Remote regioselective organocatalytic asymmetric [3+2] cycloaddition of N-2,2,2-trifluoroethyl isatin ketimines with cyclic 2,4-dienones

An organocatalytic asymmetric [3+2] cycloaddition of trifluoromethyl-containing azomethine ylides with cyclic 2,4-dienones was developed.The process enables efficient incorporation of CF3 groups into functionalized spiro [pyrro lid in-3,2'-oxindoles] in high yields with good to excellent enantio-and diastereoselectivities.     

BiVO4/TiO2 core-shell heterostructure: wide range optical absorption and enhanced photoelectrochemical and photocatalytic performance

In the present study, pristine BiVO₄, TiO₂ and BiVO₄/TiO₂ core-shell heterostructured nanoparticles are prepared by hydrothermal methods and studied for structural, morphological, optical, photoelectrochemical water splitting and photocatalytic degradation of methylene blue as an organic pollutant. Both pristine BiVO₄ and TiO₂ exhibit poor PEC and PC performance under visible light illumination. However, an enhanced PEC and PC activity in BiVO₄/TiO₂ core-shell heterostructure is observed due to high solar energy absorption and superior charge separation properties in core-shell nanoparticles. The photoelectrode prepared using BiVO₄/TiO₂ core-shell nanoparticles exhibit a photocathode behavior and produced cathodic photocurrent, however, the pristine BiVO₄ and TiO₂ photoelectrodes act as photoanode and produced anodic photocurrent. This behavior of change in current direction is also observe in the Mott-Schottky analysis where the BiVO₄/TiO₂ core-shell nanoparticles photoelectrode exhibits the positive slow showing p-type semiconducting behavior. The change in cathodic photoresponse in core-shell nanoparticles in comparison to anodic photoresponse of BiVO₄ and TiO₂ nanoparticles is explained in terms of the variations in the work function values. These results highlight the advantages of core-shell nanoparticle of suitable materials for photocatalytic and photoelectrochemical applications.     

On the development of a triple‐preserving Maxwell's equations solver in non‐staggered grids

We present in this paper a finite difference solver for Maxwell's equations in non‐staggered grids. The scheme formulated in time domain theoretically preserves the properties of zero‐divergence, symplecticity, and dispersion relation. The mathematically inherent Hamiltonian can be also retained all the time. Moreover, both spatial and temporal terms are approximated to yield the equal fourth‐order spatial and temporal accuracies. Through the computational exercises, modified equation analysis and Fourier analysis, it can be clearly demonstrated that the proposed triple‐preserving solver is computationally accurate and efficient for use to predict the Maxwell's solutions. Copyright © 2009 John Wiley & Sons, Ltd.     

Design and synthesis of new C-nucleosides as potential adenosine deaminase inhibitors

A number of new pyrazolo[3,4-c] and [4,3-b]pyridine C-nucleosides, which can be viewed as 4- or 6-deazaformycin analogues were synthesized and examined as potential adenosine deaminase (ADA) inhibitors. The compounds were prepared through the condensation of a suitably substituted, lithiated 2- or 4-methylpyridine with tri-O-benzyl-d-ribonolactone, followed by borohydride reduction of the resulting hemiacetals, intramolecular Mitsunobu cyclisation of the derived diols, formation of the pyrazolopyridine ring system and subsequent removal of the protecting groups. These derivatives were designed on the structural basis provided by docking simulations performed within the enzyme catalytic site, however they demonstrated weak ADA inhibitory activity. Theoretical calculations assisted in the interpretation of the obtained biological data, thus providing guidance for rational structural modifications within this molecular scaffold.     

Effect of sp-hybridized defects on the oscillatory behavior of carbon nanotube oscillators

Using molecular dynamics simulations, we investigate the oscillatory behaviors of carbon nanotube oscillators containing sp³-hybridized defects formed by hydrogen chemisorption. It is found that the presence of these defects significantly affects the kinetic and potential energies of the nanotube systems, which in turn affects their oscillation periods and frequencies. We have also studied the oscillatory characteristics of the oscillators containing sp³-hybridized Stone-Wales defects. Our results show that it is possible to control the motion of the inner nanotube by introducing sp³-hybridized defects on the outer nanotube, which provides a potential way to tune the oscillatory behavior of nanotube oscillators.     

