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91.
Koshevoy IO Lin CL Karttunen AJ Jänis J Haukka M Tunik SP Chou PT Pakkanen TA 《Chemistry (Weinheim an der Bergstrasse, Germany)》2011,17(41):11456-11466
Reactions of the homoleptic (AuC(2)R)(n) precursors with stoichiometric amount of diphosphine ligand PPh(2)C(6)H(4)PPh(2) (P^P) and Cu(+) ions lead to an assembly of a new family of bimetallic clusters [Au(6)Cu(2)(C(2)R)(6)(P^P)(2)](2+) (type I; R=9-fluorenolyl (1), diphenylmethanolyl (2), 2,6-dimethyl-4-heptanolyl (3), 1-cyclohexanolyl (4), Cy (5), tBu (6)). In the case of R=1-cyclohexanolyl, a structurally different complex [Au(6)Cu(2)(C(2)C(6)H(11)O)(6)(P^P)(3)](2+) (7, type II) could be obtained by treatment of 4 with one equivalent of the diphosphine, while for R=isopropanolyl only the latter type of cluster [Au(6)Cu(2)(C(2)C(3)H(7)O)(6)(P^P)(3)](2+) (8) was detected. Steric bulkiness of the alkynyl ligands and O···H-O hydrogen bonding are suggested to play an important role in stabilizing the type I and type II cluster structural motif, respectively. All the complexes exhibit intense photoluminescence in solution with emission parameters that depending on the geometrical arrangement of the octanuclear metal core. The clusters 1-4 and 6 show single emission band in a blue region (469-488 nm) with maximum quantum yield of 94% (4), while structurally different 7 and 8 emit yellow-orange (590 nm) with unity quantum efficiency. The theoretical DFT calculations of the electronic structures have been carried out to demonstrate that the metal-centered triplet emission within the heterometallic core plays a key role for the observed phosphorescence. 相似文献
92.
Eila Vhsarja Tuula T. Pakkanen Tapani A. Pakkanen Eero Iiskola Pekka Sormunen 《Journal of polymer science. Part A, Polymer chemistry》1987,25(12):3241-3253
The interaction between AlEt3 and silyl ethers, PhnSi(OMe)4-n (n = 0–3), was followed by 13C- and 29Si-NMR techniques in conditions close to those typical for an olefin polymerization reaction with supported Ziegler–Natta catalysts (A1Et3:silyl ether ratios from 1 to 10, temperature range 25–75°C). A1Et3 and silyl ethers form instantaneously at ambient temperature a donor-acceptor complex, which is stable at a 1:1 molar ratio. In the presence of excess A1Et3 the complex decomposes via a mechanism consisting, in the case of PhSi(OMe)3, of five consecutive steps: alternating complexation and ether reductions with the formation of alkylated silyl ethers, Ph(Et)nSi(OMe)3-n (n = 1,2), and dialkyl-aluminum alkoxides, (Et2A1OMe3)n (n = 2,3). The rate of decomposition was enhanced by the increasing number of methoxy groups present in the silyl ether, heating, or a high A1Et3:silyl ether ratio. The decomposition was not inhibited by the presence of 1-hexene. 相似文献
93.
Koivula A Ruohonen L Wohlfahrt G Reinikainen T Teeri TT Piens K Claeyssens M Weber M Vasella A Becker D Sinnott ML Zou JY Kleywegt GJ Szardenings M Ståhlberg J Jones TA 《Journal of the American Chemical Society》2002,124(34):10015-10024
Trichoderma reesei cellobiohydrolase Cel6A is an inverting glycosidase. Structural studies have established that the tunnel-shaped active site of Cel6A contains two aspartic acids, D221 and D175, that are close to the glycosidic oxygen of the scissile bond and at hydrogen-bonding distance from each other. Here, site-directed mutagenesis, X-ray crystallography, and enzyme kinetic studies have been used to confirm the role of residue D221 as the catalytic acid. D175 is shown to affect protonation of D221 and to contribute to the electrostatic stabilization of the partial positive charge in the transition state. Structural and modeling studies suggest that the single-displacement mechanism of Cel6A may not directly involve a catalytic base. The value of (D2O)(V) of 1.16 +/- 0.14 for hydrolysis of cellotriose suggests that the large direct effect expected for proton transfer from the nucleophilic water through a water chain (Grotthus mechanism) is offset by an inverse effect arising from reversibly breaking the short, tight hydrogen bond between D221 and D175 before catalysis. 相似文献
94.
