measurements in combination with (TD)DFT calculations are used to investigate (i) how the low-lying electronic states of the reduced species modulate the amplification of VCD signals, (ii) how this amplification depends on the distance between oscillator and amplifier, and (iii) how the spatial extent of the amplifier influences amplification. These results pave the way for further development of tailored molecular VCD amplifiers. 相似文献
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Kosova Nina V. Podgornova Olga A. Volfkovich Yury M. Sosenkin Valentin E. 《Journal of Solid State Electrochemistry》2021,25(3):1029-1037
Journal of Solid State Electrochemistry - Nanostructured carbon–coated composite cathode materials LiFe0.5Mn0.5PO4/C (LFMP/C) are prepared by the mechanochemically assisted solid-state... 相似文献
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Valentin Guillon Daniela Bauer Marc Fleury Marie-Christine Néel 《Transport in Porous Media》2014,101(2):251-267
We present a pore network model combined with a random walk algorithm allowing the simulation of molecular displacement distributions in porous media as measured by NMR. A particular feature of this technique is the ability to probe the time evolution of these distributions. The objective is to predict the displacement behaviour for time intervals larger than the experimental observation time and explore the asymptotic dispersion regime at long times. Starting from 3D micro-CT images, we computed the variance of displacement distributions of water molecules in a Fontainebleau sand and found very good agreement of the time evolution of the variance with experimental data, without fitting parameter. The model confirms a weak superdispersion in the asymptotic regime. In addition, we conclude that, since pore network models do not take into account small scale features of the porous medium (e.g., surface roughness and grain shape), the origin of the observed superdispersion is mainly due to the topology and geometry of the porous medium. 相似文献
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Valentin Yu. Irkhin 《The European Physical Journal B - Condensed Matter and Complex Systems》2014,87(5):1-8
Research into new materials to be used as hydrogen reservoirs is necessary, the increasing demand of energy in the world should be covered progressively by clean energies, trying not to pollute the environment. With this work we wish to contribute to the knowledge of the different saline hydrides and the possibility of using these as hydrogen reservoirs. We performed a systematic study on these materials. In this work we used different ab-initio codes to study several compounds of lithium and beryllium with hydrogen. 相似文献
50.
We give an abstract characterization of algebras of partial functions from A n to A endowed with the operations of the Menger superposition and the set-theoretic difference of functions as subsets of A n+1. 相似文献