Potent New Heterogeneous Asymmetric Catalysts

A set of new, air‐stable, Rh^I‐based heterogeneous asymmetric hydrogenation catalysts have been synthesised, characterised, and tested. Individual members of this new family all exhibit good enantioselectivity.     

Generation of slanted gas-filled icicles

A procedure for the generation of slanted gas-filled icicles by freezing, using a domestic refrigerator, is described. The freezing vessel was a plastic ice-cube tray, which was filled both with tap and deionized water and was frozen successively from the outer to the inner compartments of the tray. Icicles having slanted elevations grew out of the surface of the deionized water of the innermost compartments. The erection angle of the icicles to the horizontal lay between 30° and 60°, for the three longest and thinnest specimens it was almost exactly 30°. All icicles have gas inclusions. Their shape varies between an irregular distribution of circular bubbles and a nearly uninterrupted axial gas channel together with dendrite-like, radially distorted bubbles. If a cold (-18°C) specimen comes into contact with warm and humid room-air, then hoarfrost is observed at the bottom and the top of the icicle, while the area in between remains transparent.     

Bodies of constant width in arbitrary dimension

We give a number of characterizations of bodies of constant width in arbitrary dimension. As an application, we describe a way to construct a body of constant width in dimension n, one of its (n – 1)‐dimensional projection being given. We give a number of examples, like a four‐dimensional body of constant width whose 3D‐projection is the classical Meissner's body. (© 2007 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Ambient connections realising conformal Tractor holonomy

For a conformal manifold we introduce the notion of an ambient connection, an affine connection on an ambient manifold of the conformal manifold, possibly with torsion, and with conditions relating it to the conformal structure. The purpose of this construction is to realise the normal conformal Tractor holonomy as affine holonomy of such a connection. We give an example of an ambient connection for which this is the case, and which is torsion free if we start the construction with a C-space, and in addition Ricci-flat if we start with an Einstein manifold. Thus, for a C-space this example leads to an ambient metric in the weaker sense of Čap and Gover, and for an Einstein space to a Ricci-flat ambient metric in the sense of Fefferman and Graham. Current address for first author: Erwin Schr?dinger International Institute for Mathematical Physics (ESI), Boltzmanngasse 9, 1090 Vienna, Austria Current address for second author: Department of Mathematics, University of Hamburg, Bundesstra?e 55, 20146 Hamburg, Germany     

Studies on Rare-Earth/Iron and Actinide/Iron Multilayers

Hyperfine Interactions - Multilayers of Ce/Fe and U/Fe were fabricated by sputtering and studied by X-ray diffraction and reflectivity, Mössbauer spectroscopy and polarised neutron...     

13C and 1H NMR analysis of the nitration products of 2-amino-4-oxo-(3H)-5-trifluoromethylquinazoline and 2-amino-4-oxo-(3H)-5-fluoroquinazoline

Nitration of 2-amino-4-oxo-(3H)-5-trifluoromethylquinazoline is shown to occur exclusively at C⁶ as determined from an analysis of long range ¹H and ¹⁹F scalar couplings to ring carbons. Nitration of 2-amino-4-oxo-(3H)-5-fluoroquinazoline is found to occur both at C⁶ and C⁸ as evident from an analysis of the ¹⁹F and ¹H couplings of the ring protons.     

Bestmögliche innere Schalengleichungen für schubweiche Werkstoffe unter Berücksichtigung von Dickenänderungen

Übersicht Konsistente Schalentheorien lassen sich in einer besonders anschaulichen Weise durch lineare Approximation der Erhaltungssätze eines als Multi-Direktor-Körper beschriebenen, dreidimensionalen Kontinuums herleiten. Im vorliegenden Beitrag entstchen auf diesem Wege bestmögliche, in Geschwindigkeiten formulierte innere Schalengleichungen für beliebig große Deformationen und willkürliche, in eine Leistungsaussage einpaßbare Materialgesetze. Dabei finden Schub- und Querdeformationen Berücksichtigung. Der optimale Charakter der Schalentheorie mit gleichen Unschärfen in allen Einzelbeziehungen wird durch den Herleitungsgang sichergestellt und durch Einschrankungen mittels lokaler Tensornormen bewiesen.

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Best interior shell equations including transverse shear deformations and thickness changes

Summary Consistent shell theories can be derived in a particular correct manner by linear approximation of conservation laws of a three-dimensional continuum, described as a multi-director-body. In the present paper best interior shell equations-formulated in velocities—are developed, valid for arbitrarily large deformations and rather optional material laws, incorporating shear distorsions and thickness changes. The optimal character of the theory is guaranteed by the derivation process and proven by bounding techniques using tensor norms.

     

Combined-modality treatment of adductor spasmodic dysphonia with botulinum toxin and voice therapy

A combined-modality treatment program consisting of botulinum toxin injection (Botox) and voice therapy was used to treat 17 subjects diagnosed with adductor spasmodic dysphonia (ADD SD). Ten subjects with ADD SD served as the control and were given Botox only. Voice therapy after Botox injection was directed toward reducing the hyperfunctional vocal behaviors, primarily glottal overpressure at voice onset and anterior-posterior squeezing. The results indicated that subjects who underwent combined-modality treatment maintained significantly higher mean airflow rates for significantly longer periods. Moreover, there was a carryover effect in these patients when they received Botox only. Adductor spasmodic dysphonia is treated most effectively when intrinsic laryngeal muscle spasms are reduced or eliminated by Botox injection and extrinsic hyperfunctional vocal behaviors are treated with voice therapy