The structures and relative stabilities of (MgCl(2))(n)() sheetlike clusters and nanoballs were studied by quantum chemical methods. The sheets as discrete molecules were studied up to Mg(100)Cl(200). Their stabilities increase systematically as a function of the size of the sheet. Periodic ab initio calculations were performed for (001) monolayer sheets of alpha- and beta-MgCl(2), beta-sheet being slightly favored. Nanoballs were constructed from Archimedean polyhedra, producing tetrahedral, octahedral, and icosahedral symmetries, and were studied up to Mg(60)Cl(120). Nanoballs prefer to take the shape of truncated cuboctahedron (Mg(48)Cl(96)). Comparisons to sheetlike clusters and periodic calculations suggest that magnesium dichloride nanoballs are stable. 相似文献
95.
Fiber fractions from processing of barley in production and conservation of a biologic control agent
Tapani Tuomi Mari Heino Heikki Rosenqvist Katrina Nordström Simo Laakso 《Applied biochemistry and biotechnology》2001,94(2):135-145
Carriers are frequently used to overcome problems associated with microbial survival in soil after inoculation. Moreover,
the use of carriers can prolong the shelf lives and lessen dusting of both biofungicides and biologic fertilizers. This study
investigated the suitability of barley-based fiber fractions as growth media and immobilization matrices in the cultivation
of a Streptomyces griseoviridis biologic control agent, as well as for the conservation of obtained biomass in dehydrated hydrogel capsules. The second main
ingredient in all the examined carrier matrices was alginate. The aim was to find a hydrogel formulation suited for a production
process in which all individual steps, including cultivation of the organism; downstream processing; and formulation, storage,
and application of the product (i.e., biologic control agent), are carried out in the hydrogel matrix. Of the tested fractions,
brewer’s spent grain was the best choice, when considering the price vs the nutrient contents as well as the storage time
and ease of processing of the crude and the finished products. It seems that cereal fibers can be replenished with cereal
fractions less rich in fiber but having a higher content of utilizable nutrients and, hence, better suited for the production
of biomass. A high content of water-insoluble fiber favorably influenced the appearance as well as the applicability of the
products. 相似文献
96.
We study the \(\kappa \)-Borel-reducibility of isomorphism relations of complete first order theories in a countable language and show the consistency of the following: For all such theories T and \(T^{\prime }\), if T is classifiable and \(T^{\prime }\) is not, then the isomorphism of models of \(T^{\prime }\) is strictly above the isomorphism of models of T with respect to \(\kappa \)-Borel-reducibility. In fact, we can also ensure that a range of equivalence relations modulo various non-stationary ideals are strictly between those isomorphism relations. The isomorphism relations are considered on models of some fixed uncountable cardinality obeying certain restrictions. 相似文献
97.
Molecular dynamics simulations were used to study the wetting of nanogrooved PE and PVC polymer surfaces. The contact angles, equilibrium states, and equilibrium shapes of two nanosized water droplets were analyzed on surfaces with 1D-arranged periodic roughness of various dimensions. The composite solid-liquid contact, which is preferred in practical applications and in which a droplet rests on top of the surface asperities, was observed on the roughest PE surfaces, whereas water filled the similar but slightly deeper grooves on PVC surfaces. The transition from the wetted to composite contact regime occurred when the contact angle with a flat surface reached the value at which the apparent Wenzel and Cassie contact angles are equal. Droplets on grooved PE surfaces with the composite contact exhibited contact angles in agreement with Cassie's equation, but the increase in hydrophobicity on smoother surfaces with the wetted contact was less than expected from Wenzel's equation. The difference between the simulated and theoretical values decreased as the dimensions of the surface grooves increased. Only a slight increase or even a slight decrease in the contact angles was observed on the grooved PVC surfaces, owing to the less hydrophobic nature of the flat PVC surface. On both polymers, the nanodroplet assumed a spherical shape in the composite contact. Only minor anisotropy was observed in the wetted contact on PE surfaces, whereas even a highly anisotropic shape was seen on the grooved PVC surfaces. The contact angle in the direction of the grooves was smaller than that in the perpendicular direction, and the difference between the two angles decreased with the increasing size of the water droplet. 相似文献
98.
