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991.
In this study, an ammonia-gas-sensing liquid-state membrane electrode based on 1-[(2-oxyphenyl)iminomethyl]-2-oxybenzene-O,O',N-ammin-nickel(II) (Ni(II)-Schiff base) as an ionophore was developed. This membrane electrode gave a very good performance and exhibited linear response with near-Nernstian slope of 50.7+/-0.5 mV per decade, within a concentration range of 1.0x10(-1)-1.0x10(-3) M. The electrode performance depends on the pH of the test solution and the optimum pH range was 10.0-11.5. The effect of concentration of internal solutions in the electrode was also investigated. The selectivity properties of the electrode towards aliphatic amines at a pH value of 10.2 were investigated with the mixed-solution method. Furthermore, the response time and lifetime of the electrode prepared were determined. 相似文献
992.
Halit Kantekin Ümmühan Ocak Yaşar Gök Irfan Acar 《Journal of inclusion phenomena and macrocyclic chemistry》2004,48(3-4):95-101
A new (E, E)-dioxime (H 2 L) containing a diazadioxadithia macrocyclic moieties has been synthesized by reaction of an aromatic primary amine with cyanogendi-N-dioxide. The BF2 +-capped Ni2+ mononuclear complex of this new oxime has been synthesized using a precursor hydrogen-bridged mononuclear Ni2+ complex. The solvent extraction of transition metal cations by (3) and (6) with picrate anion into chloroform has been studied at 25 °C and UV-visible spectroscopy. The extractability and selectivity of transition metal picrates, (Pb2+, Ni2+, Co2+, Cd2+, Zn2+, Cu2+, Ag+) has been evaluated. The structures of new compounds are identified by using elemental analysis, 1H and 13C-NMR, IR and MS spectral data. 相似文献
993.
Bloch HA Petersen M Sperotto MM Keşmir C Radzikowski L Jacobsen S Søndergaard I 《Rapid communications in mass spectrometry : RCM》2001,15(6):440-445
Cereal varieties are normally identified using time-consuming methods such as visual examination of either the intact grain or one-dimensional electrophoretic patterns of the grain storage proteins. A fast method for identification of wheat (Triticum aestivum L.) varieties has previously been developed, which combines analysis of alcohol-soluble wheat proteins (gliadins) using matrix-assisted laser desorption/ionisation time-of-flight mass spectrometry with neural networks. Here we have applied the same method for the identification of both barley (Hordeum vulgare L.) and rye (Secale cereale L.) varieties. For barley, 95% of the mass spectra were correctly classified. This is an encouraging result, since in earlier experiments only a grouping into subsets of varieties was possible. However, the method was not useful in the classification of rye, due to the strong similarity between mass spectra of different varieties. 相似文献
994.
Süheyla Özbey F. Betül Kaynak Mahmut Toŭrul Nadir Demirel Halil Hoşgören 《Journal of inclusion phenomena and macrocyclic chemistry》2003,45(1-2):123-128
A new complex of a chiral monoaza-crown ether, [R-(-)-2-ethyl-N-benzyl-4,7,10,13-tetraoxa-8,9-benzo-1-azacyclopentadec-8-ene...NaClO4], has been prepared and studied by x-ray diffraction. The compound crystallizes in space group P21 with cell dimensions a = 8.721(1), b = 16.318(2), c = 8.905(1) Å, = 100.80(1)°. The sodium cation is heptacoordinated and located significantly out of the best plane of the macrocycle ring. The donor atoms of the macrocycle are in the half-chair arrangement. 相似文献
995.
From the aerial parts of Phlomis longifolia var. longifolia four iridoid glucosides, shanzhiside methyl ester (1), 5-deoxypulchelloside I (2), lamalbide (3), phlomiol (4) and three phenylethanoid glycosides, verbascoside (5), forsythoside B (6), leucosceptoside A (7) along with the caffeic acid ester, chlorogenic acid (8) were isolated. The structures of the isolated compounds were established by spectroscopic (UV, IR, 1D- and 2D-NMR, FABMS) and chemical evidence. The structure elucidation of the iridoid compounds 2 and 3 are discussed in detail. 相似文献
996.
The construction and basic characteristics of a new liquid-state Hg(2+)-selective membrane electrode are discussed. The membrane consists of the PAN chelate of Hg(II), dissolved in CHCl(3). The linear response range of the electrode is 10(-1) -10(-5)M Hg(2+) with a slope of 28.5 mV/decade of concentration. The response time of the electrode in dilute solutions is less than 3 min, and in concentrated solutions it is only a few sec. The electrode has been used in precipitation or complexation titrations in which Hg(2+) is involved (e.g., in the determination of some organic compounds in drug synthesis). 相似文献
997.
