全文获取类型
收费全文 | 188篇 |
免费 | 8篇 |
专业分类
化学 | 101篇 |
力学 | 4篇 |
数学 | 27篇 |
物理学 | 64篇 |
出版年
2023年 | 1篇 |
2022年 | 2篇 |
2019年 | 3篇 |
2018年 | 8篇 |
2017年 | 2篇 |
2016年 | 5篇 |
2015年 | 5篇 |
2014年 | 6篇 |
2013年 | 8篇 |
2012年 | 8篇 |
2011年 | 18篇 |
2010年 | 5篇 |
2009年 | 8篇 |
2008年 | 14篇 |
2007年 | 13篇 |
2006年 | 17篇 |
2005年 | 15篇 |
2004年 | 9篇 |
2003年 | 7篇 |
2002年 | 13篇 |
2001年 | 1篇 |
2000年 | 1篇 |
1999年 | 2篇 |
1998年 | 1篇 |
1997年 | 2篇 |
1996年 | 2篇 |
1993年 | 1篇 |
1992年 | 1篇 |
1988年 | 1篇 |
1986年 | 1篇 |
1985年 | 1篇 |
1984年 | 1篇 |
1982年 | 3篇 |
1981年 | 2篇 |
1980年 | 1篇 |
1978年 | 1篇 |
1977年 | 3篇 |
1967年 | 1篇 |
1943年 | 2篇 |
1939年 | 1篇 |
排序方式: 共有196条查询结果,搜索用时 734 毫秒
191.
Raviv U Giasson S Kampf N Gohy JF Jérôme R Klein J 《Langmuir : the ACS journal of surfaces and colloids》2008,24(16):8678-8687
Normal and shear forces were measured as a function of surface separation, D, between hydrophobized mica surfaces bearing layers of a hydrophobic-polyelectrolytic diblock copolymer, poly(methyl methacrylate)- block-poly(sodium sulfonated glycidyl methacrylate) copolymer (PMMA- b-PSGMA). The copolymers were attached to each hydrophobized surface by their hydrophobic PMMA moieties with the nonadsorbing polyelectrolytic PSGMA tails extending into the aqueous medium to form a polyelectrolyte brush. Following overnight incubation in 10 (-4) w/v aqueous solution of the copolymer, the strong hydrophobic attraction between the hydrophobized mica surfaces across water was replaced by strongly repulsive normal forces between them. These were attributed to the osmotic repulsion arising from the confined counterions at long-range, together with steric repulsion between the compressed brush layers at shorter range. The corresponding shear forces on sliding the surfaces were extremely low and below our detection limit (+/-20-30 nN), even when compressed down to a volume fraction close to unity. On further compression, very weak shear forces (130 +/- 30 nN) were measured due to the increase in the effective viscous drag experienced by the compressed, sliding layers. At separations corresponding to pressures of a few atmospheres, the shearing motion led to abrupt removal of most of the chains out of the gap, and the surfaces jumped into adhesive contact. The extremely low frictional forces between the charged brushes (prior to their removal) is attributed to the exceptional resistance to mutual interpenetration displayed by the compressed, counterion-swollen brushes, together with the fluidity of the hydration layers surrounding the charged, rubbing polymer segments. 相似文献
192.
193.
We introduce and explore a model of an ensemble of agents searching, in parallel, a long circular strand for a target site. The agents performing the search combine local-scanning (conducted by a one-dimensional motion along the strand) and random relocations on the strand. The agent-ensemble search-durations are analyzed, their limiting probability distributions are obtained in closed-form, and the optimal relocation strategies are derived. The results encompass the cases of parallel and massively parallel searches, taking place in the presence of either finite-mean or heavy-tailed relocation durations. The results are applicable to a wide spectrum of local-scans, including linear motions, Brownian motions, subdiffusive motions, fractional Brownian motions, and fractional Lévy motions. 相似文献
194.
Steiner A Szekely P Szekely O Dvir T Asor R Yuval-Naeh N Keren N Kesselman E Danino D Resh R Ginsburg A Guralnik V Feldblum E Tamburu C Peres M Raviv U 《Langmuir : the ACS journal of surfaces and colloids》2012,28(5):2604-2613
Like-charged solid interfaces repel and separate from one another as much as possible. Charged interfaces composed of self-assembled charged-molecules such as lipids or proteins are ubiquitous. The present study shows that although charged lipid-membranes are sufficiently rigid, in order to swell as much as possible, they deviate markedly from the behavior of typical like-charged solids when diluted below a critical concentration (ca. 15 wt %). Unexpectedly, they swell into lamellar structures with spacing that is up to four times shorter than the layers should assume (if filling the entire available space). This process is reversible with respect to changing the lipid concentration. Additionally, the research shows that, although the repulsion between charged interfaces increases with temperature, like-charged membranes, remarkably, condense with increasing temperature. This effect is also shown to be reversible. Our findings hold for a wide range of conditions including varying membrane charge density, bending rigidity, salt concentration, and conditions of typical living systems. We attribute the limited swelling and condensation of the net repulsive interfaces to their self-assembled character. Unlike solids, membranes can rearrange to gain an effective entropic attraction, which increases with temperature and compensates for the work required for condensing the bilayers. Our findings provide new insight into the thermodynamics and self-organization of like-charged interfaces composed of self-assembled molecules such as charged biomaterials and supramolecular assemblies that are widely found in synthetic and natural constructs. 相似文献
195.
We have theoretically and experimentally studied the local temporal and spectral characteristics of an ultrashort pulse passing a simple thin diffusive element. We show that as one moves away from the diffuser the pulse evolves into a spatiotemporal speckle. 相似文献
196.