Karttunen AJ Linnolahti M Pakkanen TA 《Chemistry (Weinheim an der Bergstrasse, Germany)》2007,13(18):5232-5237
The existence of two new allotropic forms of phosphorus, icosahedral cages and ring-shaped chains, is predicted. The cages and rings are nanostructural modifications of the black and the red phosphorus, respectively. The icosahedral and ring-shaped allotropes are compared with the experimentally known allotropic forms of phosphorus by quantum chemical methods. Both the cages and the rings are thermodynamically favored over the white phosphorus, the rings being comparable to the Hittorf's violet phosphorus and to the recently discovered fibrous red phosphorus. The stabilities of the icosahedral cages increase as a function of their size, having structural resemblance with the rhombohedral black phosphorus. The high thermodynamic stability of the phosphorus nanostructures suggests their experimental synthesis to be viable. 相似文献
99.
Filip Duša Joanna Witos Erno Karjalainen Tapani Viitala Heikki Tenhu Susanne K. Wiedmer 《Electrophoresis》2016,37(2):363-371
The use of bare fused silica capillary in CE can sometimes be inconvenient due to undesirable effects including adsorption of sample or instability of the EOF. This can often be avoided by coating the inner surface of the capillary. In this work, we present and characterize two novel polyelectrolyte coatings (PECs) poly(2‐(methacryloyloxy)ethyl trimethylammonium iodide) (PMOTAI) and poly(3‐methyl‐1‐(4‐vinylbenzyl)‐imidazolium chloride) (PIL‐1) for CE. The coated capillaries were studied using a series of aqueous buffers of varying pH, ionic strength, and composition. Our results show that the investigated polyelectrolytes are usable as semi‐permanent (physically adsorbed) coatings with at least five runs stability before a short coating regeneration is necessary. Both PECs showed a considerably decreased stability at pH 11.0. The EOF was higher using Good's buffers than with sodium phosphate buffer at the same pH and ionic strength. The thickness of the PEC layers studied by quartz crystal microbalance was 0.83 and 0.52 nm for PMOTAI and PIL‐1, respectively. The hydrophobicity of the PEC layers was determined by analysis of a homologous series of alkyl benzoates and expressed as the distribution constants. Our result demonstrates that both PECs had comparable hydrophobicity, which enabled separation of compounds with log Po/w > 2. The ability to separate cationic drugs was shown with β‐blockers, compounds often misused in doping. Both coatings were also able to separate hydrolysis products of the ionic liquid 1,5‐diazabicyclo[4.3.0]non‐5‐ene acetate at highly acidic conditions, where bare fused silica capillaries failed to accomplish the separation. 相似文献
100.
Mikko Linnolahti Pipsa Hirva Tapani A. Pakkanen 《Journal of computational chemistry》2001,22(1):51-64
The ab initio Hartree–Fock theory has been demonstrated to give accurate geometry predictions for bridged zirconocene dichlorides. Equilibrium geometries of crystallographically characterized bridged zirconocene dichlorides were optimized by Hartree–Fock, MP2, BLYP, and B3LYP methods, with basis sets ranging from 3‐21G* to 6‐311G**. Selected geometrical parameters were compared with experimental crystal structures. The least expensive HF/3‐21G* method proved to be notably accurate. The accuracy of HF/3‐21G* was verified by a comprehensive data set of 62 bridged zirconocene dichlorides. Furthermore, experimental corrections were applied to the optimized geometry parameters to eliminate systematic deviations. Corrections resulted in considerably improved accuracy for systematically overestimated metal–ligand distances, with maximum deviation falling from 0.081 to 0.039 Å, and absolute average deviations from 0.048 to 0.012 Å. Ligand–metal–ligand angles were predicted accurately with absolute average deviations of 0.7–1.3°. Zirconium–chlorine distances and chlorine–zirconium–chlorine angles are relatively constant in the studied molecules. Zirconium–cyclopentadienyl distances can be influenced mainly by modifying the ligand structure, whereas cyclopentadienyl–zirconium– cyclopentadienyl angles and cyclopentadienyl–cyclopentadienyl plane angles can be controlled by bridge modifications. The HF/3‐21G* method can be applied for the estimation of steric effects in zirconocene catalyzed polymerization reactions, therefore being suitable for the construction of structure–polymerization property correlations. © 2000 John Wiley & Sons, Inc. J Comput Chem 22: 51–64, 2001 相似文献