We study the Nash equilibria of a class of two-person nonlinear, deterministic differential games where the players are weakly coupled through the state equation and their objective functionals. The weak coupling is characterized in terms of a small perturbation parameter . With =0, the problem decomposes into two independent standard optimal control problems, while for 0, even though it is possible to derive the necessary and sufficient conditions to be satisfied by a Nash equilibrium solution, it is not always possible to construct such a solution. In this paper, we develop an iterative scheme to obtain an approximate Nash solution when lies in a small interval around zero. Further, after requiring strong time consistency and/or robustness of the Nash equilibrium solution when at least one of the players uses dynamic information, we address the issues of existence and uniqueness of these solutions for the cases when both players use the same information, either closed loop or open loop, and when one player uses open-loop information and the other player uses closed-loop information. We also show that, even though the original problem is nonlinear, the higher (than zero) order terms in the Nash equilibria can be obtained as solutions to LQ optimal control problems or static quadratic optimization problems.This research was supported in part by the US Department of Energy under Grant DE-FG-02-88-ER-13939.Paper presented at the 29th IEEE Conference on Decision and Control, Honolulu, Hawaii, 1990. 相似文献
998.
Bahattin Yalçın Perizad A. Fatullayeva Orhan Büyükgüngör Başak Koşar Sülin Taşcıoğlu Akif I. Israfilov Zaur D. Ibayev Ajdar A. Medjidov Adnan Aydın 《Polyhedron》2007
N-(2-Hydroxybenzyl)aminopyridines (Li) react with Cu(II) and Pd(II) ions to form complexes in the compositions Cu(Li)2(CH3COO)2 · nH2O (n = 0, 2, 4), Pd(Li)2Cl2 · nC2H5OH (n = 0, 2) and Pd(L2)2Cl2 · 2H2O. In the complexes, the ligands are neutral and monodentate which coordinate through pyridinic nitrogen. Crystal data of the complexes obtained from 2-amino pyridine derivative have pointed such a coordinating route and comparison of the spectral data suggests the validity of similar complexation modes of other analog ligands. Cu(II) complex of N-(2-hydroxybenzyl)-2-aminopyridine (L1), [Cu(L1)2(CH3COO)2] has slightly distorted square planar cis-mononuclear structure which is built by two oxygen atoms of two monodentate carboxylic groups disposed in cis-position and two nitrogen atoms of two pyridine rings. The remaining two oxygen atoms of two carboxylic groups form two Cu and H bridges containing cycles which joint at same four coordinated copper(II) ion. IR and electronic spectral data and the magnetic moments as well as the thermogravimetric analyses also specify on mononuclear octahedric structure of complexes [Cu(L2)2(CH3COO)2 · 2H2O] and [Cu(L3)2(CH3COO)2 · 4H2O] where L2 and L3 are N-(2-hydroxybenzyl)-2- or 3-aminopyridines, respectively. 相似文献
999.
The effectiveness of the usual harmonic oscillator basis is demonstrated on a wide class of Schrödinger Hamiltonians with various spectral properties. More specifically, it is shown numerically that an appropriately scaled Hermite–Weber basis yields extremely accurate results not only for the energy eigenvalues which differ slighly from the harmonic oscillator levels, but also for the states which reflect a purely anharmonic character. 相似文献
1000.
Klein W Rohde G Arinir U Hagedorn M Dürig N Schultze-Werninghaus G Epplen JT 《Electrophoresis》2004,25(6):804-808
Chronic obstructive pulmonary disease (COPD) is a multifactorial disorder characterized by irreversible airflow obstruction due to chronic inflammation. Hence, the gene encoding the anti-inflammatory cytokine IL 11 is a good candidate for being involved in the genetic predisposition to COPD. In order to evaluate the role of the Interleukin 11 (IL 11) gene in the genetic predisposition for COPD, a dinucleotide microsatellite polymorphism in the promoter region has been genotyped in 153 patients with COPD (including 25 non-smokers) and 463 healthy controls. Frequencies of the IL 11.A2 microsatellite allele and of IL 11.A2 homozygous individuals were significantly decreased among the patients with COPD (p < 0.012 and p < 0.022, respectively) as compared to controls. Both frequencies were even more drastically reduced among the nonsmoking patients. Tight linkage of this microsatellite allele with another polymorphism in the promotor region was established. Altered expression of IL 11 may be involved in the genetic predisposition to COPD. 相似文献