Time and Spacetime: The Crystallizing Block Universe

The nature of the future is completely different from the nature of the past. When quantum effects are significant, the future shows all the signs of quantum weirdness, including duality, uncertainty, and entanglement. With the passage of time, after the time-irreversible process of state-vector reduction has taken place, the past emerges, with the previous quantum uncertainty replaced by the classical certainty of definite particle identities and states. The present time is where this transition largely takes place, but the process does not take place uniformly: evidence from delayed choice and related experiments shows that isolated patches of quantum indeterminacy remain, and that their transition from probability to certainty only takes place later. Thus, when quantum effects are significant, the picture of a classical Evolving Block Universe (‘EBU’) cedes place to one of a Crystallizing Block Universe (‘CBU’), which reflects this quantum transition from indeterminacy to certainty, while nevertheless resembling the EBU on large enough scales.     

Derivations on Real and Complex JB*-Triples

At the regional conference held at the University of California,Irvine, in 1985 [24], Harald Upmeier posed three basic questionsregarding derivations on JB*-triples: (1) Are derivations automatically bounded? (2) When are all bounded derivations inner? (3) Can bounded derivations be approximated by inner derivations? These three questions had all been answered in the binary cases.Question 1 was answered affirmatively by Sakai [17] for C*-algebrasand by Upmeier [23] for JB-algebras. Question 2 was answeredby Sakai [18] and Kadison [12] for von Neumann algebras andby Upmeier [23] for JW-algebras. Question 3 was answered byUpmeier [23] for JB-algebras, and it follows trivially fromthe Kadison–Sakai answer to question 2 in the case ofC*-algebras. In the ternary case, both question 1 and question 3 were answeredby Barton and Friedman in [3] for complex JB*-triples. In thispaper, we consider question 2 for real and complex JBW*-triplesand question 1 and question 3 for real JB*-triples. A real orcomplex JB*-triple is said to have the inner derivation propertyif every derivation on it is inner. By pure algebra, every finite-dimensionalJB*-triple has the inner derivation property. Our main results,Theorems 2, 3 and 4 and Corollaries 2 and 3 determine whichof the infinite-dimensional real or complex Cartan factors havethe inner derivation property.     

Electro-optic detection of femtosecond electromagnetic pulses by use of poled polymers

We report the generation and coherent detection of freely propagating ultrashort baseband electromagnetic pulses. Using optical rectification in ?110? GaAs for wideband emission and electro-optic sampling in a poled polymer for wideband detection, we demonstrate spectral sensitivity that extends from the far infrared (lambda~100 mum) to ~33 THz(lambda = 9 mum) . Over a band of nearly 20 THz, a relatively flat frequency response is observed. We discuss issues that limit the response bandwidth.     

AN INVARIANT FOR HYPERGRAPHS

ＡＮＩＮＶＡＲＩＡＮＴＦＯＲＨＹＰＥＲＧＲＡＰＨＳＷＡＮＧＪＩＡＮＦＡＮＧ（ＩｎｓｔｉｔｕｔｅｏｆＡＰＰｌｉｅｄＭａｔｈｅｍａｔｉｃｓ，ＣｈｉｎｅｓｅＡｃａｄｅｍｙｏｆＳｃｉｅｎｃｅｓ，Ｂｅｉｊｉｎｇ１０００８０，ＣｈｉｎａａｎｄＡｓｉａ－Ｐａｃｉｆ...     

Order-preserving representations of the partitions on the finite set

A partial ordering is defined for monotone projections f: N → N, N = {1, 2,…, n}, such that the class of these mappings is a lattice which is isomorphic to the partition lattice. Thus a partition can be uniquely represented by an element of this class of mappings and the partial ordering of partitions is preserved. Algorithms for computing the join and meet of given partitions are presented.