g-factors of the ground state rotational band of158Dy

Theg-factors of the four lowest states of the ground state rotational band of¹⁵⁸Dy have been determined asg(2 ₁ ⁺ )=+0.362(23),g(4 ₁ ^su+ )=+0.340(20),g(6 ₁ ^su+ )=+0.207(36) andg(8 ₁ ^su+ )=+0.21(11). Theg-factors of the 2⁺ and 4⁺ states were measured by the IPAC method with radioactive samples of 2.4 h¹⁵⁸Er in external magnetic fields. To investigate the higher states, for the first time an on-line γ—γ IPAC experiment was performed with the reaction¹⁵⁶Gd(α, 2n)¹⁵⁸Dy by use of the static hyperfine field of DyGd.     

Octet-baryon form factors in the diquark model

We present an alternative parameterization of the quark-diquark model of baryons which particularly takes care of the most recent proton electric form-factor data from the E136 experiment at SLAC. In addition to electromagnetic form factors of the nucleon, for which good agreement with data is achieved, we discuss the weak axial vector form factor of the nucleon as well as electromagnetic form factors of and hyperons. Technical advance in calculating the pertinent analytic expressions within perturbative quantum chromodynamics is gained by formulating the wave function of the quark-diquark system in a covariant way. Finally, we also comment on the influence of Sudakov corrections within the scope of the diquark model.Sponsored in part by the Bundesministerium für Forschung und Technologie, Germany, under contract number 06 Wu 737     

Electrical and infrared dielectrical properties of silica aerogels and of silica-aerogel-based composites

In this contribution we have studied the key electrical parameters of silica aerogels and of silica-aerogel-based composites, namely the dielectric constants , the dielectric losses tan (at 1 kHz), and the breakdown fields E _b (at 50 Hz). For low-density bulk silica aerogels we find =1.25 and tan =0.0005. E _b is about 500 kV/cm in quasi-homogeneous fields, and of the order of MV/cm in strongly inhomogeneous fields. The dielectric constants of partially densified aerogels increase linearly with density; their dielectric losses are relatively large and their breakdown fields are comparativiely low. The same results are found for aerogels in the form of settled materials, i.e. aerogel granules and powders in air. Acrylate-based aerogel composites with volume fractions larger than 70% have low dielectric constants but their losses are at least 10 times higher than those of low-density aerogels. These materials sustain high local fields in the MV/cm region, while in quasihomogeneous fields, breakdown occurs at about 100 kV/cm. Based on the present results and the interplay with other physical properties (low mechanical resistance, low thermal conductivity, adsorption of water, etc.), silica aerogels and silica aerogel-acrylate-based composites are predicted to have a low potential for electrical insulation.     

Semi-preparative liquid-chromatographic separation of all four stereoisomers of α-bisabolol on tribenzoylcellulose

Summary A semi-preparative low-pressure liquid-chromatographic procedure using tribenzoylcellulose has been developed for the separation and isolation of the four -bisabolol stereoisomers. Stereochemical assignments were made by HPLC-polarimeter coupling and by using the authentical isomers. This method can be applied to the quality control of chamomile preparations, as it allows the detection of adulterations resulting from admixtures of synthetic -bisabolol. In addition, the isolation of all four -bisabolol stereoisomers from commercially available synthetic -bisabolol has been made possible.     

Crystal and molecular structure of the cycloaddition product between maleic anhydride,cyclopentadiene, and 1,2-bis(dibromomethyl)benzene as DMF solvate (1∶2)

Crystal structure determination reveals that the unknown cycloaddition product between maleic anhydride, cyclopentadiene, and 1,2-bis(dibromomethyl)benzene has a nona-cyclic centrosymmetric structure. The compound was studied as DMF solvate (12). There is no significant intermolecular interaction between the title molecule and the DMF. Packing is in layers for both molecular species. A possible mechanism of formation of the title compound is discussed.     

Hermite interpolation with trigonometric polynomials

Interpolation methods of Hermite type in translation invariant spaces of trigonometric polynomials for any position of interpolation points and any number of derivatives are constructed. For the case of an odd number of interpolation conditions-periodic trigonometric polynomials of minimum order are chosen as interpolation functions while for the case of an even number of interpolation conditions-antiperiodic trigonometric polynomials of minimum order are appropriate.     

The second and the third smallest distances on the sphere

Let s₁ (n) denote the largest possible minimal distance amongn distinct points on the unit sphere . In general, let s_k(n) denote the supremum of thek-th minimal distance. In this paper we prove and disprove the following conjecture of A. Bezdek and K. Bezdek: s₂(n) = s₁([n/3]). This equality holds forn > n₀ however s₂(12) > s₁(4).We set up a conjecture for s_k(n), that one can always reduce the problem of thek-th minimum distance to the function s₁. We prove this conjecture in the casek=3 as well, obtaining that s₃(n) = s₁([n/5]) for sufficiently largen.The optimal construction for the largest second distance is obtained from a point set of size [n/3] with the largest possible minimal distance by replacing each point by three vertices of an equilateral triangle of the same size . If 0, then s₂ tends to s₁([n/3]). In the case of the third minimal distance, we start with a point set of size [n/5] and replace each point by a regular pentagon.